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Journal of Materials Science

, Volume 26, Issue 7, pp 1799–1802 | Cite as

Synthesis and properties of poly (organophosphazenes) ionomers [NP(HNC6H5)2−(x+y)(HNC6H4SO3H)x (HNC6H4SO3Li)y]n

  • Y. Kurachi
  • M. Kajiwara
Papers

Abstract

Poly(anilino sulphamicphosphazenes) such as [NP(HNC6H5)2−x(HNC6H4SO3H)x]n for polymer (I) x=0.3 and for polymer (II) x=0.8 were prepared by the reaction of poly(anilinophosphazene) [NP(HNC6H5)2]n and sulphonic chloride HSO3Cl in tetrachloroethane solvent several timeS. Also, H protons in the polymer (I) and (II) were prepared from lithum hydroxide in aqueous solution. It was found, by chemical analysis, that the product prepared with (I) and (II) had compositions such as [NP(HNC6H5)1.7 (HNC6H4SO3H)0.1(HNC6H4SO3Li)0.2]n(III) and [NP(HNC6H5)1.2(HN-C6H4SO3Li)0.8]n(IV). Also, the resistivity of products (III) and (IV) were determined and found to be 3.3×107 and 1.5×107 Ωcm−1, respectively.

Keywords

Polymer Chloride Aqueous Solution Chemical Analysis Hydroxide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman and Hall Ltd 1991

Authors and Affiliations

  • Y. Kurachi
    • 1
  • M. Kajiwara
    • 2
  1. 1.Research Development CenterBS Co.TokyoJapan
  2. 2.Department of Applied Chemistry, Faculty of EngineeringNagoya UniversityNagoyaJapan

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