Journal of Materials Science

, Volume 29, Issue 10, pp 2629–2632 | Cite as

Interface reactions between glass melts containing transition metal oxides and ferrites

  • A. Nitta
  • T. Ono
  • T. Komatsu
  • K. Matusita


The interface reactions between SiO2-PbO-MO melts (M = Fe, Mn, Zn and Ni) and Mn-Zn and Ni-Zn ferrites were studied using electron probe microanalysis and X-ray diffraction. Ni ions in the glass melt containing NiO were localized at the interface between the glass and Mn-Zn ferrite. The Ni-rich layer was also detected at the interface between NiO containing glass melt and Ni-Zn ferrite; the composition of this layer was thought to be close to NiFe2O4. Pb8NiSi6O21 crystal was deposited as the product of the reaction with the glass melt and Mn-Zn ferrite at 700 °C. As compared with Mn-Zn ferrite, no reaction products were formed in Ni-Zn ferrite at various temperatures. The dissolution length of Mn-Zn ferrite in SPN5 glass melt was found to be smaller than for other melts, and it is concluded that the NiO-rich layer at the surface of the ferrite is chemically very durable to the glass melts.


Oxide Polymer Ferrite Metal Oxide Material Processing 
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Copyright information

© Chapman & Hall 1994

Authors and Affiliations

  • A. Nitta
    • 1
  • T. Ono
    • 1
    • 2
  • T. Komatsu
    • 1
  • K. Matusita
    • 1
  1. 1.Department of ChemistryNagaoka University of TechnologyNiigata-kenJapan
  2. 2.Shizuoka Operations Center, Technical Center 12117Corning Japan K. K.ShizuokaJapan

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