Abstract
The purpose of this chapter is to gather in one place some of the basic considerations that apply to the engineering techniques and unit operations that are important in the chloralkali process. Thus, the chapter begins with a discussion of material and energy balances (Section 10.2). These are basic to all of chemical engineering and are used implicitly throughout this book. Here, we present some of the fundamentals. Section 10.3 then covers current distribution. This is uniquely important in electrochemical processing. The presentation discusses methods of predicting and determining the distribution of current in electrochemical reactors of different kinds.
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References
F. Hine, Electrode Processes and Electrochemical Engineering, Plenum Press, New York (1985), p. 162.
HSC Chemistry Software, Versions 3 and 4, Outokumpu Research Oy, Espoo (1999).
V.A. Ettel, Electrometallurgy and Energy Crunch. In Energy Considerations in Electrolytic Processes, Society of Chemical Industry, London, (1980), p. 1.
T. Sugino and K. Aoki, J. Electrochem. Soc, Japan 27(1–3), E17 (1959).
R.L. LeRoy, C.T. Brown, and D.J. LeRoy, J. Electrochem. Soc. 127, 1954 (1980).
R.L. LeRoy, J. Electrochem. Soc. 130, 2159 (1983).
T.R. Beck and R.T. Ruggeri, Energy Consumption and Efficiency of Industrial Electrochemical Processes. In H. Genscher and C.W. Tobias (eds), Advances in Electrochemistry and Electrochemical Engineering, Vol. 12, John Wiley & Sons, New York (1981), p. 263.
Abam Engineers, Inc., Final Report on Process Engineering and Economic Evaluations of Diaphragm and Membrane Chlorine Cell Technologies, Contract #31-109-38-5474, Report; ANL/OEPM-80-9, Argonne National Laboratories, Argonne, IL (1980).
References
F. Hine, Electrode Processes and Electrochemical Engineering, Plenum Press, New York (1985), p. 313.
C. Kasper, Trans. Electrochem. Soc. 77, 353, 365 (1939); 78, 131, 147 (1940).
C. Wagner, J. Electrochem. Soc. 98, 115 (1951).
J.T. Weber, J. Electrochem. Soc. 101, 271 (1954); 102, 344, 420 (1955); 103, 64, 138 (1956).
F. Hine, S. Yoshizawa, and S. Okada, J. Electrochem. Soc. 103, 186 (1956).
F. Hine, Kogyo Kakaku Zasshi (J. Chem. Soc. Japan, Industrial Chemistry Section) 56, 875 (1956).
E.T. Whittaker and G.N. Watson, A Course of Modern Analysis, 4th Edition, Cambridge University Press, Cambridge (1927), p. 448.
K. Kojima, Research Reports of the Faculty of Engineering, Niigata University, 13, 183 (1964); 14, 117 (1965); 14, 131 (1965).
R.N. Fleck, Master’s Thesis, University of California (1964).
J.A. Klingert, S. Lynn, and C.W. Tobias, Electrochim, Acta 9, 297 (1961).
G.A. Prentice and C.W. Tobias, J. Electrochem. Soc. 129, 72 (1982).
J.S. Newman, Electrochemical Systems, Prentice-Hall, Englewood Cliffs, NJ (1973), p. 340.
S. Komagata, Researches of the Electrotechnical Laboratory, Ministry of Communications, Tokyo, No. 294 (1930).
C.W. Tobias and R. Wijsman, J. Electrochem. Soc. 100, 459 (1953).
C.-P. Chen and T.V. Bommaraju, Investigation of Cathode Side Screen Corrosion, in 13th Annual Chlorine/Chlorate Seminar, ELTECH Systems Corporation, Cleveland, OH (1997).
E.I. Baucom, Nafion® Membranes for the 1990s. In T.C. Wellington (ed.), Modern Chlor-Alkali Technology, vol. 5, Elsevier Applied Science, London (1992), p. 131.
References
Kagakukikai no Riron to Keisan (Theory and Calculation of Chemical Equipment), S. Kamei (ed.), Sangyo Tosho Publ. Co., Tokyo (1959), p. 58.
Chemical Engineers Handbook, R.H. Perry and D.W. Green (eds), 7th edition, MaGraw Hill Book Co., New York (1997), pp. 6–22.
Crane Catalogue 60, Crane Company, Chicago (1960), pp. 422–430.
Flow of Fluids Through Valves, Fittings and Pipes, Technical Paper #410, Crane Company, New York, (1976).
F. Hine, Electrode Processes and Electrochemical Engineering, Plenum Press, New York (1985), p. 64.
Kagakukikai no Riron to Keisan (Theory and Calculation of Chemical Equipments), S. Kamei (ed.), Sangyo Tosho Publ. Co., Tokyo (1959), p. 42.
Chemical Engineers Handbook, R.H. Perry, C.H. Chilton, and S.D. Kirkpatrick (eds), 5th edition, Section 5, McGraw Hill Book Co., New York (1968).
D.S. Scott, Properties of Cocurrent Gas-Liquid Flow, In T.B. Drew, J.W. Hoopes, Jr., and T. Vermeulen (eds), Advances in Chemical Engineering, vol. 4, Academic Press, New York (1963), p. 199.
G.W. Glovier and K. Aziz, The Flow of Complex Mixtures in Pipes, Robert E. Krieger Publishing Co., Huntington, NY (1977), p. 292.
D.Q. Kern, Hydrocarbon Processing 48(10), 105 (1969).
W.J. Davis, Brit. Chem. Eng., 8 (1963).
P.D. Hills, Chem. Eng. 90(18), 111 (1983).
References
T.H. Chilton and A.P. Colburn, Ind. Eng. Chem. 27, 255 (1935).
C.R. Robinson and E.R. Gilliland, Elements of Fractional Distillation, 4th edition, McGraw-Hill Book Co., New York (1950), p. 108.
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O’Brien, T.F., Bommaraju, T.V., Hine, F. (2005). Chemical Engineering Principles. In: Handbook of Chlor-Alkali Technology. Springer, Boston, MA. https://doi.org/10.1007/0-306-48624-5_10
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