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Reactive poly(phosphoester)-telechelics

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Abstract

Telechelic poly(phosphoester)s have been prepared via acyclic diene metathesis polymerization with varying molecular weights and end group functionalization. Telechelic alcohols, acids, epoxides, thioesters and bromides with tailorable molecular weights between 3000 and ca. 30,000 g/mol have been prepared and characterized in detail. A high end-group functionality (>99 %) was found in all cases.

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Acknowledgments

The authors thank Prof. Dr. Katharina Landfester for continuous support. F.M. is a recipient of a fellowship through funding of the Excellence Initiative (DFG/GSC 266) in the context of the graduate school of excellence “MAINZ” (Materials Science in Mainz). F.R.W. thanks the Max Planck Graduate Center (MPGC) for support.

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Authors and Affiliations

  1. Max Planck Institut für Polymerforschung, Ackermannweg 10, 55128, Mainz, Germany

    Mark Steinmann, Filippo Marsico & Frederik R. Wurm

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  1. Mark Steinmann
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  2. Filippo Marsico
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  3. Frederik R. Wurm
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Correspondence to Frederik R. Wurm.

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Steinmann, M., Marsico, F. & Wurm, F.R. Reactive poly(phosphoester)-telechelics. J Polym Res 22, 143 (2015). https://doi.org/10.1007/s10965-015-0788-1

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  • DOI: https://doi.org/10.1007/s10965-015-0788-1

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