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The Rotational Isomeric State Model

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References

  1. W. L. Mattice, C. A. Helfer, and A. P. Sokolov, Macromolecules 37, 4711 (2004).

    Google Scholar 

  2. P. Debye, J. Chem. Phys. 14, 636 (1946).

    Google Scholar 

  3. H. A. Kramers and G. H. Wannier, Phys. Rev. 60, 252 (1941).

    Google Scholar 

  4. M. V. Volkenstein, Dokl. Acad. Nauk SSSR 78, 879 (1951).

    Google Scholar 

  5. Yu. Ya. Gotlib, Zh. Tekhn. Fiz. 29, 523 (1959).

    Google Scholar 

  6. T. M. Birshtein and O. B. Ptitsyn, Zh. Tekhn. Fiz. 29, 1048 (1959).

    Google Scholar 

  7. S. Lifson, J. Chem. Phys. 30, 964 (1959).

    Google Scholar 

  8. K. Nagai, J. Chem. Phys. 31, 1169 (1959).

    Google Scholar 

  9. C. A. J. Hoeve, J. Chem. Phys. 32, 888 (1960).

    Google Scholar 

  10. P. J. Flory, Statistical Mechanics of Chain Molecules (Wiley, New York, 1969). Reprinted with the same title by Hanser, Munchen, in 1989.

    Google Scholar 

  11. P. J. Flory, Macromolecules 7, 381 (1974).

    Google Scholar 

  12. W. L. Mattice and U. W. Suter, Conformational Theory of Large Molecules. The Rotational Isomeric State Model in Macromolecular Systems (Wiley, New York, 1994).

    Google Scholar 

  13. M. Rehahn, W. L. Mattice, and U. W. Suter, Adv. Polym. Sci. 131/ 132 (1997).

    Google Scholar 

  14. A. Abe, R. L. Jernigan, and P. J. Flory, J. Am. Chem. Soc. 88, 631 (1966).

    Google Scholar 

  15. A. Abe and J. E. Mark, J. Am. Chem. Soc. 98, 6468 (1976).

    Google Scholar 

  16. M. Hutnik, A. S. Argon, and U. W. Suter, Macromolecules 24, 5956 (1991).

    Google Scholar 

  17. J. H. Ko and J. E. Mark, Macromolecules 8, 869, 874 (1975).

    Google Scholar 

  18. P. J. Flory, V. Crescenzi, and J. E. Mark, J. Am. Chem. Soc. 86, 146 (1964).

    Google Scholar 

  19. C. A. Hoeve, J. Chem. Phys. 35, 1266 (1961).

    Google Scholar 

  20. W. J. Welsh, L. DeBolt, and J. E. Mark, Macromolecules 19, 2978 (1986).

    Google Scholar 

  21. J. A. Semlyen, Trans. Faraday. Soc. 63, 743 (1967).

    Google Scholar 

  22. J. A. Semlyen, Trans. Faraday. Soc. 64, 1396 (1968).

    Google Scholar 

  23. J. W. Mark and J. G. Curro, J. Chem. Phys. 80, 5262 (1984).

    Google Scholar 

  24. T. W. Bates and W. H. Stockmayer, J. Chem. Phys. 45, 2321 (1966).

    Google Scholar 

  25. G. D. Smith, R. L. Jaffe, and D. Y. Yoon, Macromolecules 28, 3166 (1994).

    Google Scholar 

  26. O. Borodin, G. D. Smith, and D. Bedrov, J. Phys. Chem. B 106, 9912 (2002).

    Google Scholar 

  27. R. Bohmer and C. A. Angell, Phys. Rev. B: Condens. Matter & Mater. Phys. 48, 5857 (1993).

    Google Scholar 

  28. P. J. Flory and J. E. Mark, Makromol. Chem. 75, 11 (1964).

    Google Scholar 

  29. G. D. Smith, R. L. Jaffe, and D. Y. Yoon, J. Phys. Chem. 98, 9078 (1994).

    Google Scholar 

  30. D. Chen and W. L. Mattice, Polymer 45, 3877 (2004).

    Google Scholar 

  31. M. S. Beavers and J. A. Semlyen, Polymer 13, 385 (1972).

    Google Scholar 

  32. G. Allegra, E. Benedetti, and C. Pedrone, Macromolecules 3, 727 (1970).

    Google Scholar 

  33. R. H. Boyd and S. M. Breitling, Macromolecules 5, 1 (1972).

    Google Scholar 

  34. L. C. DeBolt and U. W. Suter, Macromolecules 20, 1424 (1987).

    Google Scholar 

  35. M. Vacatello and D. Y. Yoon, Macromolecules 25, 2502 (1992).

    Google Scholar 

  36. L. Carballeira, A. J. Pereiras, and M. A. Rios, Macromolecules 23, 1309 (1990).

    Google Scholar 

  37. O. G. Byutner and G. D. Smith, Macromolecules 32, 8376 (1999).

    Google Scholar 

  38. P. R. Sundararajan, Comput. Polym. Sci. 1, 18 (1991).

    Google Scholar 

  39. I. Bahar, I. Zuniga, R. Dodge, and W. L. Mattice, Macromolecules 24, 2986 (1991).

    Google Scholar 

  40. J. A. Semlyen and P. J. Flory, Trans. Faraday. Soc. 62, 2622 (1966).

    Google Scholar 

  41. R. H. Boyd and L. Kesner, J. Polym. Sci., Polym. Phys. Ed. 19, 393 (1981).

    Google Scholar 

  42. E. Saiz, J. Polym. Sci., Polym. Phys. Ed. 25, 1565 (1987).

    Google Scholar 

  43. R. D. Patil and J. E. Mark, Comput. Theor. Polym. Sci. 10, 189 (2000).

    Google Scholar 

  44. J. E. Mark and P. J. Flory, J. Am. Chem. Soc. 87, 1415 (1965).

    Google Scholar 

  45. G. D. Smith, D. Y. Yoon, and R. L. Jaffe, Macromolecules 26, 5213 (1993).

    Google Scholar 

  46. Y. Sasanuma, H. Ohta, I, Touma, H. Matoba, Y. Hayashi, and A. Kaito, Macromolecules 35, 3748 (2002).

    Google Scholar 

  47. W. G. Miller, D. A. Brant, and P. J. Flory, J. Mol. Biol. 23, 67 (1967).

    Google Scholar 

  48. A. Abe, Macromolecules 13, 546 (1980).

    Google Scholar 

  49. W. L. Mattice, J. Am. Chem. Soc. 102, 2242 (1980).

    Google Scholar 

  50. K. Kato, A. Araki, and A. Abe, Polym. J. 13, 1065 (1981).

    Google Scholar 

  51. J. E. Mark, J. Am. Chem. Soc. 88, 4354 (1966).

    Google Scholar 

  52. T. Ishikawa and K. Nagai, J. Polym. Sci., Part A-2 7, 1123 (1969).

    Google Scholar 

  53. Y. Abe and P. J. Flory, Macromolecules 4, 219 (1971).

    Google Scholar 

  54. G. D. Smith and W. Paul, J. Phys. Chem. A 102, 1200 (1998).

    Google Scholar 

  55. J. E. Mark, J. Am. Chem. Soc. 89, 6829 (1967).

    Google Scholar 

  56. T. Ishikawa and K. Nagai, Polym. J. 1, 116 (1970).

    Google Scholar 

  57. Y. Abe and P. J. Flory, Macromolecules 4, 230 (1971).

    Google Scholar 

  58. J. Guzmán, E. Riande, W. J. Welsh, and J. E. Mark, Makromol. Chem. 183, 2573 (1982).

    Google Scholar 

  59. E. Saiz, E. Riande, J. Guzmán, and J. de Abajo, J. Chem. Phys. 73, 958 (1980).

    Google Scholar 

  60. K. Inomata, N. Phataralaoha, and A. Abe, Comput. Polym. Sci. 1, 126 (1991).

    Google Scholar 

  61. E. Riande, J. Guzmán, E. Saiz, and J. de Abajo, Macromolecules 14, 608 (1981).

    Google Scholar 

  62. E. Riande and J. E. Mark, Macromolecules 11, 956 (1978).

    Google Scholar 

  63. E. Riande, J. Guzmán, W. J. Welsh, and J. E. Mark, Makromol. Chem. 183, 2555 (1982).

    Google Scholar 

  64. E. Riande and J. Guzmán, Macromolecules 12, 952 (1979).

    Google Scholar 

  65. E. Riande, J. Polym. Sci., Polym. Phys. Ed. 14, 2231 (1976).

    Google Scholar 

  66. M. Mutter, U. W. Suter, and P. J. Flory, J. Am. Chem. Soc. 98, 5745 (1976).

    Google Scholar 

  67. P. J. Flory, J. E. Mark, and A. Abe, J. Am. Chem. Soc. 88, 639 (1966).

    Google Scholar 

  68. D. Y. Yoon, P. R. Sundararajan, and P. J. Flory, Macromolecules 8, 776 (1975).

    Google Scholar 

  69. Y. Abe, A. E. Tonelli, and P. J. Flory, Macromolecules 3, 294, 303 (1970).

    Google Scholar 

  70. R. H. Boyd and S. M. Breitling, Macromolecules 5, 279 (1972).

    Google Scholar 

  71. U. W. Suter, S. Pucci, and P. Pino, J. Am. Chem. Soc. 97, 1018 (1975).

    Google Scholar 

  72. U. W. Suter and P. J. Flory, Macromolecules 8, 765 (1975).

    Google Scholar 

  73. R. M. Wolf and U. W. Suter, Macromolecules 17, 669 (1984).

    Google Scholar 

  74. A. E. Tonelli, Macromolecules 18, 1086 (1985).

    Google Scholar 

  75. A. E. Tonelli, Macromolecules 13, 734 (1980).

    Google Scholar 

  76. W. L. Mattice, Macromolecules 10, 1171 (1977).

    Google Scholar 

  77. P. R. Sundararajan, Macromolecules 23, 3178 (1990).

    Google Scholar 

  78. A. Abe, T. Hirano, and T. Tsurura, Macromolecules 12, 1092 (1979).

    Google Scholar 

  79. Y. Sasanuma, Macromolecules 28, 8629 (1995).

    Google Scholar 

  80. A. Abe, Macromolecules 10, 34 (1977).

    Google Scholar 

  81. J. E. Mark, J. Chem. Phys. 56, 451 (1972).

    Google Scholar 

  82. G. D. Smith, P. J. Ludovice, R. L. Jaffe, and D. Y. Yoon, J. Phys. Chem. 99, 164 (1995).

    Google Scholar 

  83. U. W. Suter, J. Am. Chem. Soc. 101, 6481 (1979).

    Google Scholar 

  84. A. Abe, Macromolecules 13, 541 (1980).

    Google Scholar 

  85. Y. Sasanuma, Y. Hayashi, H. Matoba, I. Touma, H. Ohta, M. Sawa- nobori, and A. Kaito, Macromolecules 24, 8216 (2002).

    Google Scholar 

  86. E. D. Akten and W. L. Mattice, Macromolecules 34, 3389 (2001).

    Google Scholar 

  87. P. R. Sundararajan, Macromolecules 11, 256 (1978).

    Google Scholar 

  88. P. J. Flory, J. Am. Chem. Soc. 89, 1798 (1967).

    Google Scholar 

  89. D. Y. Yoon, U. W. Suter, P. R. Sundararajan, and P. J. Flory, Macro- molecules 8, 784 (1975).

    Google Scholar 

  90. E. A. Ovalvo, E. Saiz, R. M. Masegosa, and I. Hernández-Fuentes, Macromolecules 12, 865 (1979).

    Google Scholar 

  91. J. A. Guest, K. Matsuo, W. H. Stockmayer, and U. W. Suter, Macro- molecules 13, 560 (1980).

    Google Scholar 

  92. P. R. Sundararajan and P. J. Flory, J. Am. Chem. Soc. 96, 5025 (1974).

    Google Scholar 

  93. M. Vacatello and P. J. Flory, Macromolecules 19, 405 (1986).

    Google Scholar 

  94. P. R. Sundararajan, Macromolecules 19, 415 (1986).

    Google Scholar 

  95. J. E. Mark and J. H. Ko, J. Polym. Sci., Polym. Phys. Ed. 13, 2221 (1975).

    Google Scholar 

  96. A. D. Williams and P. J. Flory, J. Am. Chem. Soc. 91, 3111 (1969).

    Google Scholar 

  97. R. F. Rapold and U. W. Suter, Macromol. Theory Simul. 3, 1 (1994).

    Google Scholar 

  98. A. E. Tonelli, Macromolecules 18, 2579 (1985).

    Google Scholar 

  99. E. Saiz, E. Riande, M. P. Delgado, and J. M. Barrales-Rienda, Macro- molecules 15, 1152 (1982).

    Google Scholar 

  100. A. E. Tonelli, Polymer 23, 676 (1982).

    Google Scholar 

  101. P. R. Sundararajan, Macromolecules 10, 623 (1977).

    Google Scholar 

  102. W. J. Welsh, J. R. Damewood, Jr., and R. C. West, Macromolecules 22,2947 (1989).

    Google Scholar 

  103. P. R. Sundararajan, Macromolecules 24, 1420 (1991).

    Google Scholar 

  104. J. E. Mark, J. Chem. Phys. 56, 458 (1972).

    Google Scholar 

  105. J. S. Saiz, E. Riande, J. San Román, and E. L. Madruga, Macromol- ecules 23, 786 (1990).

    Google Scholar 

  106. P. R. Sundararajan, Macromolecles 13, 512 (1980).

    Google Scholar 

  107. A. Abe, H. Kobayashi, T. Kawamura, M. Date, T. Uryu, and K. Matsuzaki, Macromolecules 21, 3414 (1988).

    Google Scholar 

  108. P. R. Sundararajan, Macromolecules 21, 1256 (1988).

    Google Scholar 

  109. C. A. Helfer, W. L. Mattice, and D. Chen, Polymer 45, 1297 (2004).

    Google Scholar 

  110. A. E. Tonelli, NMR Spectroscopy and Polymer Microstructures. The Conformational Connection. (VCH, New York, 1989).

    Google Scholar 

  111. M. Karplus, J. Chem. Phys. 30, 11 (1959).

    Google Scholar 

  112. M. Karplus, J. Chem. Phys. 33, 1842 (1960).

    Google Scholar 

  113. M. Karplus, J. Am. Chem. Soc. 35, 2870 (1963).

    Google Scholar 

  114. F. A. Bovey, A. I. Brewster, D. J. Patel, A. E. Tonelli, and D. A. Torchia, Acct. Chem. Res. 5, 193 (1972).

    Google Scholar 

  115. A. Abe, J. Am. Chem. Soc. 90, 2205 (1968).

    Google Scholar 

  116. W. K. Kim and W. L. Mattice, Comput. Theor. Polym. Sci. 8, 339 (1998).

    Google Scholar 

  117. A. D. Williams and P. J. Flory, J. Polym. Sci.: Part A-2 6, 1945 (1968).

    Google Scholar 

  118. A. D. Williams and P. J. Flory, J. Polym. Sci.: Part A-2 5, 147 (1967).

    Google Scholar 

  119. F. Mendicuti, E. Saiz, and W. L. Mattice, Polymer 33, 4908 (1992).

    Google Scholar 

  120. G. C. Rutledge, Macromolecules 25, 3984 (1992).

    Google Scholar 

  121. E. Yurtsever and B. Erman, Polymer 34, 3887 (1993).

    Google Scholar 

  122. V. S. R. Rao, N. Yathindra, and P. R. Sundararajan, Biopolymers 8, 325 (1969).

    Google Scholar 

  123. D. A. Brant and W. L. Dimpfl, Macromolecules 3, 655 (1970).

    Google Scholar 

  124. D. A. Brant and K. D. Goebel, Macromolecules 8, 522 (1975).

    Google Scholar 

  125. W. K. Olson and P. J. Flory, Biopolymers 11, 1 (1972).

    Google Scholar 

  126. D. A. Brant and P. J. Flory, J. Am. Chem. Soc. 87, 2788 (1965).

    Google Scholar 

  127. W. G. Miller and P. J. Flory, J. Mol. Biol. 15, 298 (1966).

    Google Scholar 

  128. D. A. Brant, W. G. Miller, and P. J. Flory, J. Mol. Biol. 23, 47 (1967).

    Google Scholar 

  129. D. A. Brant, A. E. Tonelli, and P. J. Flory, Macromolecules 2, 225, 228 (1969).

    Google Scholar 

  130. J. E. Mark, J. Chem. Phys. 56, 458 (1972).

    Google Scholar 

  131. C. A. Helfer and W. L. Mattice, Polymer 46, 4361 (2005).

    Google Scholar 

  132. D. C. Poland and H. A. Scheraga, Theory of Helix-Coil Transitions in Biopolymers; Statistical Mechanical Theory of Order-Disorder Transitions in Biological Macromolecules (Academic, New York, 1970).

    Google Scholar 

  133. A. E. Tonelli and F. C. Schilling, Acct. Chem. Res. 14, 223 (1981).

    Google Scholar 

  134. A. Abe, J. Am. Chem. Soc. 92, 1136 (1970).

    Google Scholar 

  135. E. Saiz and M. P. Tarazona, Macromolecules 16, 1128 (1983).

    Google Scholar 

  136. U. W. Suter, Macromolecules 14, 523 (1980).

    Google Scholar 

  137. U. W. Suter and P. Neuenschwander, Macromolecules 14, 528 (1980).

    Google Scholar 

  138. R. L. Jernigan and P. J. Flory, J. Chem. Phys. 50, 4178 (1969).

    Google Scholar 

  139. H. Jacobson and W. H. Stockmayer, J. Chem. Phys. 18, 1600 (1950).

    Google Scholar 

  140. R. L. Jernigan and P. J. Flory, J. Chem. Phys. 50, 4185 (1969).

    Google Scholar 

  141. P. J. Flory, U. W. Suter, and M. Mutter, J. Am. Chem. Soc. 98, 5733 (1976).

    Google Scholar 

  142. U. W. Suter, M. Mutter, and P. J. Flory, J. Am. Chem. Soc. 98, 5740 (1976).

    Google Scholar 

  143. M. Vacatello, D. Y. Yoon, and P. J. Flory, Macromolecules 23, 1993 (1990).

    Google Scholar 

  144. J. E. Mark and J. G. Curro, J. Chem. Phys. 81, 6408 (1984).

    Google Scholar 

  145. W. L. Mattice, Macromolecules 13, 506 (1980).

    Google Scholar 

  146. L. C. DeBolt and J. E. Mark, Macromolecules 20, 2369 (1987).

    Google Scholar 

  147. R. I. Feigin and D. H. Napper, J. Colloid. Interf. Sci. 71,117 (1979).

    Google Scholar 

  148. M. A. Sharaf, A. Kloczkowski, and J. E. Mark, Comput. Polym. Sci. 4,29 (1994).

    Google Scholar 

  149. W. M. Mattice and J. Skolnick, Macromolecules 14, 863 (1981).

    Google Scholar 

  150. R. F. Rapold and W. L. Mattice, Macromolecules 29, 2457 (1996).

    Google Scholar 

  151. T. Haliloglu and W. L. Mattice, J. Chem. Phys. 108, 6989 (1997).

    Google Scholar 

  152. P. Doruker and W. L. Mattice, Macromolecules 30, 5520 (1997).

    Google Scholar 

  153. T. C. Clancy, M. Putz, J. D. Weinhold, J. G. Curro, and W. L. Mattice, Macromolecules 33, 9452 (2000).

    Google Scholar 

  154. G. Xu, T. C. Clancy, W. L. Mattice, and S. K. Kumar, Macromol- ecules 35, 3309 (2002).

    Google Scholar 

  155. P. J. Flory, J. Polym. Sci., Polym. Phys. Ed. 11, 621 (1973).

    Google Scholar 

  156. K. Matsuo and W. H. Stockmayer, Macromolecules 8, 650 (1975).

    Google Scholar 

  157. F. Heatley, Polymer 13, 218 (1972).

    Google Scholar 

  158. B. C. Laskowski, D. Y. Yoon, D. MacLean, and R. L. Jaffe, Macro- molecules 21, 1629 (1988).

    Google Scholar 

  159. M. Vacatello, D. Y. Yoon, and P. J. Flory, Macromolecules 23, 1993 (1990).

    Google Scholar 

  160. W. L. Mattice, Comput. Polym. Sci. 1, 173 (1991).

    Google Scholar 

  161. W. L. Mattice and H. A. Scheraga, Biopolymers 23, 1701 (1984).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Polymer Science, The University of Akron, 44325-3909, Akron, OH

    Carin A. Helfer

  2. Institute of Polymer Science, The University of Akron, 44325-3909, Akron, OH

    Wayne L. Mattice

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  1. Department of Chemistry, University of Cincinnati, Crosley Tower, Martin Luther King Drive, 45221-0172, Cincinnati, OH

    James E. Mark (Distinguished Research Profess) (Distinguished Research Profess)

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Helfer, C.A., Mattice, W.L. (2007). The Rotational Isomeric State Model. In: Mark, J.E. (eds) Physical Properties of Polymers Handbook. Springer, New York, NY. https://doi.org/10.1007/978-0-387-69002-5_3

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