Journal of Materials Science

, Volume 30, Issue 11, pp 2821–2828 | Cite as

Influence of the interaction zone between coating and paper on the dynamic mechanical properties of a coated paper

  • Roger Hagen
  • Lennart Salmén


Papers coated with pigments bonded by polymer latexes have been tested by dynamic mechanical analysis. Measurements in tension and in three-point bending have been performed to determine the influence of the interaction zone between the coating and the paper on the properties of the coated paper. Comparisons have also been made with results from measurements in torsion. Experimental values of Young's modulus and the peak height of tan δ were higher than values theoretically calculated from data obtained on the separate layers, the paper and the coating. This deviation is interpreted as being due to the influence of an interaction zone between the coating and the base paper. If the thickness of the interaction zone is taken into account in the theoretical model, a better correlation with the experimental values is obtained for the peak height of tan δ. Higher values of the experimental data for the shear modulus of coated paper than from a weight-average calculation of the shear modulus of the pure components were obtained. This can be explained as being due to an increased stiffness of the coated paper as a result of the interaction zone, that was not adjusted for in the model. Further evidence for the existence of the interaction zone was provided by the pigment and latex distributions in the cross-section of coated papers determined in a scanning electron microscope using energy dispersive X-ray analysis.


Polymer Scanning Electron Microscope Mechanical Property Theoretical Model Shear Modulus 
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  1. 1.
    G. Engström, PhD dissertation, Royal Institute of Technology, Stockholm, Sweden (1993).Google Scholar
  2. 2.
    M. Akay, Compos. Sci. Technol. 47 (1993) 419.CrossRefGoogle Scholar
  3. 3.
    J. L. Thomason, Polym. Compos. 11 (1990) 105.CrossRefGoogle Scholar
  4. 4.
    Idem, Compos. Sci., Technol. 44 (1992) 87.CrossRefGoogle Scholar
  5. 5.
    Von Dr. A. Zosel, Farbe Lack 94 (1988) 809.Google Scholar
  6. 6.
    DOW Paper Latex, Product Overview-“Binders for paper and board coating”.Google Scholar
  7. 7.
    P. Lepoutre and B. Alince, J. Appl. Polym. Sci. 26 (1993) 791.CrossRefGoogle Scholar
  8. 8.
    R. Groves, J. E. Penson and C. Ruggles, in “TAPPI Proceedings of 1993 Coating Conference” (TAPPI, Atlanta, 1993) pp. 187–93.Google Scholar
  9. 9.
    N. L. Salmén and M. Rigdahl, Tappi J, 68 (1985) 105.Google Scholar
  10. 10.
    M. Htun and A. De Ruvo, Tappi 61 (6) (1978) 1.Google Scholar
  11. 11.
    R. Hagen, L. Salmén and A. De Ruvo, J. Appl. Polym. Sci. 48 (1993) 603.CrossRefGoogle Scholar
  12. 12.
    P. Kolseth, PhD dissertation, Royal Institute of Technology, Stockholm, Sweden (1983).Google Scholar
  13. 13.
    C. Fellers, H. Andersson and H. Hollmark, in “Paper Structure and Properties”, edited by J. A. Bristow and P. Kolseth (Dekker, New York, 1986) p. 151.Google Scholar
  14. 14.
    S. J. Kuang, C. A. Ferguson, A. Rezanowich and P. Lepoutre, Tappi 67 (8) (1984) 86.Google Scholar
  15. 15.
    A. Krishnagopalan and G. L. Simhard, ibid. 59 (12) (1976) 96.Google Scholar
  16. 16.
    M. Rigdahl and L. Salménj, J. Mater. Sci. 19 (1984) 2955.CrossRefGoogle Scholar
  17. 17.
    T. B. Lewis and L. E. Nielsen, J. Appl. Polym. Sci. 14 (1970) 1449.CrossRefGoogle Scholar
  18. 18.
    R. M. Jones, in “Mechanics of Composite Materials” (Scripta, Washington, 1975).Google Scholar
  19. 19.
    Z. Hashin, J. Solids Struct. 6 (1970) 539.CrossRefGoogle Scholar

Copyright information

© Chapman & Hall 1995

Authors and Affiliations

  • Roger Hagen
    • 1
  • Lennart Salmén
    • 1
  1. 1.STFI, (Swedish Pulp and Paper Research Institute)StockholmSweden

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