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Journal of Materials Science

, Volume 30, Issue 11, pp 2944–2949 | Cite as

Thermal degradation of foamed polystyrene

  • S. Mehta
  • S. Biederman
  • S. Shivkumar
Papers

Abstract

The thermal degradation of foamed polystyrene patterns in the expendable pattern casting (EPC) process has been studied. Various physical transitions that may occur during the degradation of the polymer have been determined with scanning electron microscopy, differential scanning calorimetry and thermogravimetric analysis. The effects of polymer density and bead structure on the degradation characteristics have been investigated. The results indicate that, when exposed to elevated temperatures, the polymer beads collapse at about 110–120 °C. The collapsed beads melt at 160 °C, and start to vaporize at temperatures greater than about 275 °C. Complete volatilization occurs in the temperature range 460–500 °C. The heat of degradation of expanded polystyrene has been estimated to be at the order of 912 Jg−1.

Keywords

Polymer Scanning Electron Microscopy Foam Differential Scanning Calorimetry Elevated Temperature 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    A. J. Clegg, Foundry Trade J. Int. 9 (1986) 51.Google Scholar
  2. 2.
    H. J. Heine, Foundry Man. & Tech. 114 (1986) 36.Google Scholar
  3. 3.
    S. Shivkumar and B. Gallois, Trans. Am. Foundrymen's Soc. 95 (1987) 791.Google Scholar
  4. 4.
    Idem, ibid. 95 (1987) 801.Google Scholar
  5. 5.
    L. Wang, S. Shivkumar and D. Apelian, ibid. 98 (1990) 923.Google Scholar
  6. 6.
    S. Shivkumar, L. Wang and D. Apelian, J. of Met. 42 (1990) 38.Google Scholar
  7. 7.
    J. F. Rudd, in “Polymer Handbook”, edited by J. Brandrup and E. H. Immergut (Wiley, New York, 1989) p. V-82.Google Scholar
  8. 8.
    R. H. Boundy and R. F. Boyer, “Styrene, Its Polymers, Copolymers and Derivatives” (Reinhold Publishing Corporation, New York, 1952) 43–57.Google Scholar
  9. 9.
    S. Mehta, M.Sc. Thesis, Worcester Polytechnic Institute, Worcester, MA (1992).Google Scholar
  10. 10.
    M. Guaita, Brit. Polym. J. 18 (1986) 226.CrossRefGoogle Scholar
  11. 11.
    J. L. Gurman, L. Baier and B. C. Levin, Fire & Mater. 11 (1987) 109.CrossRefGoogle Scholar
  12. 12.
    A. Guyot, Polym. Deg. & Stab. 15 (1986) 219.CrossRefGoogle Scholar
  13. 13.
    S. Shivkumar, Trans. Am. Foundrymen's Soc. 101 (1993) in press.Google Scholar

Copyright information

© Chapman & Hall 1995

Authors and Affiliations

  • S. Mehta
    • 1
  • S. Biederman
    • 1
  • S. Shivkumar
    • 1
  1. 1.Department of Mechanical EngineeringWorcester Polytechnic InstituteWorcesterUSA

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