Abstract
A mechanism is suggested for the heterogeneous catalytic epoxidation of allyl chloride with hydrogen peroxide in methanol. The kinetics of allyl chloride oxidation into epichlorohydrin in the presence of extruded titanium silicalite has been investigated. A kinetic model of the process has been derived from experimental data, and the activation energies of the target and side reactions, the rate constants of the reactions, and the adsorption equilibrium constant have been determined. The allyl chloride epoxidation process has been tested using a bench-scale continuous apparatus, and the adequacy of the kinetic model has been estimated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Epichlorohydrin: production and market survey, Evraz. Khim. Rynok, 2010, no. 3, p. 63.
Paken, A.M., Epoksidnye soedineniya i epoksidnye smoly (Epoxides and Epoxy Resins), Leningrad: Goskhimizdat, 1962.
Khlororganicheskie produkty: Spravochnik fizikokhimicheskikh velichin (Chlorinated Organics: A Handbook of Physical and Chemical Data), Moscow: MITKhT, 2013.
Epicerol Process: Growing Green, Brussels: Solvay Chemicals, 2008.
Dmitriev, G.S. and Zanaveskin, L.N., Khim. Prom-st. Segodnya, 2012, no. 3, p. 8.
Gao, H., Lu, G., Suo, J., and Li, S., Appl. Catal., A, 1996, vol. 138, no. 1, p. 27.
Kumar, R.P. and Kumar, R., Catal. Commun., 2007, no. 8, p. 379.
US Patent 5965754, 1999.
US Patent 2001020105, 2001.
Xia, H., Zhou, C.-H., Tong, D., Chen, J., Yu, W., and Liu, S., Appl. Clay Sci., 2011, vol. 53, p. 279.
Li, W., Ying, Z., and Zhentao, M., J. Chem. Technol. Biotechnol., 2007, vol. 82, p. 414.
RF Patent 2422360, 2011.
Danov, S.M., Sulimov, A.V., Kolesnikov, V.A., and Ovcharov, A.A., Kinet. Catal., 2013, vol. 54, no. 2, p. 193.
US Patent 4410501, 1983.
Clerici, M.G., Bellussi, G., and Romano, U., J. Catal., 1991, vol. 129, no. 1, p. 159.
Sulimov, A.V., Danov, S.M., and Ovcharova, A.V., Russ. J. Appl. Chem., 2009, vol. 82, no. 11, p. 1991.
Schumb, W.C., Satterfield, C.N., and Ventworth, R.L., Hydrogen Peroxide, New York: Reinhold, 1955.
Danov, S.M., Sulimov, A.V., Kolesnikov, V.A., and Ovcharova, A.V., Kinet. Catal., 2011, vol. 52, no. 6, p. 793.
Luchinskii, G.P., Khimiya titana (Titanium Chemistry), Moscow: Khimiya, 1971.
Kafarov, V.V., Metody kibernetiki v khimii i khimicheskoi tekhnologii (Methods of Cybernetics in Chemistry and Chemical Engineering), Moscow: Khimiya, 1985.
Bottino, A., Capannelli, G., and Comite, A., Chem. Eng. J., 2003, vol. 94, no. 1, p. 11.
Sridevi, U., Bhaskar Rao, B.K., and Pradhan, N.C., Chem. Eng. J., 2001, vol. 83, no. 3, p. 185.
Lebedev, N.N., Manakov, M.N., and Shvets, V.F., Teoriya khimicheskikh protsessov osnovnogo organicheskogo i neftekhimicheskogo sinteza (Theory of Chemical Processes in Bulk Organic and Petrochemical Syntheses), Moscow: Khimiya, 1984.
Zhorov, Yu.M., Kinetika promyshlennykh organicheskikh reaktsii (Kinetics of Industrially Important Organic Reactions), Moscow: Khimiya, 1989.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.V. Sulimov, S.M. Danov, A.V. Ovcharova, A.A. Ovcharov, V.R. Flid, 2014, published in Kinetika i Kataliz, 2014, Vol. 55, No. 6, pp. 730–740.
Rights and permissions
About this article
Cite this article
Sulimov, A.V., Danov, S.M., Ovcharova, A.V. et al. Kinetics of allyl chloride epoxidation with hydrogen peroxide catalyzed by extruded titanium silicalite. Kinet Catal 55, 712–721 (2014). https://doi.org/10.1134/S0023158414060135
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0023158414060135