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Products of the anionic oligomerization of the pure 1-cyclohexene-1-carbonitrile and of its mixtures with the 3-cyclohexene-1-carbonitrile isomer

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Summary

Noncyclic unsaturated dimers and trimers are the principal products in the KOC(CH3)3 catalyzed oligomerization of the pure 1-eyclohexene, 1-carbonitrile, and of its mixtures with the 3-cyclohexene-1-carbonitrile isomer.

Pure isomeric dimers such as the cis and trans 1-(2′cyanocyclohexyl)-cyclohex 3-ene-carbonitrile were isolated from the raw reaction mixtures. Their configurations and conformations were investigated by IR and NMR.

Possible mechanisms of the oligo- and cooligo- merization are proposed.

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References

  1. MESSINA Go et al. : La Chimica e l'Industria, in press (1979)

  2. SHNALKE K.E. et al. : c.a. 85; 46265y (1976)

  3. VAN CAILLE. R.: Bull, Soc. Chim. Belg. 42, 419(1933)

  4. YANOVSKAYA L.A. and SHAKHIDAYATOV Kh.: Russ. Chemical Reviews 39, 865 (1970)

  5. BOOTH H.: Progress in NMR Spectroscopy, V5, p. 149, Pergamon P., 1962

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Messina, G., Cavalli, L. & Moraglia, R. Products of the anionic oligomerization of the pure 1-cyclohexene-1-carbonitrile and of its mixtures with the 3-cyclohexene-1-carbonitrile isomer. Polymer Bulletin 1, 603–612 (1979). https://doi.org/10.1007/BF00254138

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Keywords

  • Polymer
  • Oligomerization
  • Material Processing
  • Principal Product
  • Anionic Oligomerization