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Kinetic evaluation of polyethylene autoxidation in melt

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Summary

This work proposes a description of the kinetics of polyethylene autoxidation in melt. The model takes into consideration the effect of neighbouring groups on the hydroperoxide decomposition. Using the proposed model, reliable constants can be calculated for the autoxidation of polyethylene.

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References

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Vágó, J., Fodor, Z., Nagy, T.T. et al. Kinetic evaluation of polyethylene autoxidation in melt. Polymer Bulletin 10, 559–565 (1983). https://doi.org/10.1007/BF00285376

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Keywords

  • Polymer
  • Polyethylene
  • Hydroperoxide
  • Material Processing
  • Kinetic Evaluation