Abstract
This chapter presents a recent overview of various haloforms that may be found in drinking water. It covers the main aspects related to their occurrence in drinking water in association with different disinfection processes practiced in water treatment technologies. The health effects of haloforms including carcinogenicity and reproductive and developmental toxicity are summarized and followed by a coverage of the main relevant regulations. A major section discussing the transport of haloforms in general and disinfection by-products (DBPs) in particular throughout the water distribution systems is then presented. Topics covered in this section include factors affecting DBPs formation, kinetic models for DBP formation, and DBPs transport modeling approaches in pipe networks. A recent approach developed to model the THM species in pipe networks is elaborated on at the end of the chapter with a brief presentation of its application to the distribution system of Abu Dahbi, the capital city of United Arab Emirates.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Abbreviations
- BAT:
-
Best available technology
- CNBr:
-
Cyanogen bromide
- CNX:
-
Cyanogen halides
- DBPs:
-
Disinfection by products
- D/DBPs:
-
Disinfectants disinfection by-products
- DMA:
-
Dimethylamine
- ESWTR:
-
Enhanced surface water treatment rule
- GWDR:
-
Groundwater drinking rule
- HAA5:
-
Five regulated haloacetic acids (chloro, dichloro-, trichloro-,bromo-, dibromoacetic acids)
- HAAs:
-
Haloacetic acids, same as HAA9 (HAA5+chlorobromo, dichlorobromo-, dibromochloro-, tribromoacetic acids)
- HANs:
-
Haloacetonitriles
- IESWTR:
-
Interim enhanced surface water treatment rule
- LT1ESWTR:
-
Long term 1 enhanced surface water treatment rule
- LT2ESWTR:
-
Long term 2 enhanced surface water treatment rule
- MCA:
-
Monochloramine
- MCLs:
-
Maximum contaminant levels (complying level)
- MCLGs:
-
Maximum contaminant level goals (levels below which no health effect is known)
- MRDLs:
-
Maximum residual disinfectant levels
- MRDLGs:
-
Maximum residual disinfectant level goals
- NCI:
-
National Cancer Institute
- NDMA:
-
n-Nitrosodimethylamine
- NPDWR:
-
National primary drinking water regulations
- NTP:
-
National toxicology program
- SDWA:
-
Safe drinking water act
- SHDW:
-
Synthetic haloforms in drinking water
- SUVA:
-
Specific ultra violet absorbance
- TOX:
-
Total organic halogens
- TTHM:
-
Total trihalomethanes
References
Stevens AA, Moore LA, Slocum CJ, Smith BL, Seeger DR, Ireland JC (1989) By-products of chlorination at ten operating utilities. In: Disinfection by-products: current perspectives. AWWA, Denver, Colorado
Rook JJ (1974) Water Treat Exam 23: 234
Christman RL, Johnson JD, Norwood DO, Liao WT, Hass JR, Pfaender FK, Webb MR, Bobenreith MJ (1979) Final Report of USEPA Project R–804430, EPA 600/2–81–016, NTIS Accession No.PB 81–161952, Cincinnati, Ohio
Norwood DL, Johnson JD, Christman RF, Hass JR, Bobenrieth MJ (1980) Environ Sci Technol 14: 187
Pourmoghaddas H, Stevens AA, Kinman RN, Dressman RC, Moore LA, Ireland JC (1993) J AWWA 85: 82
Cowman GA, Singer PC (1996) Environ Sci Technol 30: 16
Kronberg, L, Holmbom B, Reunanen M, Tikkanen L (1988) Environ Sci Technol 22: 1097
Symons JM, Speitel GE Jr, Hwang CJ, Krasner SW, Barrett SE, Diehl AC, Xia R (1998) Factors affecting disinfection by-product formation during chloramination. AWWA Research Foundation and AWWA, Denver, Colorado
Symons JM, Stevens AA, Clark RM, Geldreich EF, Love OT Jr, DeMarco J (1982) AWWA, Denver, Colorado
Diehl AC, Speitel GC Jr, Symons JM, Krasner SW, Hwang CJ, Barrett SE (1998) J AW W WA (submitted)
Krasner SW, McGuire MJ, Jacangel JG, Patania NL, Reagan KM, Aieta EM (1989) J AWWA 81: 41
Ohya T, Kanno S (1985) Chemosphere 14: 1717
Choi J, Valentine RL (2002) Water Res 36: 817
Jensen JN, St Aubin JJ, Christman RF, Hohnson JD (1985) Characterization of the reaction between monochloramines and isolated fulvic acid. In: Jolley RL, Bull RJ, Davis WP, Katz S, Roberts MH, Jacobs VA (eds) Water chlorination chemistry. Environmental impact and health effects, vol 5. Lewis, Chelsea, Michigan
Richardson SD, Thruston AD Jr, Caughran TV, Chen PH, Collette TW, Floyd TL (1999) Environ Sci Technol 33: 3368
Reckhow DA, Singer PC (1985) Mechanisms of organic halide formation during fulvic acid chlorination and implications with respect to preozonation. In: Jolley RL, Bull RJ, Davis WP, Katz S, Roberts MH, Jacobs VA (eds) Water chlorination chemistry. Environmental impact and health effects, vol 5. Lewis, Chelsea, Michigan
Legube B, Croue JP, Reckhow DA, Dore M (1985) Ozonation of organic halide precursors: effects of bicarbonate and bromide. In: Proceedings of the International Conference on the Role of Ozone in Water and Wastewater Treatment. Selper, London, p 73
Miltner RJ, Shukairy HM, Summers RS (1992) J AWWA 84: 53
Krasner SW (1996) The effects of ozonation, biofiltration, and secondary disinfection on DBP formation. In: Proceedings of the Water Quality Technology Conference. AWWA, Denver, Colorado
Richardson SD, Thruston AD Jr, Collette TW (1996) Environ Sci Technol 30: 3327
NCI (1976) Report on cancer carcinogenesis bioassay of chloroform. NTIS PB-264018, National Cancer Institute
Crump KS, Guess HA (1982) Annu Rev Pub Health 3: 339
Shy C (1985) Envir. Health perspectives 62: 399
Cantor KP, Hoover R, Hartge P, Mason TJ, Silverman DT, Levin LI (1985) Drinking water source and bladder cancer: a case study, chap 12. In: Jolley RL, Bull RJ, Davis WP, Katz S, Roberts MH, Jacobs VA (eds) Water chlorination chemistry. Environmental impact and health effects, vol 5. Lewis, Chelsea, Michigan
Cantor KP, Hoover R, Hartge P, Mason TJ, Silverman DT, Altman R, Austin DF, Child MA, Key CR, Marrett LD, Myers MH, Narayana AS, Levin LI, Sullvan JW, Swanson GM, Thomas DB, West DW (1987) J NCI 79: 1269
Cantor KP, Hoover R, Hartge P, Mason TJ, Silverman DT (1990) Bladder cancer, tap water consumption and drinking water source. In: Jolley RL, Bull RJ, Davis WP, Katz S, Roberts MH, Jacobs VA (eds) Water chlorination chemistry. Environmental impact and health effects, vol 6. Lewis, Chelsea, Michigan
Devesa SS, Silverman DT, McLaughlin JK, Brown CC, Connelly RR, Fraumeni JT (1990) Can Causes Cont 1: 133
McGeehin MA, Reif JS, Becher JC, Mangione EJ (1993) Am J Epidemiol 138: 492
King WD, Marrett LD (1996) Can Causes Cont 7: 596
NTP (1989) Technical Report Series 350, National Toxicology Program
NTP (1985) Technical Report Series 282, National Toxicology Program
Herren-Freund S, Pereira M (1986) Environ Health Perspect 69: 59
DeAngelo AB, Daniel FB, Stober JA, Olson GR (1991) Fundam Appl Toxicol 16: 337
DeAngelo AB, Daniel FB, Most BM, Olson GR (1996) Toxicology 114: 207
Bull RJ, Sanchez IM, Larsen MA, Lansing AJ (1990) Toxicology 63: 341
USEPA (1998) National primary drinking water regulations. Final Rule. Fed Reg P 69390
WHO (1996) Guidelines for drinking water quality Health criteria and other supporting information, 2nd edn, vol 2. Geneva, Switzerland
Komulainen H, Kosma VM, Vaittinen SL, Vartianinen T, Korhonen EK, Lotjonen S, Tuominen RK, Toumisto J (1997) J Nat Can Inst 89: 848
Fawell J, Robinson D, Bull R, Birnbaum L, Boorman G, Buutterworth B, Daniel P, Gorchev HG, Hauchman F, Julkunen P, Klaassen C, Krasner S, Zavleta JO, Reif J, Tardiff R (1997) Environ Health Perspect 105: 108
Kurokawa Y, Takayama S, Konishi Y, Hissa Y, Asahina S, Takahashi M, Maekawa A, Hayashi Y (1986) Environ Health Perspect 69: 221
Kurokawa Y, Aoli S, Matsushima Y (1986) J NCI 77: 977
Savitz DA, Andrews KW, Pastore LM (1995) Environ Health Perspect 103: 592
Waller K, Swan SH, DeLorenze G, Hopkins B (1998) Epidemiology 9: 134
Kanitz S, Franco Y, Partone V, Caltabellotta M, Raffo E, Riggi C, Timitilli D, Rayera G (1996) Environ Health Perspect 104: 516
Klinefelter G, linder R (1996) Recent reproductive effects associated with disinfection byproducts. In: Disinfection by-products in drinking water: critical issues in health effective research. Workshop Report, International Life Science Institute Press, Washington DC
Kavlock RJ, Narotsky M (1992) HERL/EPA Internal report to the Office of Water
Richard AM, Hunter S (1996) Teratology 53: 352
Packham RF (1999) Disinfection and disinfection by-products in europe. In: Singer PC (ed) Formation and control of disinfection by-products in drinking water. AWWA, Denver, Colorado, p 393
Department of the Environment & Welsh Office (1989) Guidance on safeguarding the quality of water supplies. Her Majesty’s Stationery Office, London
ILSI (1993) Safety of water disinfection: balancing chemical and microbial risks. In: Craun G (ed) International Life Science Institute Press, Washington DC
USEPA (1979) Control of trihalomethanes in drinking water. Final Rule. Fed Reg 44(231): 68, 624
USEPA (1989) National primary drinking water regulations. Final Rule. Fed Reg 54(124): 27, 486
USEPA (1989) National primary drinking water regulations. Final Rule. Fed Reg 54(124): 27, 544
USEPA (1989) Discussion of Strawman rule for disinfectant and disinfection by-products. Criteria and Standard Div, USEPA Office of Drinking Water, Washington DC
USEPA (1994) National primary drinking water regulations. Final Rule. Fed Reg 59(145): 38, 668
USEPA (1998) Disinfectants and disinfection by-products. Proposed Rule. Fed Reg 63(61): 15, 674
USEPA (1998) Disinfectants and disinfection by-products. Proposed Rule. Fed Reg 63(241): 69, 390
USEPA (2001) Revisions to the interim enhanced surface water treatment rule, stage 1DBPR, and revisions to state primacy requirements to implement the Safe drinking water act amendments. Final Rule. Fed Reg 66 (10): 3770
European Community (1980) Official J 80:778EC
WHO (1970) European standards for drinking water. World Health Organization, Geneva, Switzerland
WHO (1984) Guide lines for drinking water quality. World Health Organization, Geneva, Switzerland
WHO (1993) Guide lines for drinking water quality, 2nd edn. World Health Organization, Geneva, Switzerland
Statutory Instrument No.1147 (1989) The water supply regulations 1989. Her Majesty’s Stationary Office, London
Aeppli (1997) Potable water quality requirements, International report. International Water Supply Association, London
Kruithof, Evendijk (1995) New WHO recommendations for water quality standards. International Water Supply Association, London
USEPA website (2002) Drinking water priority rulemaking: microbial and disinfection byproduct rules
APHA (1995) Standard methods for the examination of water and wastewater, 19th edn. AWWA and WEF, Washington
Singer PC, Chang SD (1989) J AWWA 81: 61
Edzwald JK, Van Benschoten JE (1990) Fourth International Gothenburg Symposium on Chemical Treatment, Madrid, Spain
Owen DM, Amy GL, Chowdhury ZK (1993) Characterization of natural organic matter and its relationship to treatability. AWWA Research Foundation and AWWA, Denver, Colorado
Reckhow AD, Singer PC, Malcolm RL (1990) Environ Sci Technol 24: 1655
Hoehn RC, Barnes DB, Thompson BC, Randall CW, Grizzard TJ, Shaffer PT (1980) J AWWA 72: 344
Trussell RR, Umphres MD (1978) J AWWA 70: 604
Amy GL, Tan L, Davis MK (1991) Water Res 25: 191
Shams El Din AM, Rasheed AA, Hammoud AA (1991) Desalination 85: 13
Symons JM, Krasner SW, Simms LA, Sclimenti MJ (1993) J AWWA 85: 51
Singer PC (1994) J Environ Eng 120: 727
Stevens AA, Slocum CJ, Seeger DR, Robeck GG (1976) J AWWA 69: 615
Morris JC, Baum B (1978) Precursors and mechanisms of haloform formation in the chlorination of water supplies. In: Water chlorination: environmental impact and health effects, 2. Ann Arbor Science, Michigan
Fleischacher SJ, Randtke SJ (1993) J AWWA 85: 96
Reckhow DA, Singer PC (1984) J AWWA 76: 151
Croue JP, Reckhow DA (1989) Environ Sci Technol 23: 1412
Krasner SW, Reagan KM, Jacangelo JG, Patania NL, Aieta EM, Gramith KM (1990) Proc AWWA Annual Conference
Amy GL, Chadik PA, Chowdhury ZK (1987) J AWWA 79: 7
Chowdhury ZK, Amy GL (1999) Modeling disinfection by-products formation. In: Singer PC (ed) Formation and control of disinfection by-products in drinking water. AWWA, Denver, Colorado, p53
AWWA Research Foundation (1991) Disinfection by-products database and model project. AWWA, Denver, Colorado
Watson M (1993) Mathematical modeling of the formation of THMs and HAAs in chlorinated natural waters. Final Report submitted to the AWWA D/DBPs technical advisory workgroup, Denver, Colorado
Rossman LA, Richard AB, Singer PC, Nuckols JR (2001) J Water Res 35: 3483
Rossman LA, Clark RM, Grayman WM (1994) J Environ Eng ASCE 120 (4): 803
USEPA (1993) EPANET Users Manual
Liou CP, Kroon JR (1987) J AWWA 79: 54
Boulus PF, Altman T, Jarrige PA, Collevati F (1995) WRPM, ASCE 121: 49
Elshorbagy W, Lansey K (1994) AWWA Computer Conference, Los Angles, California, p 457
Elshorbagy A (2000) J WRPM, ASCE 126: 21
Clark RMWM, Grayman, Males RM (1988) J Environ Eng ASCE 114: 929
Grayman WM, Clark RM, Goodrich JA (1988) J WRPM, ASCE 114: 295
Rossman LA, Boulos PF, Altman T (1993) J WRPM, ASCE 119: 505
AWWA Research Foundation (1996) Characterization and modeling of chlorine decay in distribution systems. American Water Works Association, Denver, Colorado
Jarrige PA (1993) PICCOLO - Users manual. SAFEGE Consulting Engineers, France
Elshorbagy WA, Abu-Qdais H, Elsheamy MK (2000) J Water Res 34: 3431
Gould JP, Fitchhorn LE, Urheim E (1981) Environ Impacts Health Eff 4: 297
Clark RM, Feige (1993) Meeting the requirements of the Safe Drinking Water Act. In: Clark RM, Summers RS (eds) Strategies and technologies for meeting SDWA requirements. Tehnomic Publishing, Lancaster, PA
Grayman WM, Clark RM (1990) Proceedings of the 1990 Annual AWWA Conference, Cincinnati
Krasner SW (1996) Chemistry of disinfection by-product formation. In: Singer PC (ed) Formation and control of disinfection by-products in drinking water. AWWA, Denver, Colorado, p 27
Myer I, Francals T, Lykins BW, Dutang JM, Hartemann P (1993) Influence of biofilm on disinfection by-products in a distribution network. In: Proceedings of the Specialized Conference on Quality Aspects of Water Supply. Berlin, Germany
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2003 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Elshorbagy, W. (2003). Fate and Transport of Haloforms in Water Distribution Systems. In: Nikolaou, A.D. (eds) Haloforms and Related Compounds in Drinking Water. The Handbook of Environmental Chemistry, vol 5 / 5G. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-44997-3_5
Download citation
DOI: https://doi.org/10.1007/978-3-540-44997-3_5
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-53618-2
Online ISBN: 978-3-540-44997-3
eBook Packages: Springer Book Archive