Chemistry of Natural Compounds

, Volume 7, Issue 6, pp 714–718 | Cite as

Chemical composition of the oleoresin of the genus picea IV. Structure and absolute configuration of ajanol, a new sesquiterpene diol from Picea ajanensis

  • V. A. Babkin
  • Zh. V. Dubovenko
  • V. A. Pentegova
Article
  • 34 Downloads

Conclusions

From the neutral fraction of the oleoresin ofPicea ajanensis Fisch. a new sesquiterpene diol of the selinane type has been isolated which we have called ajanol. It has been established that it is selinane-4α,6α-diol.

Keywords

Absolute Configuration Cotton Effect Chromium Trioxide Hydroxy Ketone Secondary Hydroxy Group 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    V. A. Babkin, Zh. V. Dubovenko, and V. A. Pentegova, Izv. Sibirskogo Otd. Akad. Nauk SSSR, Ser. Khim. Nauk,1970, No. 2, Series No. 1, 168.Google Scholar
  2. 2.
    N. Bhacca and D. Williams, Applications of NMR Spectroscopy in Organic Chemistry, Holden-Day, San Francisco (1964).Google Scholar
  3. 3.
    D. H. R. Barton, J. Chem. Soc.,1953, 1027.Google Scholar
  4. 4.
    L. Jackman, Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry, Pergamon Press, Oxford (1959), p. 115.Google Scholar
  5. 5.
    C. Djerassi, R. Riniker, and B. Riniker, J. Amer. Chem. Soc.,78, 6362 (1956).CrossRefGoogle Scholar
  6. 6.
    C. Djerassi, R. Records, E. Bunnenberg, K. Mislow, and A. Moscowitz, J. Amer. Chem. Soc.,84, 870 (1962).CrossRefGoogle Scholar
  7. 7.
    V. A. Pentegova, O. Motl, and V. Herout, Collection Czech. Chem. Commun.,26, 1362 (1961).CrossRefGoogle Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • V. A. Babkin
  • Zh. V. Dubovenko
  • V. A. Pentegova

There are no affiliations available

Personalised recommendations