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Geochemical criteria for distinguishing magmatic and metasomatic albite-enrichment in granitoids — examples from the Ta-Li granite Yichun (China) and the Sn-W deposit Tikus (Indonesia)

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Two examples of albite-rich granitoids of different genesis are discussed: the Ta-Li granite at Yichun (China) exhibits dominantly igneous textures, and the sodium-enrichment zone in biotite granite of the Sn-W deposit at Tikus is characterized by metasomatic textures. The Yichun stock shows a magmatic evolution from biotite-muscovite granite to lepidolite granite with an increase of Na2O and F concentrations and a decrease of CaO and Sr concentrations. The composition of the different granite phases is close to pseudoternary minima in the haplogranite-H2O(-Li-F) system. The composition of the F-rich albitization zone at Tikus deviates strongly from the pseudoternary minima and shows a tendency to become monomineralic (nearly pure albitite). CaO and Sr concentrations are increased or remain unchanged with respect to the unaltered biotite granite at Tikus. Albitization produced by fluid-rock interaction in F-rich systems is characterized by that CaO or Sr released by the breakdown of plagioclase in the granite protolith, are fixed in newly formed fluorite or albite, respectively.

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  1. Bazarov, L.S., Kosals, Y.A., Senina, V.A., Gordeyeva, V.I. (1973) Temperatures of crystallization of zoned quartz phenocrysts in apogranite. Doklady Akad. Nauk SSSR 205:111–113

  2. Beus, A.A., Severov, E.A., Sitnin, A.A., Subbotin, K.D. (1962) Albitized and greisenized granite (apogranite) (in Russian). Moscow, Izd. Akad. Nauk SSSR, 195 p.

  3. Beus, A.A. (1966) Geochemical analysis of the phenomena of high-temperature post-magmatic metasomatism and ore-formation in granitoids. In: Vinogradov, A.P. (ed) Chemistry of the Earth's Crust, Vol. 1. Israel Program for Scientific Translations, Jerusalem, pp. 186–204

  4. Beus, A.A. (1970) Metasomatic zoning in deposits of rare elements of the albitite formation. In: Pouba, Z., Štemprok, M. (eds) Problems of Hydrothermal Ore Deposition. E. Schweizerbart'sche Verlagsbuchhandlung, Stuttgart, pp. 325–329

  5. Boguslavskiy, I.S., Kalenov, A.D., Egel', L.Y. (1966) Metasomatic albitite found for the first time in the MPR. Doklady Akad. Nauk SSSR 168:159–162

  6. Brown, G.E., Jr., Ewing, R.C. (1986) Introduction to the Jahns memorial issue. Am. Mineral. 71:233–238

  7. Burnham, C.W., Nekvasil, H. (1986) Equilibrium properties of granite pegmatite magmas. Am. Mineral. 71:239–263

  8. Černý, P., Trueman, D.L., Ziehlke, D.V., Goad, B.E., Paul, B.J. (1981) The Cat Lake-Winnipeg River and the Wekusko Lake pegmatite fields, Manitoba. Manitoba Department of Energy and Mines, Economic Geology Report ER80-1, 216 p.

  9. Chappell, B.W., White, A.J.R. (1984) I- and S-type granites in the Lachlan fold belt, south-eastern Australia. International Symposium Geology of Granites and Their Metallogenetic Relations, Nanjing, China, October 26–30, 1982, Proceedings, pp. 87–101

  10. Ginzburg, A.I., Fel'dman, L.G. (1977) Deposits of tantalum and niobium. In: Smirnov, V.I. (ed) Ore deposits of the USSR, Vol. 3. Pitmann, London, pp. 372–424

  11. Glyuk, D.S., Trufanova, L.G., Bazarova, S. B. (1980) Phase relations in the granite-H2O-LiF system at 1000 kg f/cm2. Geochemistry International 17: no. 5, pp. 35–48

  12. Groothoff, L.A. (1916) De primaire tinertsafzettingen van Billiton. Proefschrift, Delft, S-Gravenhage, Mouton, 103 p.

  13. Iiyama, J.T. (1972) Fixation des éléments alcalinoterreux, Ba, Sr et Ca dans les feldspaths — étude expérimentale. Proceedings 24th International Geological Congress, section 10, pp. 122–130

  14. Jahns, R.H., Tuttle, O.F. (1963) Layered pegmátite-aplite intrusives. Mineralogical Soc. America, Special Paper 1:78–92

  15. Jahns, R.H., Burnham, C.W. (1969) Experimental studies of pegmatite genesis. I. A model for the derivation and crystallization of granitic pegmatites. Econ. Geol. 64:843–864

  16. Jahns, R.H. (1982) Internal evolution of pegmatite bodies. In: Černý, P. (ed) Granitic pegmatites in science and industry. Short Course Handbook Mineralogical Association Canada 8:293–327

  17. James, R.S., Hamilton, D.L. (1969) Phase relations in the system NaAlSi3O8-KAlSi3O8-CaAl2O8-SiO2. Contr. Mineral. Petrol. 21:111–141

  18. Kovalenko, V.I., Kuz'min, M.I., Letnikov, F.A. (1970) Magmatic origin of lithium- and fluorine-bearing rare-metal granite. Doklady Akad. Nauk SSSR 190:189–192

  19. Kovalenko, V.I. (1978) The genesis of rare metal granitoids and related ore deposits. In: Štemprok, M., Burnol, L., Tischendorf, G. (eds) Metallization associated with acid magmatism, Vol. 3. Geological Survery, Prague, pp. 235–247

  20. Lehmann, B., Harmanto (1990) Large-scale tin depletion in the Tanjungpandan tin granite, Belitung Island, Indonesia. Econ. Geol. 85:99–111

  21. London, D. (1986) Magmatic-hydrothermal transition in the Tanco rare-element pegmatite: Evidence from fluid inclusions and phase-equilibrium experiments. Am. Mineral. 71:376–395

  22. London, D., Morgan, VI, G.B., Hervig, R.L. (1989) Vapor-undersaturated experiments with Macusani glass + H2O at 200 MPa, and the internal differentiation of granitic pegmatites. Contrib. Mineral. Petrol. 102:1–17

  23. Lu, H.Z., Shi, J.X., Yu, C.M. (1975) Temperatures of petrogenesis and metallogenesis for a certain tantalum-niobium-bearing granite (in Chinese). Geochimica 3:210–221

  24. Manning, D.A.C. (1981) The effect of fluorine on liquidus phase relationships in the system Qz-Ab-Or with excess water at 1 kb. Contrib. Mineral. Petrol. 76:206–215

  25. Martin, J.S. (1983) An experimental study of the effects of lithium on the granite system. Proc. Ussher Society 5:part 4, pp. 417–420

  26. Norton, J.J. (1983) Sequences of mineral assemblages in differentiated granitic pegmatites. Econ. Geol. 78:854–874

  27. Pollard, P.J. (1988) Mineralogical and geochemical features of raremetal granites. 5th International Symposium Tin/Tungsten Granites in Southeast Asia and the Western Pacific IGCP Project 220, October 17–19, 1988 (abstracts). Shimane University, Matsue (Japan), pp. 131–133

  28. Pollard, P.J., Taylor, R.P., Shouxi, H., Taylor, R.G. (1989) Vertical fractionation in rare-metal granites: preliminary results from the Yichun Li-Nb-Ta mine, Jiangxi province, South China. Abstracts IGCP project no. 282 First meeting Rare metal granitoids, Nanijing, China, November 10–13, 1989, pp. 44

  29. Sabet, A.H., Tsogoev, V.B., Sarin, L.P., Azazi, S.A., El Bedewi, M.A., Ghobrial, G.A. (1976) Tin-tantalum deposit of Abu Dabbab. Annals Geol. Surv. Egypt 6:93–117

  30. Schwartz, M.O., Askury, A.K. (1989) Geological, geochemical, and fluid inclusion studies of the tin granites from the Bujang Melaka pluton, Kinta Valley, Malaysia. Econ. Geol. 84:751–779

  31. Schwartz, M.O., Surjono (1990) Greisenization and albitization at the Tikus tin-tungsten deposit, Belitung, Indonesia. Econ. Geol. 85:691–713

  32. Severov, E.A. et al. (1977) A new type of tantalum-bearing apogranite. Intern. Geol. Rev. 19:507–510

  33. Sitnin, A.A. (1970) On the mobilization of Ta, Nb, Li, Rb, Cs, Be, Sn, W in the process of high-temperature metasomatism of certain granitoids. In: Pouba, Z., Štemprok, M. (eds) Problems of hydrothermal ore deposition. E. Schweizerbart'sche Verlagsbuchhandlung, Stuttgart, pp. 348–351

  34. Stern, L.A., Brown, G.E., Jr., Bird, D.K., Jahns, R.H. (1986) Mineralogy and geochemical evolution of the Little Three pegmatite-aplite layered intrusive, Ramona, California. Am. Mineral. 71:406–427

  35. Sun, S.H., Yu, J. (1989) Ta-granite microstructure. Abstracts IGCP project no. 282 First meeting Rare metal granitoids, Nanjing, China, November 10–13, 1989, pp. 55–56

  36. Suryono, Clarke, M.C.G. (1982) Primary tungsten occurrences in Sumatra and the Indonesian Tin Islands. Tungsten Geology Symposium, Jiangxi, China, ESCAP RMRDC, Bandung, Indonesia, Geological Publishing House, Beijing, China, pp. 217–231

  37. Tu, G. (1989) Differences between granite-related Ta and Nb mineralizations as well as Sn and W mineralizations in China. Abstracts IGCP project no. 282 First meeting Rare metal granitoids, Nanjing, China, November 10–13, 1989, pp. 60–61

  38. Tuttle, O.F., Bowen, N.L. (1958) Origin of granite in the light of experimental studies in the system NaAlSi3O8-KAlSi3O8-SiO2-H2O. Geol. Soc. America, memoir 74:153

  39. Vinogradov, A.P. (1962) Average contents of chemical elements in the principal types of igneous rocks of the Earth's crust. Geochemistry 7:641–664

  40. Wing-Easton, N. (1937) The tin ores of Banca, Billiton and Singkep, Malay Archipelago. Part II. Econ. Geol. 32:154–182

  41. Xu, K.Q., Zhu, J.C., Xu, S.J. (1987) Geological environments and geochemical differences of W, Sn, Nb/Ta-bearing granites and their related mineral deposits in South China. Report on the 4th Int. Symp. IGCP Project 220 (abstracts), October 21–26, 1987, Guilin (China), Nonferrous Metals Society of China, Research Institute of Geology for Mineral Resources, p. 194–197

  42. Xu, S.J., Yin, L. (1989) Geology and geochemistry of Ta(Nb)-mineralized granites in South China, and their petrogenetic significance. Abstracts IGCP project no. 282 First meeting Rare metal granitoids, Nanjing, China, November 10–13, 1989, pp. 75–76

  43. Yin, L., Yan, H. (1989) Fractional crystallization an important rock-forming model for Na, Nb-bearing granites. Abstracts IGCP project no. 282 First meeting Rare metal granitoids, Nanjing, China, November 10–13, 1989, pp. 82–83

  44. Zhang, J.T., Xia, W.H. (1989) Glomerocryst of albite in ore-bearing granite massif 414 and its genetic significance. Abstracts IGCP project no. 282 First meeting Rare metal granitoids, Nanjing, China, November 10–13, 1989, pp. 95–96

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Schwartz, M.O. Geochemical criteria for distinguishing magmatic and metasomatic albite-enrichment in granitoids — examples from the Ta-Li granite Yichun (China) and the Sn-W deposit Tikus (Indonesia). Mineral. Deposita 27, 101–108 (1992). https://doi.org/10.1007/BF00197092

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  • Mineral Resource
  • Indonesia
  • Biotite Granite
  • Magmatic Evolution
  • Geochemical Criterion