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Simultaneous reduction of perrhenate and nickel ions by hypophosphite

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Reduction of water by hypophosphite during Ni-P-Re alloy deposition proceeds in nearly the same proportion as that in the case of Ni-P deposition according to the mass spectrometric analysis of the gas evolved in deuterium-labelled electroless plating solutions. Perrhenate ion is reduced to metal rhenium as shown by the XPS analysis of the electrolessly deposited Ni-P-Re coating. Atomic hydrogen is expected to tkae part in perrhenate reduction at the catalyst surface resulting in a high hypophosphite efficiency in the overall electroless Ni-P-Re deposition process.

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Genutienė, I., Lenkaitienė, J., Jusys, Z. et al. Simultaneous reduction of perrhenate and nickel ions by hypophosphite. J Appl Electrochem 26, 118–120 (1996). https://doi.org/10.1007/BF00248197

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  • Hydrogen
  • Nickel
  • Atomic Hydrogen
  • Deposition Process
  • Rhenium