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Journal of Materials Science

, Volume 27, Issue 14, pp 3793–3798 | Cite as

Infrared and Raman spectra of binary tellurite glasses containing boron and indium oxides

  • Qiu Jian Rong
  • Akiyoshi Osaka
  • Tokuro Nanba
  • Jun Takada
  • Yoshinari Miura
Papers

Abstract

The constitution of glasses in the systems M2O3-TeO2 (M = B and In) was investigated by Raman and infrared spectroscopy. From the relation between the M2O3 content and the intensity ratios of the deconvoluted Raman peaks I(720)/I(665) and I(780)/I(665), it was concluded that In2O3 behaves as a network modifier to yield TeO 3 units and that discrete BO3 and BO4 units construct a network of glasses containing boron oxide. A structural model for those glasses was derived which involves three-coordinated oxygen atoms and TeO4 units of an intermediate configuration, O3Teδ+ ...Oδ-.

Keywords

Oxide Oxygen Polymer Indium Boron 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman & Hall 1992

Authors and Affiliations

  • Qiu Jian Rong
    • 1
  • Akiyoshi Osaka
    • 1
  • Tokuro Nanba
    • 1
  • Jun Takada
    • 1
  • Yoshinari Miura
    • 1
  1. 1.Department of Applied Chemistry, Faculty of EngineeringOkayama University 3-3-1Okayama-shiJapan

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