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Journal of Materials Science

, Volume 29, Issue 6, pp 1680–1685 | Cite as

Synthesis of silicon oxynitride from a polymeric precursor

Part II The formation of trimethylcyclotrisilazane and tetramethylcyclotetrasilazane from the ammonolysis of dichloromethylsilane in diethyl ether
  • Ga -Er Yu
  • J. Parrick
  • M. Edirisinghe
  • D. Finch
  • B. Ralph
Papers

Abstract

Proton nuclear magnetic resonance (1H NMR) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy and gas chromatography (GC) have been used to study the products of ammonolysis of dichloromethylsilane in diethyl ether at 0 °C. Results indicate that the major products are trimethylcyclotrisilazane and tetramethylcyclotetrasilazane. Hydrolysis of the cyclosilazanes has also been qualitatively investigated. A simple and useful method for the identification of cyclosilazanes has been developed using the 1H NMR technique.

Keywords

Polymer Silicon Ether Hydrolysis Fourier 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman & Hall 1994

Authors and Affiliations

  • Ga -Er Yu
    • 1
    • 2
  • J. Parrick
    • 1
  • M. Edirisinghe
    • 2
  • D. Finch
    • 2
  • B. Ralph
    • 2
  1. 1.Department of ChemistryBrunel UniversityUxbridgeUK
  2. 2.Department of Materials TechnologyBrunel UniversityUxbridgeUK

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