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Journal of Materials Science

, Volume 27, Issue 16, pp 4337–4340 | Cite as

Effect of pressure on the coking yields of coal tar pitches

  • G. Bhatia
  • R. K. Aggarwal
  • O. P. Bahl
Papers

Abstract

Pyrolysis of five coal tar pitches with wide ranging characteristics, made from the same coal tar precursor, has been studied under nitrogen pressures of 105, 50×105, 90×105 and 160×105 Pa, at a temperature of 550 °C. The residues were further heat-treated to 900 °C to obtain the ultimate normal (105 Pa) and pressure coking yields of these pitches. The literature states that for pitches with relatively lower softening points the carbonization pressure not only increases the coking yield but also lowers the temperature at which the pyrolysis is complete. This is seen to hold true for the present set of pitches, having a much wider range of softening points. Further, one of the pitches, earlier reported by us to be a good preforming pitch for carbon-carbon composites, gave an ultimate coking yield of 88% on subjection to a nitrogen pressure of 160×105 Pa at 550 °C followed by ambient pressure carbonization to 900 °C. It thus appears that a carbonization pressure of 160×105 Pa for a suitable preforming pitch can act as a reasonably good alternative to the expensive hot isostatic pressure impregnation carbonization technique employed in the production of carbon-carbon composites.

Keywords

Polymer Pyrolysis Good Alternative Ambient Pressure Softening Point 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman & Hall 1992

Authors and Affiliations

  • G. Bhatia
    • 1
  • R. K. Aggarwal
    • 1
  • O. P. Bahl
    • 1
  1. 1.Carbon Technology UnitDivision of Materials, National Physical LaboratoryNew DelhiIndia

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