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Intercalation processes influence the structure and electrophysical properties of lithium-conducting compounds having defect perovskite structure

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Abstract

The structural features and electrophysical properties of lithium-conducting compounds having defect perovskite structure based on Li0.5La0.5Nb2O6 and Li0.5La0.5TiO3 were studied using X-ray diffraction and synchrotron analyses, potentiometry, and complex impedance spectroscopy. Intercalated lithium was found to differently influence ion conductance in titanium- and niobium-containing materials. This difference was found to arise from the structural features of the materials. The systems studied have high chemical diffusion coefficients of lithium (D +Li = 1 × 10−6 cm2/s for Li0.5La0.5Nb2O6 and D +Li = 3.3 × 10−7 cm2/s for Li0.5La0.5TiO3).

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Authors and Affiliations

  1. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    O. I. V’yunov, O. N. Gavrilenko, L. L. Kovalenko, S. D. Kobilyanskaya & A. G. Belous

  2. Interagency Department of Electrochemical Power Production, National Academy of Sciences of Ukraine, Kiev, Ukraine

    S. A. Chernukhin

  3. Lviv Polytechnica National University, Lviv, Ukraine

    L. O. Vasilechko

Authors
  1. O. I. V’yunov
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  2. O. N. Gavrilenko
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  3. L. L. Kovalenko
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  4. S. A. Chernukhin
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  5. L. O. Vasilechko
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  6. S. D. Kobilyanskaya
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  7. A. G. Belous
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Additional information

Original Russian Text © O.I. V’yunov, O.N. Gavrilenko, L.L. Kovalenko, S.A. Chernukhin, L.O. Vasilechko, S.D. Kobilyanskaya, A.G. Belous, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 1, pp. 97–102.

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V’yunov, O.I., Gavrilenko, O.N., Kovalenko, L.L. et al. Intercalation processes influence the structure and electrophysical properties of lithium-conducting compounds having defect perovskite structure. Russ. J. Inorg. Chem. 56, 93–98 (2011). https://doi.org/10.1134/S0036023611010232

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  • DOI: https://doi.org/10.1134/S0036023611010232

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