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Hydrogen bonding and protonation in the interaction of garbonyl complexes of transition metals with HCl and perfluorotertiary butanol

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It has been established that HCl is capable of H-bond formation with carbonyl π-complexes of transition metals via the oxygen of the carbonyl group in the presence of a metal atom in liquid xenon at low temperatures.

  2. 2.

    The protonation of carbonyl complexes of transition metals via the metal atom may occur through a stage of hydrogen bond formation via the oxygen atom of the CO group.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    B. V. Lokshin, S. G. Kazaryan & A. G. Ginzburg

Authors
  1. B. V. Lokshin
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  2. S. G. Kazaryan
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  3. A. G. Ginzburg
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 333–338, February, 1988.

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Lokshin, B.V., Kazaryan, S.G. & Ginzburg, A.G. Hydrogen bonding and protonation in the interaction of garbonyl complexes of transition metals with HCl and perfluorotertiary butanol. Russ Chem Bull 37, 257–261 (1988). https://doi.org/10.1007/BF00957421

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  • DOI: https://doi.org/10.1007/BF00957421

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