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One-step synthesized azo-dye modified Mg-Al LDH reinforced biobased semi-aromatic polyamide containing naphthalene ring; study on thermal stability and optical properties

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Abstract

A new series of polyamide Mg-Al layered double hydroxide (LDH) nanocomposites (PANC) were prepared using solution intercalation method. The biobased polyamide (PA) was synthesized using direct polycondensation reaction. Organo azo-dye modified Mg-Al LDH (OLDH) was prepared by one-step method and its effect on the thermal and optical properties of PA was investigated. The X-ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM) results showed the uniform distribution of LDH sheets in the PA matrix. The UV-Vis spectra of PANC showed a blue shift as well as reduction in absorbance intensities and the photoluminescence studies revealed the higher emission intensities for PANC as compared to the neat PA. The results of thermogravimetric analysis (TGA) in both nitrogen and air atmospheres showed that the addition of OLDH up to 5 mass% was slightly improved thermal properties of PA.

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  1. Faculty of Chemistry, Kharazmi University, Tehran, 15719-14911, Iran

    Mohsen Hajibeygi & Mehrdad Omidi-Ghallemohamadi

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  1. Mohsen Hajibeygi
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Correspondence to Mohsen Hajibeygi.

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Hajibeygi, M., Omidi-Ghallemohamadi, M. One-step synthesized azo-dye modified Mg-Al LDH reinforced biobased semi-aromatic polyamide containing naphthalene ring; study on thermal stability and optical properties. J Polym Res 24, 61 (2017). https://doi.org/10.1007/s10965-017-1212-9

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