Summary
Living cationic copolymerization of 11-[(4-cyano-4′-biphenyl)oxy]undecanyl vinyl ether (6-11) with 2-vinyloxyethyloxy methacrylate (16-2) leads to reactive copolymers poly[(6-11)-co-(16-2)]X/Y (where X/Y is the mol ratio between the two monomers in copolymer) containing methacryloyl side groups. Upon thermal crosslinking via the polymerization of their methacryloyl side groups, the copolymers with X/Y=5/5 to 9/1 lead to liquid crystalline networks displaying a SA mesophase. These results have demonstrated that a shorter spacer in the reactive bifunctional monomer 16-2 than in the mesogenic 6-11 monomer leads to networks with broader range of mesomorphism than those derived from a reactive monomer containing a spacer length equal to that of the mesogenic monomer.
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V. Percec and Q. Zheng, Polym. Bull., submitted.
V. Percec, M. Lee and H. Jonsson, Polym. Sci. Polym. Chem. Ed., 29, 327(1991);
V. Percec and M. Lee, Macromolecules, 24, 1017(1991)
V. Percec and M. Lee, J. Macromol. Sci.-Chem., A28, 651(1991)
V. Percec, M. Lee and C. Ackerman, Polymer, 33, 703(1992)
V. Percec and M. Lee, Macromolecules, 24, 2780(1991)
V. Percec, Q. Zheng and M. Lee, J. Mater. Chem., 1, 611(1991)
V. Percec, Q. Zheng and M. Lee, J. Mater. Chem., 1, 1015(1991)
V. Percec and Q. Zheng, J. Mater. Chem., 2, 475(1992)
V. Percec and Q. Zheng, J. Mater. Chem., in press.
V. Percec and M. Lee, Polymer, 32, 2862(1991)
V. Percec and M. Lee, Polym. Bull., 25, 123(1991)
V. Percec and M. Lee, Polym. Bull., 25, 131(1991)
V. Percec and M. Lee, Macromolecules, 24, 4963(1991)
V. Percec and M. Lee, J. Mater. Chem., 1, 1007(1991)
V. Percec, M. Lee and Q. Zheng, Liq. Cryst., in press.
V. Percec and D. Tomazos, Adv. Mater., in press.
V. Percec and D. Tomazos, “Molecular Engineering of Liquid Crystalline Polymers” in “Comprehensive Polymer Science”, Supplement Vol. 1, G. Allen and J. C. Bevington Eds., Pergamon Press, Oxford, 1992, in press.
V. Percec and M. Lee, J. Mater. Chem., 2, 617(1992).
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This paper is part 27 in the series: Molecular engineering of liquid-crystalline polymers by living polymerization. Part 26: V. Percec, Q. Zheng: Polym. Bull., previous paper in the issue
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Percec, V., Zheng, Q. Thermally reactive liquid crystalline copolymers based on 11-[(4-cyano-4′-biphenyl)oxy]undecanyl vinyl ether and 2-vinyloxyethyloxy methacrylate. Polymer Bulletin 29, 493–500 (1992). https://doi.org/10.1007/BF00296709
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DOI: https://doi.org/10.1007/BF00296709