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Enzymatic mediated polymerization of functional aniline derivatives in nonaqueous media

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Abstract

Horseradish peroxidase (HRP) catalyzed H2O2-dependent oxidation and polymerization of p-aminophenylmethycarbinol (pAPMC), but not p-aminoacetophenone (pAAP) or other aniline derivative with elecron-withdrawing character. The effect of the H2O2 feed ratio on the polymerization was examined. Chemical structure was determined by IR and 1H, 13C NMR spectroscopic analysis. The p(pAMPC) formed primarily through a covalent bond between the benzilic carbons and the amino group of another pAPMC molecule. Thermal stability of p(pAPMC) was analyzed by DSC and TGA.

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References

  1. [1].

    Akkara JA, Salapu P, Kaplan DL (1992) Indian Journal of Chemestry 31B: 855

  2. [2].

    Dordick JS, Marletta MA, Klivanov AM (1987) Biotechnol. Bioeng 30: 31

  3. [3].

    Akkara JA, Senecal KJ, Kaplan DL (1991) J. Polym. Sci. Polym. Chem. 29: 561

  4. [4].

    Barabaran A, Klivanov AM (1981) Biotechnol. Bioeng. Symp. 11: 373

  5. [5].

    Nicell JA, Bewtra JK, Taylor AM, Biswas N, Pierre CS (1992) Wat. Sci. Tech. 25:157

  6. [6].

    Arias-Marin E, Romero J, Ledezma-Pérez A, Rios M (1996) Macromol. Report, A33 (SUPPLS. 3&4), 229

  7. [7].

    March J (1985) Advanced organic chemestry. Fourth edition. John Wiley & Sons, New York Chichester Toronto Brisbane Singapore

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Arias-Marín, E., Romero, J., Ledezma-Pérez, A. et al. Enzymatic mediated polymerization of functional aniline derivatives in nonaqueous media. Polymer Bulletin 37, 581–587 (1996). https://doi.org/10.1007/BF00296602

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Keywords

  • Oxidation
  • Polymerization
  • Spectroscopic Analysis
  • H2O2
  • Thermal Stability