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Intramolecular charge transfer complexes

20. Copolymers of acryloyl and methacryloyl-2′-hydroxyethyl-2-(N-phenothiazinyl)propionate with methacryloyl-2′-hydroxyethyl-3,5-dinitrobenzoate

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Summary

Radical copolymerization of acryloyl (PtA)- and methacryloyl (PtM)-2′-hydroxyethyl-2-(N-phenothiazinyl)propionate with methacryloyl-2′-hydroxyethyl-3,5-dinitrobenzoate proceeds through a mechanism which implies intermonomeric complex participation. There are indirect proofs that the intramolecular charge transfer complexes obtained present a total electron transfer phenomenon at high temperatures.

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References

  1. 1.

    C.I.Simioneacu, V.Percec and A.Natansohn, Polym.Bull., 2, 57 (1980)

  2. 2.

    V.Percec, A.Natansohn and C.I.Simionescu, Preprints Makro Mainz, 1, 345 (1979)

  3. 3.

    C.I.Simionescu, V.Percec and A.Natansohn, Polymer, 21, 417 (1980)

  4. 4.

    V.Percec, A.Natansohn and C.I.Simionescu, J.Macromol.Sci., Chem., A15. 405 (1981)

  5. 5.

    C.I.Simionescu, V.Percec and A.Natansohn, Polym.Bull., 2, 435 (1980)

  6. 6.

    C.I.Simionescu, V.Percec and A.Natansohn, Polym.Bull., 2, 441 (1980)

  7. 7.

    V.Percec, A.Natansohn, V.Barboiu, B.C.Simionescu and D.Gâlea, Polym.Bull., 2, 505 (1980)

  8. 8.

    C.I.Simionescu, V.Percec ana A.Natansohn, J.Polym.Sci., Polym.Chem.Ed., in press

  9. 9.

    C.I.Simionescu, V.Percec and A.Natansohn, Polym.Bull., 3, 529 (1980)

  10. 10.

    C.I.Simionescu, V.Percec and A.Natansohn, Polym.Bull., 3, 535 (1980)

  11. 11.

    C.I.Simionescu, A.Natansohn and V.Percec, Polym.Bull., 3, 543 (1980)

  12. 12.

    C.I.Simionescu, V.Percec and A.Natansohn, Polym.Bull., 3, 551 (1980)

  13. 13.

    V.Percec, A.Natansohn and C.I.Simionescu, Polym.Bull., 4, 247 (1981)

  14. 14.

    V.Percec, A.Natansohn and C.I.Simionescu, Polym.Bull., 4, 255 (1981)

  15. 15.

    C.I.Simionescu, V.Percec and A.Natansohn, Polym.Bull., 4, 623 (1981)

  16. 16.

    C.I.Simionescu, V.Percec and A.Natansohn, Polym.Bull., submitted

  17. 17.

    C.I.Simionescu, V.Percec and A.Natansohn, Polym.Bull., submitted

  18. 18.

    C.I.Simionescu, V.Percec and A.Natansohn, Polym.Bull., submitted

  19. 19.

    C.I.Simionescu, V.Percec and A.Natansohn, J.Polym.Sci., Polym.Chem.Ed., submitted

  20. 20.

    C.I.Simionescu, V.Percec, D.C.Tocaciu and L.Man, Polym.Bull., submitted

  21. 21.

    J.M.Pearson, S.R.Turner, and A.Ledwith, in “Molecular Associations”, R.Foster Ed., Academic Press, 1979, vol. 2, p. 79

  22. 22.

    F.Tüdös, T.Kelen, T.Foldes-Berezhnikh and B.Turcsanyi, J.Macromol.Sci., Chem., A10, 1513 (1976)

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Percec, V., Natansohn, A., Tocaciu, D.C. et al. Intramolecular charge transfer complexes. Polymer Bulletin 5, 247–253 (1981). https://doi.org/10.1007/BF00265172

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Keywords

  • Polymer
  • Propionate
  • Electron Transfer
  • Charge Transfer
  • Copolymerization