Abstract
The kinetics and mechanism of the reaction between uracil and hydrogen peroxide in aqueous solution have been investigated. Iron ion admixtures in the solution have been demonstrated to bring about two reaction pathways, one free-radical and the other molecular. The mechanism of the reaction has been analyzed by mathematical modeling methods, kinetic curves illustrating the variation of intermediate product concentrations have been obtained, and the rate constants of elementary reactions have been calculated.
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Original Russian Text © A.Ya. Gerchikov, G.M. Sharipova, G.R. Akhatova, A.G. Mustafin, M.V. Sakhibgareeva, S.I. Spivak, 2015, published in Kinetika i Kataliz, 2015, Vol. 56, No. 5, pp. 571–576.
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Gerchikov, A.Y., Sharipova, G.M., Akhatova, G.R. et al. Kinetics, mechanism, and mathematical model of the reaction between uracil and hydrogen peroxide in aqueous solution. Kinet Catal 56, 563–568 (2015). https://doi.org/10.1134/S0023158415050067
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DOI: https://doi.org/10.1134/S0023158415050067