Abstract
Understanding the correlation between morphology andmicromechanical processes of deformation and fracture of semicrystalline polymers is essential for material development, modification, and failure analysis. Since semicrystalline polymers exhibit a hierarchical morphology with structures ranging from the nanometre to the millimetre scale, various electron microscopic techniques are applied to image typical structural units such as crystalline blocks, lamellae, spherulites, and fibrils. In this chapter, a general survey of methods of morphological and micromechanical analysis is first provided, with examples given for the most significant semicrystalline polymers, polyethylene (PE) and polypropylene (PP). The chapter presents methods for enhancing contrast by chemical staining and etching, the application of electron diffraction contrast, electron beam irradiation effects, studies of crystallisation and melting phenomena, as well as typical micromechanical phenomena that can be related to brittle, ductile, or high-strength behaviour, such as crazing, chevron formation, fibrillation, and others. Additional examples of semicrystalline polymers, such as polyamides, fluoropolymers, polyurethanes, biomedical polyesters, etc., are then given.
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References
Editor (2005) Kunststoffe 95:35
Michler GH (1992) Kunststoff-Mikromechanik: Morphologie, Deformations- und Bruchmechanismen. Hanser Verlag, München
Bassett DC (2005) The morphology of crystalline polymers. In: Michler GH, Baltá Calleja FJ (eds) Mechanical properties of polymers based on nanostructure and morphology. CRC Press (Taylor and Francis), Boca Raton, FL, Chap 1, p 3
Bassett DC (1981) Principles of polymer morphology. Cambridge University Press, Cambridge
Bassett DC (1984) CRC Crit Rev Sol State Mater Sci 12:97
Hall IH (ed) (1984) Structure of crystalline polymers. Elsevier, London
Zhou JJ, Liu JG, Yan SK, Dong JY, Li L, Chan CM, Schultz JM (2005) Polymer 46:4077
Michler GH, Steinbach H, Bühler K (1988) Proc 12 Tagung Elektronenmikroskopie, Dresden, 18–20 Jan 1988, p 395
Michler GH (1996) J Macromol Sci Macromol Phys B35:329
Grubb DT (1974) J Mater Sci 9:1719
Michler GH, Gruber K, Steinbach H (1982) Acta Polym 33:550
Michler GH, Steinbach H, Hoffmann K (1986) Acta Polym 37:289
Michler GH, Naumann I, Steinbach H (1992) Prog Colloid Polym Sci 87:16
Michler GH (1992) Kunststoff-Mikromechanik: Morphologie, Deformations- und Bruchmechanismen. Hanser Verlag, München, Sect 8.3.2, p 205
Hofmann D, Geiß D, Janke A, Michler GH, Fiedler P (1990) J Appl Polym Sci 39:1595
Kajiyama T, Okada T, Takayanagi M (1974) J Macromol Sci Phys B9:35
Peterlin A (1981) J Macromol Sci Phys B19:401
Krug H, Karbach A, Petermann J (1984) Polymer 25:1687
Krumova M, Henning S, Michler GH (2006) Phil Mag 86:1689
Michler GH, Marinow SL, Naumann I (1989) Plaste Kautschuk 36:432
Henning S, Adhikari R, Michler GH (2004) Macromol Symp 214:157
Henning S, Michler GH (2005) In: Michler GH, Baltá Calleja FJ (eds) Mechanical properties of polymers based on nanostructure and morphology. CRC Press (Taylor and Francis), Boca Raton, FL, Chap 7, 245
Ania F, Baltá Calleja FJ, Bayer RK, Tshmel A, Naumann I, Michler GH (1996) J Mater Sci 31: 4199
Hine PJ, Ward IM, Jordan ND, Olley R, Bassett DC (2003) Polymer 44(4):1117
Barham PJ, Keller A (1985) J Mater Sci 20(7):2281
Smith P, Lemstra PJ (1980) J Mater Sci 15(2):505
Smook J, Pennings AJ (1984) J Mater Sci 19(1):31
Ivankova E, Vasilieva V, Myasnikowa L, Marikhin V, Henning S, Michler GH (2002) Epolymers 044:1
Pitt CG (1992) In: Vert M (ed) Biodegradable polymers and plastics; the proceedings of the Second International Scientific Workshop on Biodegradable Polymers and Plastics (Montpellier, 1991). Royal Society of Chemistry, Cambridge, p 7
Doi Y (1992) In: Vert M (ed) Biodegradable polymers and plastics; the proceedings of the Second International Scientific Workshop on Biodegradable Polymers and Plastics (Montpellier, 1991). Royal Society of Chemistry, Cambridge, p 139
Beiner M, Huth H (2003) Nature Mater 2:595
Hempel E, Budde H, Höring S, Beiner M (2006) J Non-Cryst Solids 352:5013
Al-Hussein M, de Jeu WH, Vranichar L, Pispas S, Hadjichristidis N, Itoh T, Watanabe J (2004) Macromolecules 37:6401
Chen W, Wunderlich B (1999) Macromol Chem Phys 200:283
Inomata K, Nakanishi E, Sakane Y, Koike M, Nose T (2005) J Polym Sci B Polym Phys 43:79
Sandner B, Steurich S, Gopp U (1997) Polymer 38(10):2515
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(2008). Semicrystalline Polymers. In: Electron Microscopy of Polymers. Springer Laboratory. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-36352-1_17
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DOI: https://doi.org/10.1007/978-3-540-36352-1_17
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