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“Starburst” polyarylamines and their semiconducting complexes as potentially electroactive materials

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Summary

Highly branched “starburst” polyarylamines were synthesized by repetitive condensations of 2,4dinitrofluorobenzene with anilines, followed by reduction. These starburst arylamines were complexed with iodine to form semiconducting products. The reduced arylamines were examined by cyclic voltammetry.

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References

  1. 1.

    G. Wegner in “Electronic Properties of Polymers and Related Compounds”, #63, H.Kuymay, M.Mehrig, S.Roth, Eds., Springer Verlag, Heidelberg (1985).

  2. 2.

    Honzl, J.; Ulbert, K.;Hadek, V.;Tlustakova, M.;Metalova, M. J. Polym. Sci. C 16,4465(1969).

  3. 3.

    Lantz, R.L., Obelliane, P. Bull. Soc. Chim. (France), 311(1956).

  4. 4.

    Tomalia, D.A.;Baker, H.;Dewald, J.;Hall, M.;Kallos, C.;Martin, S.;Roeck, J.;Ryder, J.;Smith, P. Polymer J. Japan 17, 117 (1985).

  5. 5.

    Tomalia, D.A.;Baker, H.;Dewald, J.;Hall, M.;Kallos, C.;Martin, S.;Roeck, J.;Ryder, J.;Smith, P. Macromolecules 19, 2466 (1986).

  6. 6.

    Suhr, H. Chem. Ber. 97,3268(1964).

  7. 7.

    Suhr, H. Chem. Ber. 97, 3277 (1964).

  8. 8.

    Van der Pauw, L.J. Philips Res. Repts 13, 1(1958).

  9. 9.

    “CRC Handbook of Chemistry and Physics”, 61st Edition, Robert C. Weast, Ed., CRC Press, Inc., Boca Raton, FL, F173–174(1980).

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Hall, H.K., Polis, D.W. “Starburst” polyarylamines and their semiconducting complexes as potentially electroactive materials. Polymer Bulletin 17, 409–416 (1987). https://doi.org/10.1007/BF00255612

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Keywords

  • Polymer
  • Iodine
  • Aniline
  • Cyclic Voltammetry
  • Material Processing