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Journal of Materials Science

, Volume 30, Issue 11, pp 2809–2820 | Cite as

Magnesium chloride — ethanol adducts

  • J. C. J. Bart
  • W. Roovers
Papers

Abstract

Some 60 addition compounds of the type MgCl2·nEtOH (6 ⩽ n ⩽ 1.4), formed between magnesium chloride and ethanol, have been prepared and were characterized by means of X-ray powder diffraction. The spectra were interpreted on the basis of a subset of nine characteristic diffraction patterns, and a range of (partially) new products, MgCl2·nEtOH with n=6, 4.5, 4, 3.33, 2.5, 1.67, 1.50 and 1.25, is described. MgCl2 adducts with alcohols can be converted to active olefin polymerization catalyst supports through the elimination of the alcohol molecules from the adducts by thermal desolvation.

Keywords

Polymer Alcohol Chloride Magnesium Adduct 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman & Hall 1995

Authors and Affiliations

  • J. C. J. Bart
    • 1
  • W. Roovers
    • 2
  1. 1.Department of Industrial ChemistryUniversity of MessinaMessinaItaly
  2. 2.DSM ResearchMD GeleenThe Netherlands

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