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Journal of Materials Science

, Volume 30, Issue 5, pp 1283–1289 | Cite as

Theory of the enhancement factors of solute diffusion in dilute BCC solid solutions

  • D. Fuks
  • V. Segel
  • J. Pelleg
Papers

Abstract

The enhancement factors for the solute diffusion in dilute b.c.c. alloys are discussed on the lines of two approaches. One of them is based on the Taylor's expansion series of activation energy and pre-exponential factor on concentration. The convergency of these series is studied. The second approach is formulated in the framework of the statistical theory. The comparative analyses of these two ways for the explanation of the enhancement of diffusion is carried out. The concentration dependencies of jump frequencies are investigated for V-Zr dilute solid solution as an example. It is shown that these dependencies are connected with the changes of the migration energy Em(c) as well as with the changes of the frequencies of vibrations. Different mechanisms that are possible for the explanation of the enhancement of D(c) are discussed.

Keywords

Polymer Migration Activation Energy Solid Solution Comparative Analysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    A. D. Le Claire, J. Nucl. Mater. 69, 70 (1978) 70.CrossRefGoogle Scholar
  2. 2.
    R. E. Hoffman, D. Turnbull and E. W. Hart, Acta Metall. 3 (1955) 417.CrossRefGoogle Scholar
  3. 3.
    H. Hadgenschulte and Th. Heumann, Phys. Status Solidi (b) 154 (1989) 71.CrossRefGoogle Scholar
  4. 4.
    A. D. Le Claire, Phil Mag. 7(73) (1962) 141.CrossRefGoogle Scholar
  5. 5.
    A. B. Lidiard, Phil. Mag. 5 (1960) 1171.CrossRefGoogle Scholar
  6. 6.
    D. D. Pruthi and R. P. Agarwala, Phil. Mag. 49(2) (1984) 263.CrossRefGoogle Scholar
  7. 7.
    D. D. Pruthi and R. P. Agarwala, Phil. Mag. 45(6) (1982) 841.CrossRefGoogle Scholar
  8. 8.
    A. D. Le Claire, Defect and Diffusion Forum 83–84 (1992) 1.Google Scholar
  9. 9.
    A. D. Le Claire, Phil. Mag. 21 (1970) 819.CrossRefGoogle Scholar
  10. 10.
    M. J. Jones and A. D. Le Claire, Phil. Mag. 26 (1972) 1191.CrossRefGoogle Scholar
  11. 11.
    N. L. Peterson and S. J. Rothman, Phys. Rev. 136A (1964) 848.Google Scholar
  12. 12.
    R. J. Borg and Dyf. Lai, J. Appl. Phys. 41 (1970) 5193.CrossRefGoogle Scholar
  13. 13.
    K. Maier, M. Peo, B. Saile et al. Phil. Mag. 40 (1979) 701.CrossRefGoogle Scholar
  14. 14.
    J. Pelleg and J. Haddad, private communication.Google Scholar
  15. 15.
    J. Trapenau and Ch. Herzig, J. Phys.: Condens. Matter 2 (1990) 9345.Google Scholar

Copyright information

© Chapman & Hall 1995

Authors and Affiliations

  • D. Fuks
    • 1
  • V. Segel
    • 1
  • J. Pelleg
    • 1
  1. 1.Department of Materials EngineeringBen-Gurion University of the NegevBeer ShevaIsrael

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