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Die viscosimetrische Molekulargewichtsbestimmung von Polymeren

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Fortschritte Der Hochpolymeren-Forschung

Part of the book series: Advances in Polymer Science ((POLYMER,volume 3/1))

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Literatur

  1. Alexander, P., and K. A. Stacy: The light-scattering and non-Newtonian viscosity of high molecular weight polymethacrylic acid. Trans. Faraday Soc. 51, 299 (1955).

    Article  CAS  Google Scholar 

  2. Altgelt, K., u. G. V. Schulz: Bestimmung der makromolekularen Konstanten von Naturkautschuk III. Makromol. Chem. 36, 209 (1960).

    Article  CAS  Google Scholar 

  3. Archibald, W. J.: A demonstration of some new methods of determining molecular weights from the data of the ultrazentrifuge. J. Phys. Chem. 51, 1204 (1947).

    Article  CAS  Google Scholar 

  4. Arond, L. M., and H. P. Frank: Molecular weight, molecular weight distribution and molecular size of a native dextran. J. Phys. Chem. 58, 953 (1954).

    Article  CAS  Google Scholar 

  5. Atkins, J. T., L. T. Muus, C. W. Smith and E. T. Pieski: The molecular structure of polyethylene. IX. Weight-average molecular weight and intrinsic viscosity of linear polyethylene. J. Am. Chem. Soc. 79, 5089 (1957).

    Article  CAS  Google Scholar 

  6. Badger, R. M., and R. H. Blaker: The investigation of the properties of nitrocellulose molecules in solution by light-scattering methods. II. J. Phys. Chem. 53, 1056 (1949).

    Article  CAS  Google Scholar 

  7. Basu, S., and H. B. Roy: Determination of the molecular weight of benzylcellulose. J. Sci. Ind. Res. 11 B, 94 (1952).

    Google Scholar 

  8. Batzer, H.: Über lineare Polyester. Makromol. Chem. 5, 5 (1950).

    Article  CAS  Google Scholar 

  9. u. A. Möschle: Über die Eigenschaften von Mischpolyamiden in Lösung und im festen Zustand. Makromol. Chem. 22, 195 (1957).

    CAS  Google Scholar 

  10. Bawn, C. E. H., E. S. Hill and M. A. Wajid: The osmotic pressure of dilute solutions of polystyrene and polyisobutene. Trans. Faraday Soc. 52, 1651 (1956).

    CAS  Google Scholar 

  11. R. D. Patel: Viscosity and chain dimensions of polyisobutene and polystyrene in mixed sovents. Trans. Faraday Soc. 52, 1669 (1956).

    CAS  Google Scholar 

  12. Berkowitz, J. B., M. Yamin and R. M. Fuoss: The Flory constants for poly-4-vinylpyridine in ethanol. J. Polymer Sci. 28, 69 (1958).

    CAS  Google Scholar 

  13. Bier, G., u. H. Krämer: Beitrag zur Struktur von Polyvinylchlorid. Makromol. Chem. 18/19, 151 (1950).

    Google Scholar 

  14. Polymerisation von Vinylchlorid und Struktur von Polyvinylchlorid. Kunststoffe 46, 498 (1956).

    CAS  Google Scholar 

  15. Billmeyer, F. W.: The molecular structure of polyethylene. III. Determination of long chain branching. J. Am. Chem. Soc. 75, 6118 (1953).

    Article  CAS  Google Scholar 

  16. C. B. De Than: Dissymmetry of molecular light scattering in polymethyl methacrylates. J. Am. Chem. Soc. 77, 4763 (1955).

    Article  CAS  Google Scholar 

  17. Bischoff, J., and V. Desreux: Properties of dilute solutions of polymethylmethacrylate. II. J. Polymer Sci. 10, 79 (1953).

    Google Scholar 

  18. Bisschops, J.: Viscosity, diffusion and sedimentation of polyacrylonitrile solution. Polymer Sci. 17, 81 (1954).

    Google Scholar 

  19. Booth, G. C., and V. Gold: Molecular weight studies of dextran. J. Chem. Soc. (London) 1956, 3380.

    Google Scholar 

  20. Boyes, A. G., and U. P. Strauss: Light scattering and viscosity studies on poly-4-vinylpyridine. J. Polymer Sci. 22, 463 (1956).

    CAS  Google Scholar 

  21. Brinkman, H. C.: Calculation of the viscosity and the sedimentation constant for solutions of large chain molecules taking into account the hampered flow of the solvent through these molecules. Physica 13, 447 (1947); Appl. Sci. Res. (B) 1, 27, 81 (1947); 2, 190 (1949).

    Article  CAS  Google Scholar 

  22. Bueche, A. M.: Dimensions of coiling polymer molecules from viscosity and light scattering. J. Am. Chem. Soc. 71, 1452 (1949).

    CAS  Google Scholar 

  23. Cantow, H. J.: Die Bestimmung der Molekulargewichtsverteilung in der Ultrazentrifuge bei der θ-Temperatur. Makromol. Chem. 30, 169 (1959).

    CAS  Google Scholar 

  24. Cantow, M., G. Meyerhoff u. G. V. Schulz: Verzweigungsgrad und Viscositätszahl bei Polystyrolen. Makromol. Chem. 49, 1 (1961).

    Article  CAS  Google Scholar 

  25. Carter, W. C., R. L. Scott and M. Magat: The viscosity-molecular weight relation for natural rubber. J. Am. Soc. 68, 1480 (1946).

    Article  CAS  Google Scholar 

  26. Chiang, R.: Light scattering on dilute solutions of polypropylene. J. Polymer Sci. 28, 235 (1958).

    Google Scholar 

  27. Chiang, R.: Comments on intrinsic viscosity weight average molecular weight relationships for polyethylene. J. Polymer Sci. 36, 91, 155 (1959).

    CAS  Google Scholar 

  28. Chinai, S. N.: Poly-n-hexyl methacrylate. IV. Dilute solution properties by viscosity and light scattering. J. Polymer Sci. 25, 413 (1957).

    CAS  Google Scholar 

  29. C. W. Bondurant: Polymethyl methacrylate, light scattering study in an ideal solvent. J. Polymer Sci. 22, 555 (1956).

    CAS  Google Scholar 

  30. R. A. Guzzi: Poly-n-butyl-methacrylate. III. Dilute solution properties by viscosity and light scattering. J. Polymer Sci. 21, 417 (1956).

    CAS  Google Scholar 

  31. Poly-n-lauryl methacrylate. V. Dlilute solution properties by viscosity and light scattering. J. Polymer Sci. 41, 475 (1959).

    CAS  Google Scholar 

  32. , J. D. Matlack, A. L. Resnick and R. J. Samuels: Polymethyl methacrylate: Dilute solution properties by viscosity and light scattering. J. Polymer Sci. 17, 391 (1955).

    CAS  Google Scholar 

  33. , A. L. Resnick and H. T. Lee: Poly-n-octyl methacrylate. V. Dilute solution properties by viscosity and light scattering. J. Polymer Sci. 33, 471 (1951).

    Google Scholar 

  34. R. J. Samuels: Polyethyl methacrylate. II. Dilute solution properties by viscosity and light scattering. J. Polymer Sci. 19, 463 (1956).

    CAS  Google Scholar 

  35. , P. C. Scherer, C. V. Bondurant and D. W. Levi: Dilute solution studies on polystyrene by light scattering and viscosity. J. Polymer Sci. 22, 527 (1956).

    CAS  Google Scholar 

  36. , and D. M. Levi: Molecular weight of polyvinyl acetate by light scattering and Viscosity techniques. J. Polymer Sci. 17, 117 (1955).

    CAS  Google Scholar 

  37. R. J. Valles: Comparison of unperturbed molecular parameters of methacrylate polymers. J. Polymer Sci. 39, 363 (1959).

    CAS  Google Scholar 

  38. Chirico, A. D.: Ricerce chimico-fisiche su soluzioni di policarbonato in chloroformio. Chim. e ind. (Milan) 42, 248 (1960).

    Google Scholar 

  39. Ciampa, G., u. H. Schwindt: Zur viskosimetrischen Molekulargewichtsbestimmung des Polyvinylchlorids. Makromol. Chem. 21, 169 (1956).

    Article  CAS  Google Scholar 

  40. Ciferri, A., M. Kryszewski et G. Weil: Étude par diffusion de la lumière et viscosimetrie du bromure de polyvinyle en solution. J. Polymer Sci. 167 (1958).

    Google Scholar 

  41. , u. H. Lauretti: Die Viscosität von Polyvinylbromid in einem idealen Lösungsmittel. Ann. Chim. (Roma) 48, 198 (1958).

    CAS  Google Scholar 

  42. Claesson, S., W. Bergmann u. G. Jayme: Über Sedimentations-und Diffusionsmessungen an in alkalischen Eisen-Weinsäure-Natrium-Komplex-(EWNN)-Lösungen gelöster Cellulose. Svensk Papperstidn. 62, 141 (1959).

    CAS  Google Scholar 

  43. U. Lohmander: Non-Newtonian flow of macromolecular solutions studied by capillary viscometry with a million fold change in the velocity gradient. Makromol. Chem. 44–46, 461 (1961).

    Google Scholar 

  44. Cleland, R. C.: A light scattering study of alfin polybutadiene. J. Polymer Sci. 27, 349 (1958).

    CAS  Google Scholar 

  45. Cleland, R. L., and W. H. Stockmayer: An intrinsic viscosity molecular weight relation for polyacrylnitrile. J. Polymer Sci. 17, 473 (1955).

    CAS  Google Scholar 

  46. McCormick, H. W.: Molecular weight distribution of polystyrene by sedimentation velocity analysis. J. Polymer Sci. 36, 341 (1959).

    CAS  Google Scholar 

  47. Conix, A.: On the molecular weight determination of poly (ethylene terephthalate). Makromol. Chem. 26, 226 (1958).

    Article  CAS  Google Scholar 

  48. Cowie, J. M. G., D. J. Worsfeld and S. Bywater: Light-scattering and osmotic pressure study on solutions of polystyrene of narrow molecular-weight distribution produced by anionic catalysis. Trans. Faraday Soc. 57, 705 (1961).

    Article  CAS  Google Scholar 

  49. Debye, P., and A. M. Bueche: Intrinsic viscosity, diffusion and sedimentation rate of polymers in solution. J. Chem. Phys. 16, 573 (1948).

    Article  CAS  Google Scholar 

  50. Dialer, K., u. K. Vogler: Molekulargewichtsverteilung von Polyvinylpyrrolidon. Makromol. Chem. 6, 191 (1951).

    Article  CAS  Google Scholar 

  51. Dialer, K., K. Vogler, u. F. Patat: Zur Charakterisierung fraktionierter Polyvinylalkohole. Helv. Chim. Acta. 35, 869 (1952).

    Article  CAS  Google Scholar 

  52. Didot, F. E., S. N. Chinai and D. Levi: VI. Dilute solution properties by viscosity and light scattering. J. Polymer Sci. 43, 557 (1960).

    CAS  Google Scholar 

  53. Dieu, H. A.: Études des solutions d'alcool polyvinylique. J. Polymer Sci. 12, 417 (1954).

    CAS  Google Scholar 

  54. Duch, E., u. L. Küchler: Molgewichtsbestimmungen bei höheren Temperaturen. Z. Elektrochem. 60, 218 (1956).

    CAS  Google Scholar 

  55. Elias, H. G.: Über extrem große Makromoleküle III. Lichtstreuung, Extinktion und Mehrfachstreuung von Dextran-Lösungen. Makromol. Chem. 27, 192 (1958).

    CAS  Google Scholar 

  56. Über extrem große Makromoleküle IV. Ultrazentrifugen-und Diffusionsmessungen an nicht-Newtonschen Lösungen nativer Dextrane. Makromol. Chem. 33, 166 (1959).

    CAS  Google Scholar 

  57. u. F. Patat: Zur Verzweigung von Polyvinylacetat II. Makromol. Chem. 25, 13 (1957).

    Google Scholar 

  58. Zum Verhalten von Makromolekülen in Lösung. J. Polymer. Sci. 29, 141 (1958).

    CAS  Google Scholar 

  59. Everett, W. W., and J. F. Forster: The subfractionation of amylose and characterisation of the subfractions by light scattering. J. Am. Chem. Soc. 81, 3459 (1959).

    CAS  Google Scholar 

  60. The conformation of amylose in solution. J. Am. Chem. Soc. 81, 3464 (1959).

    CAS  Google Scholar 

  61. Fattakhov, K. Z., V. N. Tsvetkov and O. V. Kallistov: Investigation of solutions of linear polymers by the light-dispersion method (Tyndall effect). Zhur. Exper. i Teoret. Fiz. 26, 345, 351 (1954).

    CAS  Google Scholar 

  62. Fee, J. G., W. S. Port and L. P. Witnauer: Molecular weight viscosity relationship of gamma-irradiated octadecyl vinyl ether and octadecyl methacrylate. J. Polymer Sci. 33, 95 (1958).

    CAS  Google Scholar 

  63. Fessler, J. H., and A. G. Ogston: Studies of the sedimentation, diffusion and viscosity of some sarcosine polymers in aqueous solution. Trans. Faraday Soc. 47, 667 (1951).

    Article  CAS  Google Scholar 

  64. Fixman, M.: Excluded volume in polymer chains. J. Chem. Phys. 23, 1656 (1955).

    CAS  Google Scholar 

  65. Flory, P. J.: Molecular size distribution in linear condensation polymers. J. Am. Chem. Soc. 58, 1877 (1936).

    Article  CAS  Google Scholar 

  66. Molecular size distribution in ethylene oxide polymers. J. Am. Chem. Soc. 62, 1561 (1940).

    CAS  Google Scholar 

  67. -Principles of polymer chemistry. Cornell Univ. Press (1953).

    Google Scholar 

  68. T. G. Fox: Molecular configuration and thermodynamic parameters from intrinsic viscosities. J. Polymer Sci. 5, 745 (1950).

    CAS  Google Scholar 

  69. Treatment of intrinsic viscosities. J. Am. Chem. Soc. 73, 1904, 1909 (1951).

    CAS  Google Scholar 

  70. Frank, H. P., and G. B. Levy: Determination of molecular weight of polyvinylpyrrolidone. J. Polymer Sci. 10, 371 (1953).

    CAS  Google Scholar 

  71. Frisch, H. L., and J. L. Lundberg: A viscometric criterion of polymer polydispersity. J. Polymer Sci. 37, 123 (1959).

    CAS  Google Scholar 

  72. Frisman, E. V., u. L. F. Shalaeva: Lichtstreuung von Polydichlorstyrol in Toluol. Doklady Akad. Nauk S.S.S.R. 101, 907 (1955).

    CAS  Google Scholar 

  73. Frömbling, K., u. F. Patat: Über extrem große Makromoleküle I. Die Charakterisierung von Dextranen. Makromol. Chem. 25, 41 (1958).

    Article  Google Scholar 

  74. Fujita, H., and T. Homma: Viscosity behavior of sodium carboxy methyl cellulose in water a high dilutions. J. Coll. Sci. 9, 591 (1954).

    CAS  Google Scholar 

  75. , K. Mitsuhashi and T. Homma: Viscosities of sodium polyacrylate in aqueous chloride. J. Coll. Sci. Imp. Univ. Tokyo 9, 466 (1959).

    Google Scholar 

  76. Gaylord, N. G., and S. Rosenbaum: Intrinsic viscosity and molecular weight of polyethylene terephthalate. J. Polymer Sci. 39, 545 (1959).

    CAS  Google Scholar 

  77. Graham, W. D.: Viscosity weight average molecularweight for dextrans in the higher clinical size range. Can. J. Techn. 34, 83 (1956).

    CAS  Google Scholar 

  78. Weight average molecular weight of polyvinylpyrrolidone preparations as determinated by light scattering. J. Pharm. and Pharmacol. 9, 230 (1957).

    CAS  Google Scholar 

  79. Gralén, N.: Sedimentations and diffusion measurements on cellulose and cellulose derivatives. Dissertation Uppsala (1944).

    Google Scholar 

  80. G. Lagermalm: A constribution to the knowledge of some physicochemical properties of polystyrene. J. Phys. Chem. 56, 514 (1954).

    Google Scholar 

  81. Granath, K. A.: Solution properties of branched dextrans. J. Colloid Sci. 13, 308 (1958).

    Article  CAS  Google Scholar 

  82. Guzman, G. M., and J. M. G. Fatou: Configurational properties of polyvinyl chloride by viscosity and light scattering measurements. Anales real. soc. españ. fis. y quim. 55 B, 129 (1959).

    Google Scholar 

  83. Haug, A.: Dissertation Mainz 1961.

    Google Scholar 

  84. Hengstenberg, J.: Über Lichtstreuungsmessungen an Fadenmolekülen. Makromol. Chem. 6, 127 (1950).

    Google Scholar 

  85. u. E. Schuch: Molekulargewichtsbestimmung von Polyvinylpyrrolidonen (PVP) mittels des osmotischen Drucks und der Lichtstreuung ihrer Lösungen. Makromol. Chem. 7, 236 (1952).

    Article  CAS  Google Scholar 

  86. Henley, D.: The cellulose solvent cadoxen, a preparation and a viscometric relationship with cupriethylene diamine. Svensk Papperstidn. 63, 143 (1960).

    CAS  Google Scholar 

  87. Henrici-Olivé, G., S. Olivé u. G. V. Schulz: Selbstverzweigung und Übertragungsreaktion am Polymeren bei Polystyrol. Z. physik. Chem. N. F. 20, 176 (1959).

    Google Scholar 

  88. Henry, P. M.: Fractionation of polyethylene. J. Polymer Sci. 36, 3 (1959).

    CAS  Google Scholar 

  89. Holtzer, A. M., H. Benoit and P. Doty: The molecular configuration and hydrodynamic behavior of cellulose trinitrate. J. Phys. Chem. 58, 624 (1954).

    Article  CAS  Google Scholar 

  90. Huggins, M. L.: The viscosity of dilute solutions of long chain molecules. IV. Dependence on concentration. J. Am. Chem. Soc. 64, 2716 (1942).

    CAS  Google Scholar 

  91. Hunt, M. L., S. Newman, H. A. Scheraga and P. J. Flory: Dimensions and hydrodynamic properties of cellulose trinitrate molecules in dilute solutions. J. Phys. Chem. 60, 1278 (1956).

    Article  CAS  Google Scholar 

  92. Huque, H. M., D. A. Goring and S. G. Mason: Molecular size and configuration of cellulose trinitrate in solution. Can. J. Chem, 36, 952 (1958).

    CAS  Google Scholar 

  93. Immergut, E. H., B. G. Ranby and H. F. Mark: Recent work on molecular weight of cellulose. Ind. Eng. Chem. 45, 2483 (1953).

    CAS  Google Scholar 

  94. Ito, H., S. Shimizu and S. Suzuki: Dependence of the viscosity of solutions of polymethylacrylate and polysodiumacrylate on molecular weight. Kôgyô Kagaku Zasshi 59, 930 (1956).

    CAS  Google Scholar 

  95. Jayme, G., u. K. Neuschäffer: Cadmiumaminkomplexbasen als Lösungsmittel für Cellulose. Makromol. Chem. 23, 71 (1957).

    Article  CAS  Google Scholar 

  96. Jullander, J.: Studies on nitrocellulose including the construction of an osmotic balance. Arkiv Kemi, Mineral. Geol. 20 A, Nr. 8 (1945).

    Google Scholar 

  97. Katchalsky, A., and H. Eisenberg: Molecular weight of polyacrylic and polymethacrylic acid. J. Polymer Sci. 6, 145 (1951).

    CAS  Google Scholar 

  98. Kern, W., u. D. Braun: Über die Polymerisation von p-Bromstyrol. Makromol. Chem. 27, 23 (1958).

    Article  CAS  Google Scholar 

  99. Kinell, P. O.: On the Determination of molecular weight averages from sedimentation and diffusion data. Arkiv Kemi 31, 327 (1959).

    Google Scholar 

  100. Kinsinger, J. B., and R. E. Hughes: Intrinsic viscosity-molecular weight relationships for isotactic and atactic polypropylene. J. Phys. Chem. 63, 2002 (1959).

    Article  CAS  Google Scholar 

  101. Kirkwood, J. G. and J. Riseman: The intrinsic viscosities and diffusion constants of flexible macromolecules in solution. J. Chem. Phys. 16, 565 (1948).

    Article  CAS  Google Scholar 

  102. Kirste, R., u. G. V. Schulz: Über die Temperatur-und die Molekulargewichtsabhängigkeit des 2. osmotischen Virialkoeffizienten von Polymethylmethacrylatlösungen. Z. physik. Chem. N. F. 27, 20 (1960) und Internat. Symposium über Makromoleküle Wiesbaden 1959 II B 3.

    Google Scholar 

  103. Koepp, H. M., u. H. Werner: Endgruppenbestimmung und molekulare Verteilung bei Polyäthylenterephthalat. Makromol. Chem. 32, 79 (1959).

    Article  CAS  Google Scholar 

  104. Korshak, V. V., and S. A. Palova: Determination of molecular weights of polyamides from viscosity of their solutions in cresol and methanol. Izvest. Akad. Nauk. S.S.S.R. 1955, 1107.

    Google Scholar 

  105. Krigbaum, W. R., and D. K. Carpenter: The configuration of polymer molecules: polystyrene in cyclohexane. J. Phys. Chem. 59, 1166 (1955).

    Article  CAS  Google Scholar 

  106. P. J. Flory: Molecular weight dependence of the intrinsic viscosity of polymer solutions. J. Polymer. Sci. 11, 37 (1953).

    CAS  Google Scholar 

  107. A. M. Kotliar: The molecular weight of polyacrylonitile. J. Polymer Sci. 32, 323 (1958).

    CAS  Google Scholar 

  108. L. Mandelkern and P. J. Flory: Molecular weight dependence of intrinsic viscosity of polymer solutions. J. Polymer Sci. 9, 381 (1952).

    CAS  Google Scholar 

  109. Kuhn, W., u. H. Kuhn: Diffusion, Sedimentation und Viscosität bei Lösungen verzweigter Fadenmoleküle. Helv. Chim. Acta 30, 1233 (1947).

    CAS  Google Scholar 

  110. u. P. Buchner: Hydrodynamisches Verhalten von Makromolekülen in Lösung. Ergebn. exakt. Naturw. 25, 1 (1951).

    Google Scholar 

  111. Kuhn, H., W. Kuhn and A. Silberberg: Improved relations for diffusion and sedimentation constants and for viscosity and streaming birefringence of solutions of polymers. J. Polymer Sci. 14, 193 (1954).

    CAS  Google Scholar 

  112. Kurata, M., and H. Yamakawa: Theorie of dilute polymer solution II. Osmotic pressure and frictional properties. J. Chem. Phys. 29, 311 (1958).

    Article  CAS  Google Scholar 

  113. Kurosaki, S., T. Sudo and S. Watanabe: Sedimentation, diffusion and viscosity of polystyrene fractions in benzene solutions. J. Chem. Soc. Japan, Pure Chem. Sect. 73, 789 (1952).

    CAS  Google Scholar 

  114. Lee, H. T., and D. W. Levi: Dilute solution study of poly (n-lauryl methacrylate) in an ideal solvent. J. Polymer Sci. 47, 449 (1960).

    CAS  Google Scholar 

  115. Levy, G. B., and H. P. Frank: Determination of molecular weight of polyvinylpyrrolidone II. J. Polymer Sci. 17, 247 (1955).

    CAS  Google Scholar 

  116. Lundberg, J. L., M. Y. Hellman and H. L. Frisch: The study of the polydispersity of polymers by viscometry. J. Polymer Sci. 46, 3 (1960).

    CAS  Google Scholar 

  117. Manley, R. St. J.: Properties of ethylhydroxyethyl cellulose molecules in solution. Arkiv Kemi 9, 519 (1956).

    CAS  Google Scholar 

  118. Marshall, J. and A. Todd: The thermal degradation of polyethylene terephthalate. Trans. Faraday Soc. 49, 67 (1953).

    Article  CAS  Google Scholar 

  119. Marx, M.: Viskosimetrische Molekulargewichtsbestimmung von Cellulose in Kupfer-Äthylendiamin. Makromol. Chem. 16, 157 (1955).

    Article  CAS  Google Scholar 

  120. , u. G. V. Schulz: Methodisches zur Bestimmung der Viscositätszahl (Staudinger Index) von Cellulose und Cellulosenitraten. Makromol. Chem. 31, 140 (1959).

    Article  CAS  Google Scholar 

  121. Masuda, Y.: Solution viscosity of N,N′-dimethylhexamethylene diaminephthalic-acid condensation polymers. Kobunshi Kagaku 13, 540 (1956).

    CAS  Google Scholar 

  122. Matsumoto, M., and Y. Ohyanygi: Viscosity-molecular weight relationship for polyvinyl acetate. J. Polymer Sci. 46, 441 (1960).

    CAS  Google Scholar 

  123. Mendelson, R. A.: High molecular dimensions as estimated from solution properties of whole polymers. J. Polymer Sci. 46, 493 (1960).

    CAS  Google Scholar 

  124. Meyerhoff, G.: Über die Durchschnittswerte der Molekulargewichte makromolekularer Substanzen. Makromol. Chem. 12, 61 (1954).

    CAS  Google Scholar 

  125. Molekulargewichtsbestimmungen an verschieden scharf fraktionierten Polymethacrylsäuremethylestern. Makromol. Chem. 12, 45 (1954).

    CAS  Google Scholar 

  126. Über den experiment. Zusammenhang zwischen Molekulargewicht und Viscositätszahl von Polystyrolen im Bereich vom M = 1000 bis 500000 auf Grund von Sedimentations-und Diffusionsmessungen. Z. physik. Chem. N. F. 4, 336 (1955).

    Google Scholar 

  127. Über den Einfluß der Form des gelösten Moleküls auf das Viscositätsverhalten im Grenzbereich zwischen Nieder-und Hochmolekularen. Z. physik. Chem. N. F. 4, 346 (1955).

    CAS  Google Scholar 

  128. Zur Charakterisierung semipermeabler Membranen für osmotische Zwecke. Z. Elektrochemie 61, 325 (1957).

    CAS  Google Scholar 

  129. Zur Bestimmung von Molekulargewichten und ihrer Verteilung bei unfraktionierten Polymeren. Z. Elektrochemie 61, 1249 (1957).

    CAS  Google Scholar 

  130. Ultrazentrifugenmessungen an Cellulosenitraten. Papier 11, 43 (1957).

    CAS  Google Scholar 

  131. Neuere Bestimmungen des Molekulargewichtes und der molekularen Konstanten von Cellulosenitraten in Lösung. J. Polymer Sci. 29, 399 (1958).

    CAS  Google Scholar 

  132. Zur Viskositäts-Molekulargewichtsbeziehung von Cellulosenitraten verschiedener Herkunft. Makromol. Chem. 32, 249 (1959).

    Article  CAS  Google Scholar 

  133. Dimension of linear polymers in real and hypothetical solvents. J. Polymer Sci. 43, 269 (1960).

    CAS  Google Scholar 

  134. Moleküldimensionen von Polymeren auf Grund hydrodynamischer Messungen. Makromol. Chem. 37, 97 (1960).

    Article  CAS  Google Scholar 

  135. Viscositätszahl, Molekulargewicht und Einheitlichkeit anionischer Polystyrole nach Szwarc. Z. physik. Chem. N. F. 23, 100 (1960).

    CAS  Google Scholar 

  136. u. M. Cantow: Molekulargewichte und Molekulargewichtsverteilungen unverzweigter und verzweigter Polystyrole. J. Polymer Sci. 34, 503 (1959).

    CAS  Google Scholar 

  137. u. G. V. Schulz: Molekulargewichtsbestimmungen an Polymethacrylsäureestern mittels Sedimentation in der Ultrazentrifuge und Diffusion. Makromol. Chem. 7, 294 (1952).

    Article  CAS  Google Scholar 

  138. Miller, L. E., and F. A. Hamm: Macromolecular properties of polyvinylpyrrolidone: Molecular weight distribution. J. phys. Chem. 57, 110 (1953).

    Article  CAS  Google Scholar 

  139. Moore, W. R., and A. M. Brown: Relationship between viscosity and molecular weight of ethylcellulose. J. Appl. Chem. (London) 8, 363 (1958).

    CAS  Google Scholar 

  140. Viscosity-temperature relationships for dilute solutions of cellulose derivatives I. Temperature dependence of solution viscosities of ethyl cellulose. J. Colloid Sci. 14, 1 (1959).

    CAS  Google Scholar 

  141. B. M. Tidswell: Viscosity molecular weight relationships for cellulose acetate. J. Appl. Chem. (London) 8, 232 (1958).

    CAS  Google Scholar 

  142. Mukherja, R. N., et P. Rempp: Étude physico-chimique de polymère obtenus par voie anionique en phase homogène. J. chim. phys. 56, 94 (1959).

    Google Scholar 

  143. Muus, L. T., and F. W. Billmeyer: The molecular structure of polyethylene. VI. Molecular weight from dissymmetry of scattered light. J. Am. Chem. Soc. 79, 5079 (1957).

    Article  CAS  Google Scholar 

  144. Naito, R.: Viscosity measurements on polyvinylalcohol solutions in dimethylsulfoxide. Kobunski Kagaku 15, 597 (1958).

    CAS  Google Scholar 

  145. Newman, S., L. Loeb and C. M. Conrad: Viscosity, sedimentation, diffusion, and osmotic behavior of long chain nitrocellulose molecules. J. Polymer Sci. 10, 463 (1953).

    CAS  Google Scholar 

  146. Notley, N. T., and P. Debye: Dimensions of linear polystyrene molecules in solution: Molecular weight dependence for low molecular weights. J. Polymer Sci. 24, 275 (1957).

    CAS  Google Scholar 

  147. Nowakowski, B.: Unveröffentlichte Mainzer Messungen.

    Google Scholar 

  148. Oehrn, O. E.: Precision viscometry of extremely dilute solutions of high polymers. Arkiv. Kemi 12, 397 (1958).

    Google Scholar 

  149. Onyon, P. F.: Molecular weights and intrinsic viscosities of solution polymerized polyacrylonitrile. J. Polymer Sci. 37, 315 (1954).

    Google Scholar 

  150. Characterization of molecular weight distributions by a viscometric method. Nature (Lond.) 183, 1670 (1959).

    CAS  Google Scholar 

  151. Outer, P., C. I. Carr and B. H. Zimm: Light scattering investigation of the structure of polystyrene. J. Chem. Phys. 18, 830 (1950).

    Article  CAS  Google Scholar 

  152. Oyama, T., and K. Kawahara: Light scattering investigation on polystyrenes of high molecular weight in toluene solutions. Nippon Kagaku Zashi 78, 484 (1957).

    CAS  Google Scholar 

  153. and M. Ueda: Light scattering investigation on polystyrenes of high molecular weight dissolved in methylethylketone. Nippon Kagaku Zashi 79, 727 (1958).

    CAS  Google Scholar 

  154. Parrini, P., F. Sebastiano and G. Messina: Intrinsic viscosity and molecular weight of isotactic polypropylene, Makromol. Chem. 38, 27 (1960).

    Article  CAS  Google Scholar 

  155. Patat, F.: Das Problem der Membran bei osmotischen Messungen an Hochpolymeren. Z. Elektrochem. 60, 208 (1956).

    CAS  Google Scholar 

  156. Membrane für osmotische Messungen. Makromol. Chem. 34, 120 (1959).

    Article  CAS  Google Scholar 

  157. Peebles, L. H.: Branching in polyacrylonitrole. J. Am. Chem. Soc. 80, 5603 (1956).

    Google Scholar 

  158. Peterlin, A.: Viscosity and sedimentation of linear macromolecules exhibiting partial solvent immobilization. J. Polymer Sci. 5, 473 (1950).

    CAS  Google Scholar 

  159. Determination of the diameter of the coiled macromolecule from viscosity, sedimentation, and diffusion. J. Coll. Sci. 10, 587 (1955).

    Article  CAS  Google Scholar 

  160. Die Viskositätszahl bei linearen und verzweigten Hochpolymeren. Z. Naturforsch. 10a, 412 (1955).

    CAS  Google Scholar 

  161. Bestimmung von Molekülabmessungen aus Viskosität, Sedimentation und Diffusion. Makromol. Chem. 18/19, 254 (1956).

    CAS  Google Scholar 

  162. Determination of molecular dimensions from rheological data. Makromol. Chem. 34, 89 (1959).

    Article  CAS  Google Scholar 

  163. Philipp, H. J., and C. F. Bjork: Viscosity molecular weight relationship for cellulose acetate in acetone. J. Polymer. Sci. 6, 549 (1951).

    CAS  Google Scholar 

  164. Pouradier, J., et A. M. Venet: Contribution a l'étude de la structure des gelatines. J. Chim. Phys. 47, 391 (1950).

    CAS  Google Scholar 

  165. Price, F. P., S. G. Martin and J. P. Bianchi: The structure of polysiloxanes. J. Polymer Sci. 22, 41, 49 (1956).

    CAS  Google Scholar 

  166. Ptitsyn, O. B., u. Y. E. Ejzner: Die Viskositätszahl Polymerer in guten Lösungsmitteln. Zhurn. Fiz. Khim. 32, 2464 (1958).

    CAS  Google Scholar 

  167. Raman, N. K., and J. J. Hermans: Solution studies of some polyethylene samples. J. Polymer Sci. 35, 71 (1959).

    CAS  Google Scholar 

  168. Rempp, P.: Contribution a l'étude des solution de molécules en chaine a squelette oxygéné. J. Chim. Phys. 54, 421, 432 (1957).

    Google Scholar 

  169. Ribeyrolles, Ph., A. Guillot et H. Benoit: Étude physico-chimique des propriétés d'un polybutadiène en solution. J. Chim. Phys. 56, 377 (1959).

    CAS  Google Scholar 

  170. Rusznak, I., I. Géczy and A. Ady: The viscometric determination of the molecular weight of super polyamides in aqueous chloralhydrate. Textiltechn. 7, 490 (1956).

    CAS  Google Scholar 

  171. Sadron, C., et P. Rempp: Viscosités intrinseques de solutions de chaines courtes. J. Polymer Sci. 29, 127 (1958).

    CAS  Google Scholar 

  172. Saini, G., G. Maldifassi u. L. Trossarelli: Molekulargewichts-Viskositätsbeziehung von Polyvinylacetat. Ann. Chim. (Rom) 44, 533 (1954).

    CAS  Google Scholar 

  173. , Saini, G., u. L. Trossarelli: Die Polymeren von Butylacrylat. Atti. acced. sci. Torino 90, 410 (1955–56).

    Google Scholar 

  174. Sato, T.: Determination of molecular weight of dextrans by light scattering. Kobunshi Kagaku 13, 526 (1956).

    CAS  Google Scholar 

  175. Sato, H., and T. Yamamoto: Intrinsic viscosity molecular weight relation for poly-2-methyl-5-vinylpyridine (in Methanol und Dimethylformamid). Nippon Kagaku Zashi 80, 1393 (1959).

    CAS  Google Scholar 

  176. Schaefgen, J. R., and P. J. Flory: Synthesis of multichain polymers and investigation of their viscosities. J. Am. Chem. Soc. 70, 2709 (1948).

    CAS  Google Scholar 

  177. Scherer, P. C., A. Tannenbaum, and D. W. Levi: Molecular weight of ethyl cellulose. J. Polymer Sci. 43, 531 (1960).

    CAS  Google Scholar 

  178. Schick, A. F., and S. J. Singer: On the concentration dependence of the rates of diffusion of macromolecules in solution. J. Phys. Chem. 54, 1028 (1950).

    Article  CAS  Google Scholar 

  179. Scholtan, W.: Molekulargewichtsbestimmung von Polyvinylpyrrolidon mittels der Ultrazentrifuge. Makromol. Chem. 7, 209 (1952).

    Article  CAS  Google Scholar 

  180. Schulz, G. V.: Über die Beziehung zwischen Reaktionsgeschwindigkeit und Zusammensetzung des Reaktionsproduktes bei Makropolymerisationsvorgängen. Z. physik. Chem. B 30, 379 (1935).

    Google Scholar 

  181. u. F. Blaschke: Eine Gleichung zur Berechnung der Viscositätszahl für sehr kleine Konzentrationen. J. prakt. Chem. 158, 130 (1941).

    CAS  Google Scholar 

  182. u. H. J. Cantow: Vorschlag zur Unterscheidung der 2 Größen: „Grenzviskositätszahl“ und „konventionelle Viskositätszahl“. Makromol. Chem. 13, 71 (1954).

    Article  CAS  Google Scholar 

  183. u. G. Meyerhoff: Bestimmung des Durchmessers geknäuelter Fadenmoleküle aus Lichtzerstreuung und Viskositätszahl: Untersuchungen an Polymethylmethacrylaten. J. Polymer Sci. 10, 79 (1953).

    CAS  Google Scholar 

  184. G. Henrici-Olivé u. S. Olivé: Zur quantitativen Berücksichtigung veränderlicher Mittelwerte des Polymerisationsgrades bei der Bestimmung von Übertragungskonstanten. Z. physik. Chem. N. F. 19, 125 (1959).

    CAS  Google Scholar 

  185. u. A. Horbach: Die molekularen Konstanten von Polycarbonaten in Lösung. Makromol. Chem. 29, 93 (1959).

    CAS  Google Scholar 

  186. u. G. Meyerhoff: Bestimmung der Knäueldimensionen von Fadenmolekülen in Lösungen aus Reibungsdaten. Z. Elektrochemie 56, 904 (1952).

    CAS  Google Scholar 

  187. Senti, F. R., N. N. Hellman u. Mitarb.: Viscosity, sedimentation and lightscattering properties of fractions of an acid hydrolyzed dextran. J. Polymer Sci. 17, 527 (1955).

    CAS  Google Scholar 

  188. Sharples, A., and H. M. Major: Determination of constants in the intrinsic viscosity molecular weight equation (cellulose acetat). J. Polymer Sci. 27s, 433 (1958).

    Google Scholar 

  189. Shultz, A. R.: Polyvinylacetate: a light scattering and viscosity study. J. Am. Chem. Soc. 76, 3422 (1952).

    Google Scholar 

  190. Singer, S.: Molecular weight averages obtained from sedimentation velocity and diffusion measurements. J. Polymer Sci. 1, 445 (1946).

    CAS  Google Scholar 

  191. Staudinger, H., u. M. Sorkin: Über Viscositätsuntersuchungen an Cellulosenitraten. Ber. dtsch. chem. Ges. 70, 1993 (1937).

    Google Scholar 

  192. Stockmayer, W. H., and A. C. Albrecht: Friction constants of chain molecules with excluded volume. J. Polymer Sci. 32, 215 (1958).

    CAS  Google Scholar 

  193. u. R. O. Howard: Zitiert nach [M 5).

    Google Scholar 

  194. Strauss, U. P., and P. L. Wineman: Molecular dimensions and interaction of long chain polyphosphates in sodium bromide solutions. J. Am. Chem. Soc. 80, 2366 (1958).

    CAS  Google Scholar 

  195. Thurmond, C. D., and B. H. Zimm: Size and shape of the molecules in artifically branched polystyrene. J. Polymer Sci. 8, 477 (1952).

    CAS  Google Scholar 

  196. Tossarelli, L., and E. Campi: Light scattering of isotactic polystyrene. J. Polymer Sci. 35, 205 (1959).

    Google Scholar 

  197. Trementozzi, Q. A.: Effect of long chain branching on some solution properties of polyethylene. J. Polymer Sci. 23, 887 (1957).

    CAS  Google Scholar 

  198. Molecular weights and molecular dimensions of linear and branched polyethylenes. J. Polymer Sci. 36, 113 (1959).

    CAS  Google Scholar 

  199. Tsvetkov, V. N., and O. V. Kallistov: Light dispersion and viscosity of solutions of the fractions of poly-p-tert-butylphenylmethacrylate in acetone. Zhur. Fiz. Khim. 33, 710 (1959).

    CAS  Google Scholar 

  200. S. Y. Kotlyar: Investigation of polyvinylacetet solutions by the lightdispersing method. Zhur. Fiz. Khim. 30, 1100 (1956).

    CAS  Google Scholar 

  201. Tung, L. H.: Zitiert nach P. M. Henry: (H 6).

    Google Scholar 

  202. Molecular weight-intrinsic viscosity relationship and molecular weight distribution of low pressure polyethylenes. J. Polymer Sci. 24, 333 (1957).

    CAS  Google Scholar 

  203. A light-scattering study of low pressure polyethylene fractions. J. Polymer Sci. 36, 287 (1959).

    CAS  Google Scholar 

  204. Uda, K., u. G. Meyerhoff: Hydrodynamische Eigenschaften von Methylcellulosen in Lösung. Makromol. Chem. 47, 168 (1961).

    Article  CAS  Google Scholar 

  205. Wales, M., P. A. Marshall and S. G. Weissberg: Intrinsic viscosity molecular weight relationships for dextran. J. Polymer Sci. 10, 229 (1953).

    CAS  Google Scholar 

  206. , J. W. Williams, J. O. Thompson and R. H. Ewart: Sedimentation equilibra of polydisperse non-ideal-solutes. J. Phys. Chem. 52, 983 (1948).

    CAS  Google Scholar 

  207. Walsh, E. K., and H. S. Kaufman: Intrinsic viscosity molecular weight relationships for polychlorotrifluoroethylene. J. Polymer Sci. 26, 1 (1957).

    CAS  Google Scholar 

  208. Ward, I. M.: Measurement of hydroxyl and carboxyl endgroups in polyethylene terephthalate. Trans. Faraday Soc. 53, 1406 (1957).

    Article  CAS  Google Scholar 

  209. Molecular weight determination in polyethylene terephthalate. Nature (Lond.) 180, 141 (1957).

    CAS  Google Scholar 

  210. Wesslau, H.: Die Molekulargewichtsverteilung einiger Niederdruckpolyäthylene. Makromol. Chem. 20, 111 (1956).

    CAS  Google Scholar 

  211. Zimm, B. H.: Dynamics of polymer molecules in dilute solution: Viscoelasticity, flow birefringence and dielectric loss. J. Chem. Phys. 24, 269 (1956).

    CAS  Google Scholar 

  212. R. W. Kilb: Dynamics of branched polymer molecules in dilute solution. J. Polymer Sci. 37, 19 (1959).

    CAS  Google Scholar 

  213. W. H. Stockmayer: The dimensions of chain molecules containing branches and rings. J. Chem. Phys. 17, 1301 (1949).

    Article  CAS  Google Scholar 

  214. and M. Fixman: Excluded volume in polymer chains. J. Chem. Phys. 21, 1716 (1953).

    CAS  Google Scholar 

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    G. Meyerhoff

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Meyerhoff, G. (1961). Die viscosimetrische Molekulargewichtsbestimmung von Polymeren. In: Fortschritte Der Hochpolymeren-Forschung. Advances in Polymer Science, vol 3/1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0050516

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