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Journal of Materials Science

, Volume 28, Issue 4, pp 1081–1089 | Cite as

Polyethylene-polyethylene microfibrillar composites

  • Z. Bashir
  • J. A. Odell
Papers

Abstract

Solid-state drawing of melt-crystallized, or gel(solution)-crystallized, polyethylene (PE) is well established as a means of producing high modulus high-strength fibres. Here, an alternative route, based on melt-processing, is reviewed and its merits are assessed. Contrary to expectation, melt processing of flexible chain polymers can directly yield oriented products with good mechanical properties, without the need for post-drawing in the solid state. The melt-processed PE can give a special microfibrillar composite morphology which results in good mechanical properties. The paper also reviews aspects of composites design by comparing these microfibrillar composites with traditional fibre composites and molecular composites.

Keywords

Polymer Mechanical Property Polyethylene Solid State Chain Polymer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    J. A. Odell, D. T. Grubb and A. Keller, Polymer 19 (1978) 617.CrossRefGoogle Scholar
  2. 2.
    Z. Bashir, J. A. Odell and A. Keller, J. Mater. Sci. 19 (1984) 617.CrossRefGoogle Scholar
  3. 3.
    Idem, ibid. 21 (1986) 3993.CrossRefGoogle Scholar
  4. 4.
    Z. Bashir and A. Keller, Colloid Polym. Sci. 267 (1989) 116.CrossRefGoogle Scholar
  5. 5.
    G. Capaccio, T. A. Crompton and I. M. Ward, J. Polym. Sci. Polym. Phys. Ed. 14 (1976) 1641.CrossRefGoogle Scholar
  6. 6.
    Idem, ibid. 18 (1980) 301.CrossRefGoogle Scholar
  7. 7.
    P. Smith, P. J. Lemstra and H. J. Booij, ibid, 19 (1981) 877.CrossRefGoogle Scholar
  8. 8.
    W. Hoogsteen, H. Kormelink, G. Eshuis, G. Ten Brinke and A. J. Pennings, J. Mater. Sci. 23 (1988) 3467.CrossRefGoogle Scholar
  9. 9.
    A. Peterlin, in “Man Made Fibres”, Vol. 1, edited by H. Mark, S. M. Atlas and E. Cernia (Interscience, New York, 1967) pp. 317.Google Scholar
  10. 10.
    D. Hull, “An Introduction to Composite Materials” (Cambridge University Press, 1981).Google Scholar
  11. 11.
    S. Sato, A. Kurumada, H. Iwaki and Y. Komatsu, Carbon 27 (1989) 791.CrossRefGoogle Scholar
  12. 12.
    J. L. White and P. M. Sheaffer, Carbon 27 (1989) 697.CrossRefGoogle Scholar
  13. 13.
    R. Wehrenberg, Plastics World, October (1985) 60.Google Scholar
  14. 14.
    Polymer Engineering Course, PT 614, Unit 5, Polymer Composites, Open University (1984), Milton Keynes, UK.Google Scholar
  15. 15.
    D. S. Parker and A. F. Yee, J. Thermoplast. Compos. Mater. 2 (1989) 2.CrossRefGoogle Scholar
  16. 16.
    Ciba-Geigy data sheets RTA 100c (April 1985) and FTA 49e (August 1984).Google Scholar
  17. 17.
    S. L. Kaplan, K. Scholle and H. X. Nguyen “High Performance Textiles”, Vol. 9, no. 8, “Properties of high performance PE fibres” (Elsevier, Oxford, 1989) pp. 3–4.Google Scholar
  18. 18.
    E. Helminiak, C. L. Benner, F. E. Arnold and G. E. Husman, US Pat. 4207 407 (1980).Google Scholar
  19. 19.
    S. J. Krause, T. Haddock, G. E. Price, P. G. Lenhart, J. F. O'Brien, T. E. Helminiak and W. W. Adams, J. Polym. Sci. B Polym. Phys. Ed. 24 (1986) 1991.CrossRefGoogle Scholar
  20. 20.
    M. Takayanagi, Pure. Appl. Chem. 55 (1983) 819.CrossRefGoogle Scholar
  21. 21.
    M. Ballauf, Polym Adv. Technol. 1 (1990) 109.CrossRefGoogle Scholar
  22. 22.
    M. M. Coleman, D. J. Skrovanek, H. Hu and P. C. Painter, Macromolecules 21 (1988) 59.CrossRefGoogle Scholar
  23. 23.
    G. T. Pawlikowski, D. Dutta and R. A. Weiss, Ann. Rev. Mater. Sci. 21 (1991) 159.CrossRefGoogle Scholar
  24. 24.
    J. S. Wallace, Loon-Seng Tan, F. E. Arnold, Polymer 31 (1990) 2411.CrossRefGoogle Scholar
  25. 25.
    B. C. Auman and V. Percec, Polymer 29 (1988) 938.CrossRefGoogle Scholar
  26. 26.
    T. D. Shaffer and V. Percec, Makromol. Chem. 187 (1986) 111.CrossRefGoogle Scholar
  27. 27.
    J. L. Kardos and J. Raisoni, Polym. Engng. Sci. 15 (1975) 183.CrossRefGoogle Scholar
  28. 28.
    R. A. Weiss, Wansoo Huh and L. Nicolais, ibid. 27 (1987) 684.CrossRefGoogle Scholar
  29. 29.
    A. Siegmann, A. Dagan and S. Senig, Polymer 26 (1985) 1325.CrossRefGoogle Scholar
  30. 30.
    E. G. Joseph, G. L. Wilkes and D. G. Baird, Polym. Engng. Sci. 25 (1985) 377.CrossRefGoogle Scholar
  31. 31.
    K. G. Blizard and D. G. Baird, ibid. 27 (1987) 653.CrossRefGoogle Scholar
  32. 32.
    G. Kiss, ibid. 27 (1987) 410.CrossRefGoogle Scholar
  33. 33.
    R. H. Baughman, E. A. Turi, A. F. Pueziosi and K.-C. Yee., US Pat. 4255 535 (1981).Google Scholar
  34. 34.
    M. R. Piggott, “Load Bearing Fibre Composites” editor D. M. R. Taplin (Pergamon Press, Oxford, 1980).Google Scholar
  35. 35.
    T. H. Courtney, in “Mechanical Behaviour of Materials” (McGraw-Hill, 1990) Ch. 6, pp. 248–51.Google Scholar
  36. 36.
    H. Sprenger, H. Richter and J. J. Nickl, J. Mater. Sci. 11 (1976) 2075.CrossRefGoogle Scholar
  37. 37.
    I. Sakurada, T. Ito and K. Nakamae, Makromol. Chem. 75 (1964) 1.CrossRefGoogle Scholar
  38. 38.
    R. F. Shauffele and T. Shimanouchi, J. Chem Phys. 47 (1967) 3605.CrossRefGoogle Scholar
  39. 39.
    D. C. Bassett, “Principles of Polymer Morphology” (Cambridge University Press, 1981).Google Scholar
  40. 40.
    J. W. Weeton, “Engineer's Guide to Composite Materials”, Section 3 (American Society for Metals, Ohio, 1987).Google Scholar
  41. 41.
    T. S. Chung, Z. Gurion and J. B. Stamatoff, Polym. Compos. 6 (1985) 181.CrossRefGoogle Scholar
  42. 42.
    W. W. Adams and R. K. Eby, Mater. Res. Soc. Bull., 12 (1987) 22.CrossRefGoogle Scholar
  43. 43.
    S. Rastogi and J. A. Odell, Polym. Commun. (1991) submitted.Google Scholar
  44. 44.
    K. A. Narh and A. Keller, Polymer 32 (1991) 2512.CrossRefGoogle Scholar
  45. 45.
    A. Keller, J. Dlugosz, M. J. Folkes, E. Pedemont, F. P. Scalisi and F. M. Willmouth, J. Phys. 32 C5a (1971) 295.CrossRefGoogle Scholar
  46. 46.
    R. D. B. Fraser, T. P. Macrae, D. A. D. Parry and E. Suzuki, Polymer 12 (1971) 35.CrossRefGoogle Scholar
  47. 47.
    R. D. B. Fraser, T. P. Macrae, G. R. Millward, D. A. D. Parry, E. Suzuki and P. A. Tulloch, Appl. Polym. Symp. 18 (1971) 65.Google Scholar

Copyright information

© Chapman & Hall 1993

Authors and Affiliations

  • Z. Bashir
    • 1
  • J. A. Odell
    • 1
  1. 1.H.H. Wills Physics LaboratoryUniversity of BristolUK

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