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Synthesis and Antimicrobial Activity of New Schiff Bases Having the –SiOR Group (R = CH 3 or CH2CH3), and their Transition Metal Complexes

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Abstract

Two new Schiff base ligands containing −SiOCH3 or −SiOCH2CH3 groups, 4-{[(3-trimethoxysilanepropyl)imino]methyl}benzene-1,3-diol (1) Hmsb and 4-{[(3-triethoxysilanepropyl)imino]methyl}benzene-1,3-diol (5) Hesb, have been synthesized by the reaction of 2,4-dihydroxybenzaldehyde with 3-aminopropyltrimethoxysilane and 3-aminopropyltriethoxysilane. Six new transition metal [CuII, NiII and CoII complexes of these Schiff Base ligands were prepared. The complexes are formed by coordination of N, O atoms of the ligands. Their structures were confirmed by elemental analyses, 1H nmr, i.r. and u.v.–vis. spectral data. The analytical data shows that the metal-to-ligand ratio in the Schiff Base complexes contains silane in 1:2. In addition, the antimicrobial activity of (1) Hmsb and (5) Hesb Schiff ligands, and their [M(msb)2] and [M(esb)2] type coordination compounds, were investigated

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References

  1. S.J. Lippard J.M. Berg (1994) Principles of Bioionorganic Chemistry University Science Books California

    Google Scholar 

  2. D.E. Fenton (1995) Bioinorganic Chemistry Oxford University Press Oxford

    Google Scholar 

  3. Y. Yoshikawa E. Ueda K. Kawabe K. Miyabe T. Takino H. Sakurai Y. Kojima (2002) J.Biol. Inorg. Chem 7 68 Occurrence Handle10.1007/s007750100266 Occurrence Handle11862542

    Article  PubMed  Google Scholar 

  4. J.P. Glusker A.K. Katz C.W. Bock (1999) Rigaku J 16 8

    Google Scholar 

  5. A.M. Amado P.J.A. Ribeiro-Claro (2004) Inorg. Biochem 98 561 Occurrence Handle10.1016/j.jinorgbio.2004.01.007

    Article  Google Scholar 

  6. J. Park Y. Chung Y. Suh H. Rhee (2004) Catal. Today 93–95 445 Occurrence Handle10.1016/j.cattod.2004.06.093

    Article  Google Scholar 

  7. P.C. L’Argentiere E.A. Cagnola M.E. Quitoga D.A. Liprandi (2002) Appl. Catal. A 226 253 Occurrence Handle10.1016/S0926-860X(01)00911-5

    Article  Google Scholar 

  8. J. Balsells L. Mejorado M. Phillips F. Ortega G. Aguirre R. Somanathan P.J. Walsh (1998) Tetrahedron Asym 9 4135 Occurrence Handle10.1016/S0957-4166(98)00431-5

    Article  Google Scholar 

  9. J. Sima (2001) Crao. Chem. Acta 74 593

    Google Scholar 

  10. Ouyang X.M., Fei B.L., Okamuro T.A., Sun W.Y., Tang W.X., Ueyama N. (2002). Chem Lett 362

  11. N. Raman Y.P. Raja A. Kulandaismy (2001) Proc. Ind. Acad. Sci (Chem. Sco.) 113 183

    Google Scholar 

  12. A. Datta N.K. Karan S. Mitra G. Rosair (2002) Z. Naturf 576 999

    Google Scholar 

  13. C. Jayabalakrishnan K. Natarajan (2002) Transition Met. Chem 27 75 Occurrence Handle10.1023/A:1013437203247

    Article  Google Scholar 

  14. H. Sharghi M.A. Nasseri (2003) Bull. Chem. Soc. (Jpn.) 76 137 Occurrence Handle10.1246/bcsj.76.137

    Article  Google Scholar 

  15. W.T. Gao Z. Zheng (2002) Molecules 7 511

    Google Scholar 

  16. A.Z. El-Sonbati A.A. El-Bindary (2000) Polish J. Chem 74 621

    Google Scholar 

  17. G.G. Mohamed Z.H.A. El-Wahab (2005) Spectrochim. Acta Part A: Mol. Biomol. Spectrosc 61 1059 Occurrence Handle10.1016/j.saa.2004.06.021

    Article  Google Scholar 

  18. (a). H. Schiff, Ann. Chem. Suppl. 3:343 (1864); (b). H. Schiff, Ann. Chem. 150:193 (1869); (c). H. Schiff, Ann. Chem., 151:186 (1869)

  19. P.J. Toscano L.G. Marzilli (1984) Progr. Inorg. Chem 31 105

    Google Scholar 

  20. A. Valent M. Melník D. Hudecová B. Dudová R. Kivekäs M.R. Sundberg (2002) Inorg. Chim. Acta 340 15 Occurrence Handle10.1016/S0020-1693(02)01062-9

    Article  Google Scholar 

  21. M. Tümer H. Köksal M.K. Şener S. Serin (1999) Transition Met. Chem 24 414 Occurrence Handle10.1023/A:1006973823926

    Article  Google Scholar 

  22. E.P. Plueddemann (1991) Silane Coupling Agents EditionNumber2 Plenum Press New York

    Google Scholar 

  23. (a) K.L. Mittal (ed.), Silanes and Other Coupling Agents, VSP, Utrecht, 1992; (b) K.L. Mittal (ed.), Silanes and Other Coupling Agents, VSP, Utrecht, 2000, vol. 2

  24. D. Zhu W.J.V. Ooij (2004) Electrochim Acta 49 7 1113 Occurrence Handle10.1016/j.electacta.2003.10.023

    Article  Google Scholar 

  25. (a) J.R. Ashes and J.K. Haken, J. Chromatogr., 60:33 (1972); (b) J.R. Ashes and J.K. Haken, Anal. Chem., 45:1131 (1973); (c) J. Appleyard and J.K. Haken, J. Chromatogr., 99:319 (1974); (d) J.K. Haken and D.K.M. Ho, J. Chromatogr., 112:135 (1975)

  26. W. Wasiak W. Urbaniak (1997) J Chromatogr A 757 1–2 137 Occurrence Handle10.1016/S0021-9673(96)00683-8

    Article  Google Scholar 

  27. (a) E. Peker and S. Serin,Synth. React. Inorg. Met.-Org. Chem., 34:859 (2004); (b) N. Kurtoğlu, M. Kurtoğlu and S. Serin, Synth. React. Inorg. Met.- Org. Chem 29:1779 (1999); (c) N. Birbiçer, M. Kurtoğlu and S. Serin, Synth. React. Inorg. Met.-Org. Chem 29:1353 (1999); (d) M. Kurtoglu, and S. Serin, Synth. React. Inorg. Met.-Org. Chem 32:629 (2002); (e) M. Kurtoglu and S. Serin, Synth. React. Inorg. Met.-Org. Chem 31:1129 (2001); (f) M. Kurtoglu, S. Serin, Synth. React. Inorg. Met.-Org. Chem., 31:1229 (2001); (g) M. Kurtoğlu, Synth. React. Inorg. Met.-Org.Chem., 34:967 (2004)

  28. G. Sacarescu R. Ardeleanu L. Sacarescu M. Simionescu (2003) J. Organometallic Chem 685 202 Occurrence Handle10.1016/S0022-328X(03)00642-9

    Article  Google Scholar 

  29. S.D. Bella I. Fragala N. Leonardi S. Sortino (2004) Inorg. Chim. Acta 357 3865 Occurrence Handle10.1016/j.ica.2004.04.011

    Article  Google Scholar 

  30. T. Ogasawara A. Yoshino H. Okabayashi C.J. O’Connor (2001) A: Physicochem Eng. Aspects 180 317 Occurrence Handle10.1016/S0927-7757(00)00813-X

    Article  Google Scholar 

  31. N.S. Biradar G.V. Karajagi T.M. Aminabhavi (1984) Inorg. Chim. Acta 82 211 Occurrence Handle10.1016/S0020-1693(00)82494-9

    Article  Google Scholar 

  32. J.P. Kim Y.S. Cho J.W. Kang J.J. Kim J.S. Lee (2002) Opt. Mater 21 445 Occurrence Handle10.1016/S0925-3467(02)00180-5

    Article  Google Scholar 

  33. J. Sanmartin M.R. Bermejo A.M. Gariç-Deibe M. Maneiro C. Large A.J. Costa-Filho (2000) Polyhedron 19 185 Occurrence Handle10.1016/S0277-5387(99)00341-1

    Article  Google Scholar 

  34. J.K. Jaworska (1994) Transition Met. Chem 19 296

    Google Scholar 

  35. R.C. Maurya D.D. Mishra S. Jain M. Jaiswal (1993) Synth. React. Inorg. Met.-Org Chem 23 1335

    Google Scholar 

  36. F.A. El-Saied M.I. Ayad S.A. Aly (1993) Transition Met. Chem 18 279

    Google Scholar 

  37. J. Zhao J. Han Y. Zhang (2005) J. Mol. Catal. A: Chem 231 129 Occurrence Handle10.1016/j.molcata.2005.01.006

    Article  Google Scholar 

  38. Cazacu M., Marcu M., Vlad A., Vasiliu M. (2004). J Macromol Sci Part A–Pure Appl Chem 565

  39. C.H. Collins P.M. Lyne (1970) Microbial Methods University Park Press Baltimore

    Google Scholar 

  40. S.K. Sengupta O.P. Pandey B.K. Srivastava V.K. Sharma (1998) Transition Met. Chem 23 349 Occurrence Handle10.1023/A:1006986131435

    Article  Google Scholar 

  41. Kurtoğlu M., İspir E., Kurtoðlu N., Toroğlu S., Serin S. Transition Met Chem., (2005) (in press)

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Arts, Kahramanmaraş Sütçü İmam University, Kahramanmaraş, 46050-9, Turkey

    Esin İspir, Mükerrem Kurtoğlu & Fatih Purtaş

  2. Department of Chemistry, Faculty of Science and Arts, Çukurova University, Adana, 01330, Turkey

    Selahattin Serin

Authors
  1. Esin İspir
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  2. Mükerrem Kurtoğlu
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  3. Fatih Purtaş
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  4. Selahattin Serin
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Correspondence to Mükerrem Kurtoğlu.

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İspir, E., Kurtoğlu, M., Purtaş, F. et al. Synthesis and Antimicrobial Activity of New Schiff Bases Having the –SiOR Group (R = CH 3 or CH2CH3), and their Transition Metal Complexes. Transition Met Chem 30, 1042–1047 (2005). https://doi.org/10.1007/s11243-005-6311-5

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  • DOI: https://doi.org/10.1007/s11243-005-6311-5

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