Skip to main content
SpringerLink
Log in

Improved electrochemical performance of sandwich-like silver nanowires/graphene oxide nanostructure

  • Research Article
  • Published:
Journal of Applied Electrochemistry Aims and scope Submit manuscript

Abstract

This paper demonstrates the fabrication of silver nanowires (AgNWs)/graphene oxide stacking structure for enhanced electrochemical performance. In this sandwich-type structure, the stratum of Ag nanowires acts as a highway bridge between the two layers of graphene oxide, where electrons can be transferred easily through this stacked network. The GO-AgNWs showed a specific capacitance of 251 Fg−1 at 10 mV s−1 and an energy density of 34.05 Wh kg−1 at 0.1 mA, indicating the positive synergistic effect of AgNW and GO. The obtained electrochemical characteristics are encouraging and found to be mainly attributed to an effective combination of graphene oxide and AgNWs.

Graphical Abstract

Figure shows the steps involved in the development of the sandwich-like AgNW/GO nanostructure electrode.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Frackowiak E (2007) Carbon materials for supercapacitor application. Phys Chem Chem Phys 9:1774–1785

    Article  CAS  Google Scholar 

  2. Lee WH, Moon JH (2014) Monodispersed N-doped carbon nanospheres for supercapacitor application. ACS Appl Mater Interfaces 6:13968–13976

    Article  CAS  Google Scholar 

  3. Liu Y, Shi Z, Gao Y, An W, Cao Z, Liu J (2016) Biomass-swelling assisted synthesis of hierarchical porous carbon fibers for supercapacitor electrodes.ACS Appl Mater Interfaces. doi:10.1021/acsami.5b11558

    Google Scholar 

  4. Yao Y, Ma C, Wang J, Qiao W, Ling L, Long D (2015) Rational design of high-surface-area carbon nanotube/microporous carbon core–shell nanocomposites for supercapacitor electrodes. ACS Appl Mater Interfaces 7:4817–4825

    Article  CAS  Google Scholar 

  5. Li X, Wei B (2013) Supercapacitors based on nanostructured carbon. Nano Energy 2:159–173

    Article  CAS  Google Scholar 

  6. Borchardt L, Oschatz M, Kaskel S (2014) Tailoring porosity in carbon materials for supercapacitor applications. Mater Horiz 1:157–168

    Article  CAS  Google Scholar 

  7. Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80(6):1339–1339

    Article  CAS  Google Scholar 

  8. Dimiev AM, Tour JM (2014) Mechanism of graphene oxide formation. ACS Nano 8:3060–3068

    Article  CAS  Google Scholar 

  9. Pei S, Cheng HM (2012) The reduction of graphene oxide. Carbon 50:3210–3228

    Article  CAS  Google Scholar 

  10. Xu B, Yue S, Sui Z, Zhang X, Hou S, Cao G, Yang Y (2011) What is the choice for supercapacitors: graphene or graphene oxide? Energy Environ Sci 4:2826–2830

    Article  CAS  Google Scholar 

  11. Hu ZA, Wang YX, Xie YL, Yang YY, Zhang ZY, Wu HY (2010) Ag nanowires and its application as electrode materials in electrochemical capacitor. J Appl Electrochem 40:341–344

    Article  CAS  Google Scholar 

  12. Yu Z, Li C, Abbitt D, Thomas J (2014) Flexible, sandwich-like Ag-nanowire/PE.:PSS nanopillar/MnO2 high performance supercapacitors. J Mater Chem A 2:10923–10929

    Article  CAS  Google Scholar 

  13. Zhi J, Zhao W, Liu X, Chen A, Liu Z, Huang F (2014) Highly conductive ordered mesoporous carbon based electrodes decorated by 3D graphene and 1D silver nanowire for flexible supercapacitor. Adv Funct Mater 24:2013–2019

    Article  CAS  Google Scholar 

  14. Yuksel R, Coskun S, Unalan HE (2016) Coaxial silver nanowire network core molybdenum oxide shell supercapacitor electrodes. Electrochim Acta 193:39–44

    Article  CAS  Google Scholar 

  15. Yun YS, Kim DH, Kim B, Park HH, Jin HJ (2012) Transparent conducting films based on graphene oxide/silver nanowire hybrids with high flexibility. Synth Met 162:1364–1368

    Article  CAS  Google Scholar 

  16. Shaw JE, Perumal A, Bradley DC, Stavrinou PN, Anthopoulos TD (2016) Nanoscale current spreading analysis in solution-processed graphene oxide/silver nanowire transparent electrodes via conductive atomic force microscopy. J Appl Phys 119:195501–195508

    Article  Google Scholar 

  17. Chen R, Das SR, JeongC, Khan MR, Janes DB, AlamMA (2013) Co-percolating graphene-wrapped silver nanowire network for high performance, highly stable, transparent conducting electrodes. Adv Funct Mater. doi:10.1002/adfm.201300124

    Google Scholar 

  18. Meenakshi P, Karthick R, SelvarajM, Ramu S (2014) Investigations on reduced graphene oxide film embedded with silver nanowires as a transparent conducting electrode. Sol Energy Mater Sol Cells 128:264–269

    Article  CAS  Google Scholar 

  19. Li SM, Wang YS, Hsiao ST, Liao WH, Lin CW, Yang SY, Tien HW, Ma CC, Hu CC (2015) Fabrication of a silver nanowire-reduced graphene oxide-based electrochemical biosensor and its enhanced sensitivity in the simultaneous determination of ascorbic acid, dopamine, and uric acid. J Mater Chem C 3:9444–9453

    Article  CAS  Google Scholar 

  20. Khosrozadeh A, Darabi MA, Xing M, Wang Q (2016) Flexible electrode design: fabrication of freestanding polyaniline-based composite films for high-performance supercapacitors. ACS Appl Mater Interfaces 8:11379–11389

    Article  CAS  Google Scholar 

  21. Zhang K, Zhang Y, Wang S (2013) Enhancing thermoelectric properties of organic composites through hierarchical nanostructures. Sci Rep 3:3448–3455

    Google Scholar 

  22. Mishra SK, Tripathi SN, Choudhary V, Gupta BD (2014) SPR based fibre optic ammonia gas sensor utilizing nanocomposite film of PMMA/reduced graphene oxide prepared by in situ polymerization. Sens Actuators B 199:190–200

    Article  CAS  Google Scholar 

  23. Wilson NR, Pandey PA, Beanland R, Young RJ, Kinloch IA, Gong L, LiuZ, Suenaga K, Rourke JP, YorkS J, Sloan J, (2009) Graphene oxide: structural analysis and application as a highly transparent support for electron microscopy. ACS Nano 3:2547–2556

    Article  CAS  Google Scholar 

  24. Xu B, Wu F, Wang F, Chen S, Cao GP, Yang YS (2006) Single-walled carbon nanotubes as electrode materials for supercapacitors. Chin J Chem 241505–1508

    Article  CAS  Google Scholar 

  25. Bao Q, Bao S, Li CM, Qi X, Pan C, ZangJ, Lu Z, Li Y, Tang DY, Zhang S, Lian K (2008) Supercapacitance of solid carbon nanofibers made from ethanol flames. J Phys Chem C 112:3612–3618

    Article  CAS  Google Scholar 

  26. Patil DS, Shaikh JS, Pawar SA, Devan RS, Ma YR, Moholkar AV, Kim JH, Kalubarme RS, Park CJ, Patil PS (2012) Investigations on silver/polyaniline electrodes for electrochemical supercapacitors. Phys Chem Chem Phys 14:11886–11895

    Article  CAS  Google Scholar 

  27. Patil DS, Pawar SA, Devan RS, Gang MG, Ma YR, Kim JH, Patil PS (2013) Electrochemical supercapacitor electrode material based on polyacrylic acid/polypyrrole/silver composite. Electrochim Acta 105:569–577

    Article  CAS  Google Scholar 

  28. Theophile N, Jeong HK (2017) Electrochemical properties of poly(vinyl alcohol) and graphene oxide composite for supercapacitor applications. Chem Phys Lett 669:125–129

    Article  CAS  Google Scholar 

  29. BuI YY, Huang R (2017) Fabrication of CuO-decorated reduced graphene oxide nanosheets for supercapacitor applications. Ceram Int 43:45–50

    Article  Google Scholar 

  30. Jeon H, Han JH, Yu DM, Lee JY, Kim TH, Hong YT (2017) Synthesis of mesoporous reduced graphene oxide by Zn particles for electrodes of supercapacitor in ionic liquid electrolyte. J Ind Eng Chem 45:105–110

    Article  CAS  Google Scholar 

  31. Sliwak A, Grzyb B, Díez N, Gryglewicz G (2017) Nitrogen-doped reduced graphene oxide as electrode material for high rate supercapacitors. Appl Surf Sci 399:265–271

    Article  CAS  Google Scholar 

  32. Dezfuli AS, Ganjali MR, Naderi HR (2017) Anchoring samarium oxide nanoparticles on reduced graphene oxide for high-performance supercapacitor. Appl Surf Sci 402:245–253

    Article  CAS  Google Scholar 

  33. Nathan DMGT, Boby SJM (2017) Hydrothermal preparation of hematite nanotubes/reduced graphene oxide nanocomposites as electrode material for high performance supercapacitors. J Alloys Compd 700:67–74

    Article  CAS  Google Scholar 

  34. Yuan D, Zeng J, Kristan N, Wang Y, Wang X (2009) Bi2O3 deposited on highly ordered mesoporous carbon for supercapacitors. Electrochem Commun 11:313–317

    Article  CAS  Google Scholar 

  35. Patil DS, Shaikh JS, Dalavi DS, Kalagi SS, Patil PS (2011) Chemical synthesis of highly stable PVA/PANI films for supercapacitor application. Mater Chem Phys 128:449–455

    Article  CAS  Google Scholar 

  36. Li X, ZangX, Li Z, Li X, Li P, Sun P, Lee X, Zhang R, Huang Z, Wang K, Wu D, Kang F, Zhu H (2013) Large-area flexible core–shell graphene/porous carbon woven fabric films for fiber supercapacitor electrodes. Adv Funct Mater 23:4862–4869

    CAS  Google Scholar 

  37. Patil DS, Pawar SA, Kim JH, Patil PS, Shin JC (2016) Facile preparation and enhanced capacitance of the Ag-PE.:PSS/polyaniline nanofiber network for supercapacitors. Electrochim Acta 213:680–690

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This study was supported by the Korea Evaluation Institute of Industrial Technology (KEIT) Grant 10052824 funded by the Korea government (MOTIE).

Author information

Authors and Affiliations

  1. Department of Physics, Yeungnam University, Gyeongsan, Gyeongbuk, 38541, South Korea

    Dipali S. Patil, Sachin A. Pawar & Jae Cheol Shin

  2. Thin Film Materials Laboratory, Department of Physics, Shivaji University, Kolhapur, 416 004, India

    Pramod S. Patil

Authors
  1. Dipali S. Patil
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Sachin A. Pawar
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Pramod S. Patil
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jae Cheol Shin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Dipali S. Patil or Jae Cheol Shin.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Patil, D.S., Pawar, S.A., Patil, P.S. et al. Improved electrochemical performance of sandwich-like silver nanowires/graphene oxide nanostructure. J Appl Electrochem 47, 487–496 (2017). https://doi.org/10.1007/s10800-017-1053-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10800-017-1053-6

Keywords

Search

Navigation