Journal of Materials Science

, Volume 30, Issue 5, pp 1386–1390 | Cite as

Antiferroelectric lead zirconate thin films derived from acetate precursors

  • K. K. Li
  • F. Wang
  • G. H. Haertling


Antiferroelectric lead zirconate (PbZrO3) films derived from acetate precursors have been fabricated on Pt/Ti-coated silicon wafers and fused silica at 700 °C with an automatic dip-coating process. Films formed directly on the metallized silicon wafer showed the coexistence of perovskite and pyrochlore phases. A pre-coated titania layer of about 10 nm facilitated the formation of the desired perovskite phase. Films deposited on fused silica exhibited interactions between lead and silica which inhibited the crystallization of the films. In this case, a pre-coated titania layer in the range 50–75 nm acted as a diffusion barrier layer, allowing the formation of the perovskite phase. Antiferroelectricity in the films was confirmed by X-ray superstructure, dielectric double hysteresis loops and d.c. bias behaviour at room temperature. The corresponding transverse electro-optic properties were also measured for films deposited on fused silica.


Crystallization Perovskite Hysteresis Loop Silicon Wafer Fuse Silica 
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  1. 1.
    E. Sawaguchi, G. Shirane and Y. Takagi, J. Phys. Soc. Jpn 6 (1951) 333.CrossRefGoogle Scholar
  2. 2.
    G. Shirane, E. Sawaguchi and Y. Takagi, Phys. Rev. 84 (1951) 476.CrossRefGoogle Scholar
  3. 3.
    E. Sawaguchi, H. Maniwa and H. Hoshina, ibid. 83 (1951) 1078.CrossRefGoogle Scholar
  4. 4.
    H. Fujishita, Y. Shiozaki, N. Achiwa and E. Sawaguchi, J. Phys. Soc. Jpn 51 (1982) 3583.CrossRefGoogle Scholar
  5. 5.
    L. N. Chapin and S. A. Myers, Mater. Res. Soc. Symp. Proc. 200 (1990) 153.CrossRefGoogle Scholar
  6. 6.
    C.-C. Hsueh and M. L. Mecartney, ibid. 200 (1990) 219.CrossRefGoogle Scholar
  7. 7.
    A. H. Carim, B. A. Tuttle, D. H. Doughty and S. L. Martinez, J. Am. Ceram. Soc. 74 (1991) 1455.CrossRefGoogle Scholar
  8. 8.
    K. D. Preston and G. H. Haertling, Integr. Ferroelect. 1 (1992) 89.CrossRefGoogle Scholar
  9. 9.
    S. L. Swartz, S. J. Bright, P. J. Melling and T. R. Shrout, Ferroelectrics 108 (1990) 71.CrossRefGoogle Scholar
  10. 10.
    S. Hirano and K. Kato, J. Non-Cryst. Solids 100 (1988) 538.CrossRefGoogle Scholar
  11. 11.
    B. Jaffe, Proc. Inst. Radio Eng. 49 (1961) 1264.Google Scholar
  12. 12.
    K. Uchino and S. Nomura, Ferroelectrics 50 (1983) 191.CrossRefGoogle Scholar
  13. 13.
    F. Wang, K. K. Li and G. H. Haertling, Opt. Lett. 17 (1992) 1122.CrossRefGoogle Scholar
  14. 14.
    D. Berlincourt, H. H. A. Krueger and B. Jaffe, J. Phys. Chem. Solids 25 (1964) 659.CrossRefGoogle Scholar
  15. 15.
    G. H. Haertling, Ferroelectrics 116 (1991) 51.CrossRefGoogle Scholar
  16. 16.
    K. K. Li, G. H. Haertling and W.-Y. Howng, Integr. Ferroelect. 3 (1992) 81.CrossRefGoogle Scholar
  17. 17.
    F. Wang, C. B. Juang, C. Bustamante and A. Y. Wu, in “Proceedings of the 4th International SAMPE Electronic Conference”, Albuquerque, New Mexico, June 1990 (Society for the Advancement of Materials and Process Engineers, Covina, CA, 1990) p. 712.Google Scholar
  18. 18.
    Y. Takahashi, Y. Matsuoka, K. Yamaguchi, M. Matsuki and K. Kobayashi, J. Mater. Sci. 25 (1990) 3960.CrossRefGoogle Scholar
  19. 19.
    K. D. Budd, S. K. Dey and D. A. Payne, Br. Ceram. Proc. 36 (1985) 107.Google Scholar
  20. 20.
    Y. Takahashi and K. Yamaguchi, J. Mater. Sci. 25 (1990) 3950.CrossRefGoogle Scholar
  21. 21.
    B. A. Tuttle, private communication (1992).Google Scholar
  22. 22.
    K. K. Li, G. H. Haertling and W.-Y. Hwong, presented at the American Ceramic Society 94th Annual Meeting, Minneapolis, MN, April 1992 (Abstr. 45-E-92)Google Scholar

Copyright information

© Chapman & Hall 1995

Authors and Affiliations

  • K. K. Li
    • 1
  • F. Wang
    • 1
  • G. H. Haertling
    • 1
  1. 1.Department of Ceramic EngineeringClemson UniversityClemsonUSA

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