Skip to main content
SpringerLink
Log in

Model sulfur-resistant NSR catalysts: An XPS study of the interaction of BaO/TiO2-ZrO2 and Pt-BaO/TiO2-ZrO2 with NO2

  • II Russian Congress on Catalysis-Ruscatalysis (Samara, October 2–5, 2014)
  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The interaction of NO2 with BaO/TiO2-ZrO2 and Pt-BaO/TiO2-ZrO2 model NO x storage-reduction (NSR) catalysts prepared on the surface of FeCrAl alloy substrates has been investigated by X-ray photoelectron spectroscopy. The action of nitrogen dioxide on these catalysts at room temperature causes the consecutive formation of surface barium nitrite and nitrate. Supposedly, NO2 reduction yielding barium nitrite at the early stages of the interaction is due to the oxidation of amorphous carbon impurities. The introduction of platinum into the catalyst accelerates nitrogen dioxide sorption. On being exposed to NO2 for a long time, platinum oxidizes to PtO2. This process is more pronounced in the sample containing freshly deposited platinum. Heat treatment of this sample in a vacuum, which coarsens the platinum particles, makes them more resistant to oxidation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Matsumoto, S., CATTECH, 2000, vol. 4, no. 2, p. 102.

    Article  CAS  Google Scholar 

  2. Sedlmair, Ch., Seshan, K., Jentys, A., and Lercher, J.A., Catal. Today, 2002, vol. 75, p. 413.

    Article  CAS  Google Scholar 

  3. Liu, Z. and Anderson, J.A., J. Catal., 2004, vol. 228, p. 243.

    Article  CAS  Google Scholar 

  4. Hirata, H., Hachisuka, I., Ikeda, Y., Tsuji, S., and Matsumoto, S., Top. Catal., 2001, vols. 16–17, p. 145.

    Article  Google Scholar 

  5. Takahashi, N., Suda, A., Hachisuka, I., Sugiura, M., Sobukawa, H., and Shinjoh, H., Appl. Catal., B, 2007, vol. 72, p. 187.

    Article  CAS  Google Scholar 

  6. Andonova, S.M., Senturk, G.S., Kayhan, E., and Ozensoy, E., J. Phys. Chem. C, 2009, vol. 113, p. 11014.

    Article  CAS  Google Scholar 

  7. Smirnov, M.Yu., Kalinkin, A.V., Nazimov, D.A., Bukhtiyarov, V.I., Vovk, E.I., and Ozensoy, E., J. Struct. Chem., 2014, vol. 55, no. 4, p. 757.

    Article  CAS  Google Scholar 

  8. Smirnov, M.Yu., Kalinkin, A.V., Dubkov, A.A., Vovk, E.I., Sorokin, A.M., Nizovskii, A.I., Carberry, B., and Bukhtiyarov, V.I., Kinet. Catal., 2008, vol. 49, no. 6, p. 831.

    Article  CAS  Google Scholar 

  9. Smirnov, M.Yu., Kalinkin, A.V., Dubkov, A.A., Vovk, E.I., Sorokin, A.M., Nizovskii, A.I., Carberry, B., and Bukhtiyarov, V.I., Kinet. Catal., 2011, vol. 52, no. 4, p. 595.

    Article  CAS  Google Scholar 

  10. Moulder, J.F., Stickle, W.F., Sobol, P.E., and Bomben, K.D., Handbook of X-Ray Photoelectron Spectroscopy, Chastain, J., Ed., Eden Prairie, Minn.: PerkinElmer, 1992.

  11. Vasquez, R.P., J. Electron Spectrosc. Relat. Phenom., 1991, vol. 56, p. 217.

    Article  CAS  Google Scholar 

  12. Tsami, A., Grillo, F., Bowker, M., and Nix, R.M., Surf. Sci., 2006, vol. 600, p. 3403.

    Article  CAS  Google Scholar 

  13. Kalinkin, A.V., Sorokin, A.M., Smirnov, M.Yu., and Bukhtiyarov, V.I., Kinet. Catal., 2014, vol. 55, no. 3, p. 354.

    Article  CAS  Google Scholar 

  14. Mudiyanselage, K., Yi, C.-W., and Szanyi, J., Langmuir, 2009, vol. 25, p. 10820.

    Article  CAS  Google Scholar 

  15. Yi, C.-W., Kwak, J.H., and Szanyi, J., J. Phys. Chem. C, 2007, vol. 111, p. 15299.

    Article  CAS  Google Scholar 

  16. Staudt, T., Desikusumastuti, A., and Happel, M., J. Phys. Chem. C, 2008, vol. 112, p. 9835.

    Article  CAS  Google Scholar 

  17. Schmitz, P.J. and Baird, R.J., J. Phys. Chem. B, 2002, vol. 106, p. 4172.

    Article  CAS  Google Scholar 

  18. Wang, Y., Feng, C., Zhang, M., Yang, J., and Zhang, Z., Appl. Catal., B, 2011, vol. 104, p. 268.

    Article  CAS  Google Scholar 

  19. Luan, Y., Jing, L., Xie, M., Shi, X., Fan, X., Cao, Y., and Feng, Y., Phys. Chem. Chem. Phys., 2012, vol. 14, p. 1352.

    Article  CAS  Google Scholar 

  20. Xiang, Q., Yu, J., and Jaronie, M., Phys. Chem. Chem. Phys., 2011, vol. 13, p. 4853.

    Article  CAS  Google Scholar 

  21. Christie, A.B., Lee, J., Sutherland, I., and Walls, J.M., Appl. Surf. Sci., 1983, vol. 15, p. 224.

    Article  CAS  Google Scholar 

  22. Smirnov, M.Yu., Kalinkin, A.V., and Bukhtiyarov, V.I., J. Struct. Chem., 2007, vol. 48, no. 6, p. 1053.

    Article  CAS  Google Scholar 

  23. Mason, M.G., Phys. Rev. B: Condens. Matter, 1983, vol. 27, p. 748.

    Article  CAS  Google Scholar 

  24. Baumer, M. and Freund, H.-J., Prog. Surf. Sci., 1999, vol. 61, p. 127.

    Article  CAS  Google Scholar 

  25. Smirnov, M.Yu., Vovk, E.I., Kalinkin, A.V., Pashis, A.V., and Bukhtiyarov, V.I., Kinet. Catal., 2012, vol. 53, no. 1, p. 117.

    Article  CAS  Google Scholar 

  26. Kaushik, V.K., Z. Phys. Chem., 1991, vol. 173, p. 105.

    Article  CAS  Google Scholar 

  27. Silvestre-Albero, J., Sepúlveda-Escribano, A., Rodríguez-Reinoso, F., and Anderson, J.A., J. Catal., 2004, vol. 223, p. 179.

    Article  CAS  Google Scholar 

  28. Zafeiratos, S., Papakonstantinou, G., Jacksic, M.M., and Neophytides, S.G., J. Catal., 2005, vol. 232, p. 127.

    Article  CAS  Google Scholar 

  29. Huang, C.H., Wang, I.K., Lin, Y.M., Tseng, Y.H., and Lu, C.M., J. Mol. Catal. A: Chem., 2010, vol. 316, p. 163.

    Article  CAS  Google Scholar 

  30. Smirnov, M.Yu., Kalinkin, A.V., Vovk, E.I., Sorokin, A.M., and Bukhtiyarov, V.I., XI Eur. Congr. on Catalysis, Lyon, 2013, S5-T2–OR-04.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    M. Yu. Smirnov, A. V. Kalinkin, D. A. Nazimov, A. V. Toktarev & V. I. Bukhtiyarov

  2. Novosibirsk State University, Novosibirsk, 630090, Russia

    D. A. Nazimov & V. I. Bukhtiyarov

Authors
  1. M. Yu. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Kalinkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. A. Nazimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Toktarev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. I. Bukhtiyarov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. Yu. Smirnov.

Additional information

Original Russian Text © M.Yu. Smirnov, A.V. Kalinkin, D.A. Nazimov, A.V. Toktarev, V.I. Bukhtiyarov, 2015, published in Kinetika i Kataliz, 2015, Vol. 56, No. 4, pp. 547–555.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Smirnov, M.Y., Kalinkin, A.V., Nazimov, D.A. et al. Model sulfur-resistant NSR catalysts: An XPS study of the interaction of BaO/TiO2-ZrO2 and Pt-BaO/TiO2-ZrO2 with NO2 . Kinet Catal 56, 540–548 (2015). https://doi.org/10.1134/S0023158415040163

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158415040163

Keywords

Search

Navigation