Advertisement

Journal of Materials Science

, Volume 29, Issue 14, pp 3743–3748 | Cite as

ZrO2 obtained by the sol-gel method: influence of synthesis parameters on physical and structural characteristics

  • M. L. Rojas -Cervantes
  • R. M. Martin -Aranda
  • A. J. Lopez -Peinado
  • J. De D. Lopez -Gonzalez
Article

Abstract

The effects of some synthesis parameters, such as alcohol/alcoxide and water/alcoxide molar ratios, type of solvent and reaction temperature, on the physical and crystalline characteristics of ZrO2 prepared by the sol-gel method were studied. The results show that gelling time, weight loss, surface area, pore-size distribution and crystalline phases were influenced by the preparation conditions.

Keywords

Polymer Structural Characteristic Reaction Temperature Crystalline Phasis Material Processing 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    M. Haruta, T. Kobayashi, H. Sano and N. Yamada, Chem. Lett. 829 (1987) 405.CrossRefGoogle Scholar
  2. 2.
    A. Knell, P. Barnickel, A. Baiker and A. Wokaun, J. Catal. 137 (1992) 306.CrossRefGoogle Scholar
  3. 3.
    K. Tanabe, Mater. Chem. Phys. 13 (1985) 347.CrossRefGoogle Scholar
  4. 4.
    S. Sakka and Y. Toshinobu, Struct. Bonding 77 (1992) 89.CrossRefGoogle Scholar
  5. 5.
    A. Z. Khan and E. Ruckenstein, Appl. Catal. 90 (1992) 199.Google Scholar
  6. 6.
    L. G. Hubert-Pfalzgraf, New. J. Chem. 11 (1987) 663.Google Scholar
  7. 7.
    I. A. Montoya, T. Viveros, J. M. Dominguez, L. A. Canales and I. Schifter, Catal. Lett. 15 (1992) 207.CrossRefGoogle Scholar
  8. 8.
    B. E. Yoldas, J. Mater. Sci. 21 (1986) 1087.CrossRefGoogle Scholar
  9. 9.
    K. S. Mazdiyasni, C. T. Lynch and J. S. Smith, J. Am. Ceram. Soc. 48 (7) (1965) 372.CrossRefGoogle Scholar
  10. 10.
    R. C. Mehrotra, in “Sol-Gel Science and Technology”, Proceedings of the Winter School on Glasses and Ceramics from Gels, Sao Carlos (SP), Brazil, August 1989, edited by M. A. Aeger, M. Jr. Jafelicci, D. F. Souza and E. E. Zanotto, (San Carlos, SP, 1989) p. 1.Google Scholar
  11. 11.
    D. C. Bradley and P. Thornton, in “Comprehensive Inorganic Chemistry” edited by J. C. Bailar, H. J. Emeléus, R. Nyholm and A. F. Trotman-Dickenson (Pergamon press, Oxford, 1973) p. 449.Google Scholar
  12. 12.
    W. B. Beumenthal, “The Chemical Behavior of Zirconium” (Von Nostrand, NJ, 1958) p. 181.Google Scholar
  13. 13.
    B. E. Yoldas, J. Am. Ceram, Soc. 65 (1982) 387.CrossRefGoogle Scholar
  14. 14.
    K. S. Mazdiyani, in “Reactivity of solids”, Proceedings of the VI International Symposium on the Reactivity of Solids, Schenectady, January 1969, edited by J. W. Mitchell (WileyInterscience, New York, 1969) p. 115.Google Scholar
  15. 15.
    B. E. Yoldas, J. Mater. Sci. 21 (1986) 1080.CrossRefGoogle Scholar
  16. 16.
    R. C. Garvie and P. S. Nicholson, J. Am. Ceram. Soc. 55 (1972) 152.CrossRefGoogle Scholar

Copyright information

© Chapman & Hall 1994

Authors and Affiliations

  • M. L. Rojas -Cervantes
    • 1
  • R. M. Martin -Aranda
    • 1
  • A. J. Lopez -Peinado
    • 1
  • J. De D. Lopez -Gonzalez
    • 1
  1. 1.Departmento de Quimica Inorgánica y Quimica Tecnica (U.N.E.D.)MadridSpain

Personalised recommendations