Chemistry of Natural Compounds

, Volume 12, Issue 2, pp 193–197 | Cite as

Structure and features of the fragmentation of the products of the reduction of dubinidinone

  • I. A. Bessonova
  • Ya. V. Rashkes
  • S. Yu. Yunusov
Article

Summary

The Clemmensen reduction of dubinidinone (II) leads to the hydrogenolysis of the dihydrofuran ring with the predominant formation of α-methoxy-α-methyl-α,β-dihydropyrano-2-quinolone.

An explanation of the characteristics of the fragmentation of the products of the reduction of dubinidinone has been found.

Keywords

Pyrylium Hydrofuran Platinum Black Tropylium Anhydrous Sodium Carbonate 

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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • I. A. Bessonova
  • Ya. V. Rashkes
  • S. Yu. Yunusov

There are no affiliations available

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