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Small-angle X-ray scattering study of halato-telechelic polybutadienes

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Summary

The small-angle X-ray scattering curves of carboxy-telechelic polymers exhibit very strong scattering at the lowest angles which points to the presence of large aggregates in the samples. Beyond the position of the main scattering maximum, common to all ionomers, a faint modulation is observed at a position corresponding to a second diffraction order. These observations are discussed with respect to other data in the litterature.

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Reference

  1. 1.

    R. Longworth and D.J. Vaughan, Am. Chem. Soc. Polym. Prepr., 9, 525 (1968).

  2. 2.

    C.L. Marx, D.F. Caulfield, S.L. Cooper, Macromol., 6, 344 (1973).

  3. 3.

    F.L. Binsbergen and G.F. Kroon, Macromolecules, 6, 344 (1973).

  4. 4.

    A. Moudden, A.M. Levelut, M. Pineri, J. Polym. Sci. Polym. Phys., 15, 1707 (1977).

  5. 5.

    M. Pineri, C. Meyer, A.M. Levelut, and M. Lambert, J. Polym. Sci. Polym. Phys., 12, 15 (1974).

  6. 6.

    D.G. Peiffer, R.A. Weiss and R.D. Rundberg, J. Polym. Sci. Polym. Phys., 20, 1503 (1982).

  7. 7.

    W.J. MacKnight, W.P. Taggart and R.S. Stein, J. Polym. Sci., 45, 113 (1974).

  8. 8.

    C.T. Meyer and M. Pineri, J. Polym. Sci. Polym. Phys., 16, 569 (1978).

  9. 9.

    D.J. Yarusso and S.L. Cooper, Macromolecules, 16, 1871 (1983).

  10. 10.

    W.J. MacKnight and T.R. Earnest, J. Polym. Sci. Macromol. Rev., 16, 41 (1981).

  11. 11.

    M. Fujimura, T. Hashimoto and H. Kawai, Macromolecules, 15, 136 (1982).

  12. 12.

    E.J. Roche, R.S. Stein, T.P. Russel and W.J. MacKnight, J. Polym. Sci. Polym. Phys., 18, 1497 (1980).

  13. 13.

    G. Broze, R. Jérôme, Ph. Teyssié and B. Gallot, J. Polym. Sci. Polym. Letters, 19, 415 (1981).

  14. 14.

    C.G. Vonk, J. Appl. Cryst., 4, 340 (1971).

  15. 15.

    G. Porod, Kolloid-Z, 124, 83 (1951).

  16. 16.

    J. Ledent, F. Fontaine and H. Reynaers, Symposium on Small Angle Scattering and Related Methods, Hamburg, 20–23 august (1984).

  17. 17.

    F. Fontaine, J. Ledent, R. Jérôme and H. Reynaers, Eight European Crystallographic Meeting, Liège, 8–12 august (1983).

  18. 18.

    C.E. Williams, Symposium on Polymer Research at Synchrotron Radiation Sources. Brookhaven National Laboratory (1984).

  19. 19.

    C.E. Williams, J. Horrion, R. Jerome, T.P. Russel and G. Vlaic, Symposium: Progess in X-Ray studies by Synchrotron Radiation. Strasbourg 1985. Abstract 3-2(B)3.

  20. 20.

    A. Guinier and G. Fournet, Small Angle Scattering of X-Rays, Wiley, New-York (1955).

  21. 21.

    E.J. Roche, R.S. Stein and W.J. MacKnight, Polym. Sci. Polym. Phys., 18, 1035 (1980).

  22. 22.

    J. Horrion, Ph.D. Thesis in preparation, University of Liège.

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Correspondence to F. Fontaine.

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Ledent, J., Fontaine, F., Reynaers, H. et al. Small-angle X-ray scattering study of halato-telechelic polybutadienes. Polymer Bulletin 14, 461–468 (1985). https://doi.org/10.1007/BF00263463

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Keywords

  • Polymer
  • Lower Angle
  • Large Aggregate
  • Diffraction Order
  • Polybutadiene