Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Preparation of homo- and co-dimers of styrene derivatives using phosphate

Summary

Dimers were preferably obtained in the oligomerization of styrene derivatives by diphenyl hydrogen phosphate. The reaction was assumed to proceed through the formation of esters from the monomers and diphenyl hydrogen phosphate as intermediate. This assumption was confirmed by the fact that treatment of the esters with alternative styrene derivatives gave linear codimers.

This is a preview of subscription content, log in to check access.

References

  1. BRIGL, P. and H. MÜLLER: Ber. 72B, 2121 (1939)

  2. CALDER, I. C., W. Y. LEE and F. E. TRELOAR: Aust. J. Chem. 22, 2689 (1969)

  3. HIGASHIMURA, T. and N. NISHII: J. Polym. Sci. Polym. Lett. Ed., 15, 329 (1977)

  4. NISHII, N. and T. HIGASHIMURA: J. Polym. Sci. Polym. Lett. Ed., 15, 1179 (1977)

  5. ROSEN, M. J.: J. Org. Chem., 18, 1701 (1953)

  6. SAWAMOTO, M., T. MASUDA, N. HTSHII and T. HIGASHIMURA: J. Polym. Sci. Polym. Lett. Ed., 13, 279 (1975)

Download references

Author information

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Yamazaki, N., Nakahama, S., Yamaguchi, K. et al. Preparation of homo- and co-dimers of styrene derivatives using phosphate. Polymer Bulletin 3, 219–224 (1980). https://doi.org/10.1007/BF00291960

Download citation

Keywords

  • Hydrogen
  • Polymer
  • Phosphate
  • Ester
  • Oligomerization