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Physicochemical study by multi-angle light scattering of water-soluble methacryloylaminophenylarsonate copolymers

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Abstract

The properties of aqueous solutions of polyelectrolytes of sodium o- and p-methacryloylaminophenylarsonate (o- and p- MAPHA-Na) with acrylamide (AAD) or sodium methacrylate (MA-Na): poly(sodium o-methacryloylaminophenylarsonate) (poly(o-MAPHA-Na)), poly(sodium o-methacryloylaminophenylarsonate-co-acrylamide) (poly(o-MAPHA-Na-co-AAD)) (26:74), poly(sodium o-methacryloylaminophenylarsonate-co-sodium methacrylate) (poly(o- MAPHA-Na-co-AM-Na) (35:65) and (14:86), and poly(sodium p-methacryloylaminophenylarsonate-co-sodium methacrylate) (poly(p- MAPHA-Na-co-AM-Na)) (34:66) were studied by off-line, multi-angle light scattering, and in-line using size exclusion chromatography coupled with multi-angle light scattering (SEC-MALS) and refractometric (RI) detection. The Mw value corresponding to the homopolymer poly(o-MAPHA-Na) was 1,300,000 g/mol and for the copolymers the Mw and gyration radius values were decreased when the AAD or AM-Na comonomer composition increased. The macromolecular parameters obtained using SEC-MALS were in agreement with the values measured in the off-line mode. Also, SEC-MALS experiments allowed examination of the radius of gyration-Mw relationship in order to determine the polyelectrolyte conformation (ρ) in solution; these values fell between 0.7-0.53, indicating that the polyelectrolytes are random coils at θ-conditions. In addition, the effect of the pH on the macromolecular parameters was evaluated. At pH 4.5, the Mw and gyration radius values corresponding to poly(o-MAPHA-Na) and poly(o-MAPHA-Na-co-AAD) (26/74) remained very close to those measured at pH 7. However, <r g 2 > values for poly(o-MAPHA-Na-co-AM-Na) copolymers at pH 4.5 were less than pH 7, indicating that the presence of AM-Na reduced the size of the copolymer through intermolecular interactions.

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Acknowledgments

We thank CONACYT (projects 183833 and 157552), PROMEP-SEP (Thematic network of collaboration), and VIEP-BUAP for supporting the research. Also, we thank Dr. Aym Berges from Wyatt.

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Authors and Affiliations

  1. Laboratorio de Polímeros, Centro de Química, Instituto de Ciencias, Benemérita Universidad Autónoma de Puebla (BUAP), Complejo de Ciencias, Edif. 103H, Ciudad Universitaria, Puebla, Puebla, 72570, México

    Guillermo Soriano-Moro, Judith Percino, Margarita Cerón, María Eugenia Castro & Víctor M. Chapela

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  1. Guillermo Soriano-Moro
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  2. Judith Percino
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  3. Margarita Cerón
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  4. María Eugenia Castro
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  5. Víctor M. Chapela
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Correspondence to Guillermo Soriano-Moro.

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Soriano-Moro, G., Percino, J., Cerón, M. et al. Physicochemical study by multi-angle light scattering of water-soluble methacryloylaminophenylarsonate copolymers. J Polym Res 21, 492 (2014). https://doi.org/10.1007/s10965-014-0492-6

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  • DOI: https://doi.org/10.1007/s10965-014-0492-6

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