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The Small Load Approximation Revisited

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The Quartz Crystal Microbalance in Soft Matter Research

Part of the book series: Soft and Biological Matter ((SOBIMA))

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Abstract

The chapter contains two extensions of the SLA. The first (Sect. 6.1) generalizes the SLA to arbitrary resonator shapes and modes of vibration. The load impedance in this formulation is a 3rd-rank tensor. The formalism shows that the statistical weight in area-averaging is the square of the local amplitude. The second extension (Sect. 6.2) is a perturbation analysis, applied to the model of the parallel plate. The perturbation is carried to 3rd order. The 3rd-order result fixes an inconsistency obtained when treating viscoelastic thin films in air with the conventional SLA.

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Notes

  1. 1.

    Among the resonators having been subjected to modal analysis is the sun. It displays a group of acoustic resonances at frequencies between 2 and 4 mHz [5]. The amplitudes are a few hundred kilometers. Readers may also consult a certain J. W. Goethe on that matter. In his prolog to “Faust” he lets Raphael say:

    The Sun sings out, in ancient mode [!],

    His note among his brother-spheres,

    And ends his pre-determined road

    With peals of thunder for our ears.

    In this case, J. W. got it right: There indeed is a lot of noise on the sun [6].

References

  1. Sakurai, J.J.: Modern Quantum Mechanics. Addison Wesley, New York (1985)

    Google Scholar 

  2. Ohno, I.: Rectangular parallellepiped resonance method for piezoelectric-crystals and elastic-constants of alpha-quartz. Phys. Chem. Miner. 17(5), 371–378 (1990)

    Article  ADS  Google Scholar 

  3. Ogi, H., Ohmori, T., Nakamura, N., Hirao, M.: Elastic, anelastic, and piezoelectric coefficients of alpha-quartz determined by resonance ultrasound spectroscopy. J. Appl. Phys. 100(5), 053511 (2006)

    Google Scholar 

  4. Herrscher, M., Ziegler, C., Johannsmann, D.: Shifts of frequency and bandwidth of quartz crystal resonators coated with samples of finite lateral size. J. Appl. Phys. 101(11), 114909 (2007)

    Google Scholar 

  5. Rabello-Soares, M.C., Korzennik, S.G., Schou, J.: The determination of MDI high-degree mode frequencies. ESA Spec. Publ. 464, 129–136 (2001)

    ADS  Google Scholar 

  6. http://www.guardian.co.uk/science/2003/jul/24/research.science. Accessed 11 Mar 2013

  7. Pechhold, W.: Zur Behandlung von Anregungs- und Störungsproblemen bei akustischen Resonatoren. Acustica 9, 48–56 (1959)

    Google Scholar 

  8. http://en.wikipedia.org/wiki/Euler%E2%80%93Bernoulli_beam_theory. Accessed 30 Mar 2013

  9. Gere, J.M., Timoshenko, S.P.: Mechanics of Materials. PWS Publishing Company, Boston (1997)

    Google Scholar 

  10. Mason, W.P., Baker, W.O., McSkimin, H.J., Heiss, J.H.: Measurement of shear elasticity and viscosity of liquids at ultrasonic frequencies. Phys. Rev. 75(6), 936–946 (1949)

    Article  ADS  Google Scholar 

  11. Raiteri, R., Grattarola, M., Butt, H.J., Skladal, P.: Micromechanical cantilever-based biosensors. Sens. Actuators B-Chem. 79(2–3), 115–126 (2001)

    Article  Google Scholar 

  12. Ballantine, D.S., White, R.M., Martin, S.J., Ricco, A.J., Zellers, E.T., Frye, G.C., Wohltjen, H.: Acoustic Wave Sensors: Theory, Design and Physico-Chemical Applications. Academic Press, New York (1997)

    Google Scholar 

  13. Hempel, U., Lucklum, R., Hauptmann, P.R., EerNisse, E.P., Puccio, D., Diaz, R.F.: Quartz crystal resonator sensors under lateral field excitation—a theoretical and experimental analysis. Measur. Sci. Technol. 19(5), 055201 (2008)

    Google Scholar 

  14. http://www.comsol.com/model/download/177395/models.mems.thickness_shear_quartz_oscillator.pdf. Accessed 20 Feb 2014

  15. Johannsmann, D.: Derivation of the shear compliance of thin films on quartz resonators from comparison of the frequency shifts on different harmonics: a perturbation analysis. J. Appl. Phys. 89(11), 6356–6364 (2001)

    Article  ADS  Google Scholar 

  16. Wolff, O., Seydel, E., Johannsmann, D.: Viscoelastic properties of thin films studied with quartz crystal resonators. Faraday Discuss. 107, 91–104 (1997)

    Article  ADS  Google Scholar 

  17. Wolff, O., Johannsmann, D.: Shear moduli of polystyrene thin films determined with quartz crystal resonators in the sandwich configuration. J. Appl. Phys. 87(9), 4182–4188 (2000)

    Article  ADS  Google Scholar 

  18. Schilling, H., Pechhold, W.: Two quartz resonator methods for investigation of complex shear modulus of polymers. Acustica 22(5), 244 (1969)

    Google Scholar 

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Authors and Affiliations

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Correspondence to Diethelm Johannsmann .

Glossary

Variable

Definition

\( \left\langle . \right\rangle \)

Average

[.]

As a superscript: perturbation order

A

Effective area of the resonator plate

A

ω2-operator

c ijkl

Stiffness tensor

comp

As an index: related to compressional waves

c D

Stiffness tensor at constant electric displacement (Eq. 6.1.33)

cr

As an index: exerted by the crystal

d f

Film thickness

diss

As an index: caused by dissipative processes

d q

Thickness of the resonator

\( {\hat{\mathbf{D}}},{\mathbf{D}} \)

Electric displacement

e

As an index: electrode

\( {\hat{\mathbf{E}}},{\mathbf{E}} \)

Electric field

f n

Resonance frequency at overtone order n

f r

Resonance frequency

f 0

Resonance frequency at the fundamental (f 0 = Z q /(2m q ) = Z q /(2ρ q d q ))

G q

Shear modulus of AT-cut quartz (G q  ≈ 29 × 109 Pa)

h

One of the tensors quantifying piezoelectric coupling (Eq. 6.1.33)

k

Wavenumber

h q

Half the thickness of the resonator plate

I

Second moment of area

Shear compliance

L

Width of a resonator plate

liq

As an index: liquid

m f

Mass per unit area of a film

m q

Mass per unit area of the resonator (m q  = ρ q d q  = Z q /(2f 0))

n

Overtone order

n

n i, Surface normal (a vector)

OC

As an index: resonance condition of the unloaded plate under open-circuit conditions. With no current into the electrodes (more precisely, with vanishing electric displacement everywhere), piezoelectric stiffening is fully accounted for by using the piezoelectrically stiffened shear modulus

q

As an index: quartz resonator

r, r i

Position, a vector and its components

ref

As an index: reference state of a crystal in the absence of a load

r S , r S,i

Position on the resonator surface, a vector and its components

S

As an index: Surface

S

Infinitesimal strain tensor (Eq. 6.1.33)

T

Temperature

T

Stress tensor (Eq. 6.1.33)

û

Displacement (a vector)

Velocity (a vector)

L,ijk

Load impedance in tensor form

mot

Impedance to the left of the transformer in the Mason circuit (Fig. 4.10)

Z q

Acoustic wave impedance of AT-cut quartz (Z q  = 8.8 × 106 kg m−2 s−1)

Γ

Imaginary part of a resonance frequency

δαβ

Kronecker δ (δαβ = 1 if α = β, δαβ = 0 otherwise)

δ(.)

Dirac δ-function

ε −1 S

Inverse dielectric permittivity at constant strain (a tensor) (Eq. 6.1.33)

Δ

As a prefix: A shift induced by the presence of the sample

\( {\hat{\upsigma }}_{S,ij} \)

Stress tensor

η liq

Viscosity

μ

Non-dimensional mass (Eq. 6.2.9)

ρ

Density

ξ liq

Nondimensional shear-wave impedance of the bulk liquid (Eq. 6.2.9)

ω

Angular frequency

ω r

Angular resonance frequency (–ω 2 r is the eigenvalue of the ω2-operator)

ζ

Non-dimensional measure of the inverse square shear-wave impedance (Eq. 6.2.9)

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Johannsmann, D. (2015). The Small Load Approximation Revisited. In: The Quartz Crystal Microbalance in Soft Matter Research. Soft and Biological Matter. Springer, Cham. https://doi.org/10.1007/978-3-319-07836-6_6

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