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Synthesis, crystal structure and thermochemical study on a novel ternary coordination compound [Bi(C7H5O3)3C12H8N2]

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Abstract

A new ternary bismuth complex [Bi(C7H5O3)3C12H8N2] (C7H6O3, o-hydroxybenzoic acid; C12H8N2, 1,10-phenanthroline monohydrate) and its crystal were prepared and characterized. The results showed that the crystal is triclinic, space group P ī with a = 10.184(2) Å, b = 11.807(2) Å, c = 12.893(3) Å, α = 76.81(3)°, β = 68.79(3)°, γ = 80.85(3)°, Z = 2, Dc = 1.891 g cm−3, F(000) = 776. The crystal contains a mononuclear molecule. Bi3+ is eight-coordinated by three bidentate chelating carboxylic groups and one o-phenanthroline molecule; C7H6O3 coordinated with Bi3+ in the form of carboxylate; the two nitrogen atoms of C12H8N2 are bidentate-coordinated with Bi3+ forming a chelate ring. At 298.15 K, the standard molar enthalpy of formation of the title complex was estimated to be Δ f H Θ m [Bi(C7H5O3)3C12H8N2 (s), 298.15 K] = −(303.99 ± 4.95) kJ mol−1.

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Acknowledgements

This work was financially supported by the National Natural Sciences Foundation of China (No. 21273190), the Science and Technology Plan Project of Hunan Province, China (No. 2012TP4021-6), the Key Project of Hunan Provincial Key Laboratory Opening Topic Fund Subsidization (No. 2012XGJSZD03) and the Construct Program of the Key Discipline in Hunan Province, China.

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Authors and Affiliations

  1. Department of Chemistry and Life Science, Xiangnan University, Chenzhou, 423043, Hunan Province, People’s Republic of China

    Sheng-Xiong Xiao, Xiao-Fang Zheng, Wen-Juan Li, Chuan-Hua Li, Shu-Li Jiang, Liang Lu, Xu Li & Qiang-Guo Li

  2. Hunan Provincial Key Laboratory of Rare-Precious Metals Compounds and Applications, Chenzhou, 423043, Hunan Province, People’s Republic of China

    Sheng-Xiong Xiao, Chuan-Hua Li, Xu Li & Qiang-Guo Li

  3. Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, People’s Republic of China

    Bu-Xing Han

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  1. Sheng-Xiong Xiao
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Correspondence to Sheng-Xiong Xiao.

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Xiao, SX., Zheng, XF., Li, WJ. et al. Synthesis, crystal structure and thermochemical study on a novel ternary coordination compound [Bi(C7H5O3)3C12H8N2]. J Therm Anal Calorim 120, 1859–1865 (2015). https://doi.org/10.1007/s10973-015-4529-9

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