Abstract
A self-supporting binder-free tin oxide (SnO2) graphene nanocomposite electrode was synthesized through a novel one step solvothermal treatment of graphene oxide (GO) paper. To characterize this electrode X-ray Diffraction, Scanning Electron Microscopy, Atomic Force Microscopy, Raman spectroscopy, Energy-dispersive X-ray spectroscopy, cyclic voltammetry, and constant current galvanic cycling were performed. The solvothermal treatment simultaneously coats amorphous carbon and SnO2 nanoparticles onto the surface of GO paper, while reducing the GO nanosheets to graphene nanosheets (GNS). This creates a SnO2/GNS film that is flexible, free-standing, and can be used as the negative electrode in lithium ion batteries to deliver a reversible capacity of 400 mA h g−1 after repeated cycling.
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References
Hossain S (1984) Rechargeable lithium batteries (ambient temperature). In: Linden D (ed) Handbook of batteries, vol 30, 2nd edn. McGraw-Hill Inc, New York, pp 36.31–36.44
Doughty D, Roth PE (2012) A general discussion of Li ion battery safety. Electrochem Soc Interface 21(2):37–44
Bruce PG, Scrosati B, Tarascon JM (2008) Nanomaterials for rechargeable lithium batteries. Angew Chem Int Ed 47(16):2930–2946
Chen CM, Zhang Q, Huang JQ, Zhang W, Zhao XC, Huang CH, Wei F, Yang YG, Wang MZ, Su DS (2012) Chemically derived graphene-metal oxide hybrids as electrodes for electrochemical energy storage: pre-graphenization or post-graphenization? J Mater Chem 22(28):13947–13955
Li J, Zhao Y, Wang N, Guan L (2011) A high performance carrier for SnO2 nanoparticles used in lithium ion battery. Chem Commun 47(18):5238–5240
Zhu X, Zhu Y, Murali S, Stoller MD, Ruoff RS (2011) Reduced graphene oxide/tin oxide composite as an enhanced anode material for lithium ion batteries prepared by homogenous coprecipitation. J Power Sour 196(15):6473–6477
U.S. Department of Health and Human Services (2005) Production, import/export, use, and disposal. In: Toxicological profile for tin and tin compounds. Agency for toxic substances and disease registry. U.S. Department of Health and Human Services, Washington, DC, pp 243–248
Tao HC, Fan LZ, Mei Y, Qu X (2011) Self-supporting Si/reduced graphene oxide nanocomposite films as anode for lithium ion batteries. Electrochem Commun 13(12):1332–1335
Chen Z, Zhou M, Cao Y, Ai X, Yang H, Liu J (2012) In situ generation of few-layer graphene coatings on SnO2-SiC core-shell nanoparticles for high-performance lithium-ion storage. Adv Energy Mater 2(1):95–102
Li X, Meng X, Liu J, Geng D, Zhang Y, Banis MN, Li Y, Yang J, Li R, Sun X, Cai M, Verbrugge MW (2012) Tin oxide with controlled morphology and crystallinity by atomic layer deposition onto graphene nanosheets for enhanced lithium storage. Adv Funct Mater 22(8):1647–1654
Zhang HX, Feng C, Zhai YC, Jiang KL, Li QQ, Fan SS (2009) Cross-stacked carbon nanotube sheets uniformly loaded with SnO2 nanoparticles: a novel binder-free and high-capacity anode material for lithium-ion batteries. Adv Mater 21(22):2299–2304
Szabo DV, Kilibarda G, Schlabach S, Trouillet V, Bruns M (2012) Structural and chemical characterization of SnO2-based nanoparticles as electrode material in Li-ion batteries. J Mater Sci 47(10):4383–4391
Kim JH, Khanal S, Islam M, Khatri A, Choi D (2008) Electrochemical characterization of vertical arrays of tin nanowires grown on silicon substrates as anode materials for lithium rechargeable microbatteries. Electrochem Commun 10(11):1688–1690
Park MS, Wang GX, Kang YM, Wexler D, Dou SX, Liu HK (2007) Preparation and electrochemical properties of SnO2 nanowires for application in lithium-ion batteries. Angew Chem Int Ed 46(5):750–753
Xia X, Li S, Wang X, Liu J, Wei Q, Zhang X (2013) Structures and properties of SnO2 nanofibers derived from two different polymer intermediates. J Mater Sci 48(9):3378–3385
Wang J, Du N, Zhang H, Yu J, Yang D (2011) Large-scale synthesis of SnO2 nanotube arrays as high-performance anode materials of Li-ion batteries. J Phys Chem C 115(22):11302–11305
Liu H, Huang J, Li X, Liu J, Zhang Y (2012) One-step hydrothermal synthesis of flower-like SnO2/carbon nanotubes composite and its electrochemical properties. J Sol-Gel Sci Technol 63(3):569–572
Zou Y, Wang Y (2011) Sn@CNT nanostructures rooted in graphene with high and fast Li-storage capacities. ACS Nano 5(10):8108–8114
Chen T, Pan L, Liu X, Yu K, Sun Z (2012) One-step synthesis of SnO2-reduced graphene oxide-carbon nanotube composites via microwave assistance for lithium ion batteries. R Soc Chem Adv 2(31):11719–11724
Wen Z, Cui S, Kim H, Mao S, Yu K, Lu G, Pu H, Mao O, Chen J (2012) Binding Sn-based nanoparticles on graphene as the anode of rechargeable lithium-ion batteries. J Mater Chem 22(8):3300–3306
Sathish M, Mitani S, Tomai T, Unemoto A, Honma I (2012) Nanocrystalline tin compounds/graphene nanocomposite electrodes as anode for lithium-ion battery. J Solid State Electrochem 16(5):1767–1774
Sathish M, Mitani S, Tomai T, Honma I (2012) Ultrathin SnS2 nanoparticles on graphene nanosheets: synthesis, characterization, and Li-ion storage applications. J Phys Chem C 116(23):12475–12481
Luo B, Wang B, Li XL, Jia YY, Liang MH, Zhi LJ (2012) Graphene-confined Sn nanosheets with enhanced lithium storage capability. Adv Mater 24(26):3538–3543
Wang G, Wang B, Wang X, Park J, Dou S, Ahn H, Kim K (2009) Sn/graphene nanocomposite with 3D architecture for enhanced reversible lithium storage in lithium ion batteries. J Mater Chem 19(44):8378–8384
Jiang S, Yue W, Gao Z, Ren Y, Ma H, Zhao X, Liu Y, Yang X (2013) Graphene-encapsulated mesoporous SnO2 composites as high performance anodes for lithium-ion batteries. J Mater Sci 48(10):3870–3876
Lian P, Wang J, Cai D, Ding L, Jia Q, Wang H (2014) Porous SnO2@C/graphene nanocomposite with 3D carbon conductive network as a superior anode material for lithium-ion batteries. Electrochim Acta 116(10):103–110
Zhu J, Wang D, Wang L, Lang X, You W (2013) Facile synthesis of sulfur coated SnO2-graphene nanocomposites for enhanced lithium ion storage. Electrochim Acta 91(28):323–329
Zhao B, Zhang G, Song J, Jiang Y, Zhuang H, Liu P, Fang T (2011) Bivalent tin ion assisted reduction for preparing graphene/SnO2 composite with good cyclic performance and lithium storage capacity. Electrochim Acta 56(21):7340–7346
Yue W, Yang S, Ren Y, Yang X (2013) In situ growth of Sn, SnO on graphene nanosheets and their application as anode materials for lithium-ion batteries. Electrochim Acta 92(1):412–420
Liang S, Zhu X, Lian P, Yang W, Wang H (2011) Superior cycle performance of Sn@C/graphene nanocomposite as an anode material for lithium-ion batteries. J Solid State Chem 184(6):1400–1404
Wu P, Du N, Liu J, Zhang H, Yu J, Yang D (2011) Solvothermal synthesis of carbon-coated tin nanorods for superior reversible lithium ion storage. Mater Res Bull 46(12):2278–2282
Qiao H, Zheng Z, Zhang L, Xiao L (2008) SnO2@C core-shell spheres: synthesis, characterization, and performance in reversible Li-ion storage. J Mater Sci 43(8):2778–2784
Li X, Zhong Y, Cai M, Balogh MP, Wang D, Zhang Y, Li R, Sun X (2013) Tin-alloy heterostructures encapsulated in amorphous carbon nanotubes as hybrid anodes in rechargeable lithium ion batteries. Electrochim Acta 89(1):387–393
Magasinski A, Dixon P, Hertzberg B, Kvit A, Ayala J, Yushin G (2010) High-performance lithium-ion anodes using a hierarchical bottom-up approach. Nat Mater 9(4):353–358
Yao J, Shen XP, Wang B, Liu H, Wang GX (2009) In situ chemical synthesis of SnO2–graphene nanocomposite as anode materials for lithium-ion batteries. Electrochem Commun 11(10):1849–1852
Zhong C, Wang J, Chen Z, Liu H (2011) SnO2-graphene composite synthesized via an ultrafast and environmentally friendly microwave autoclave method and its use as a superior anode for lithium-ion batteries. J Phys Chem C 115(50):25115–25120
Hassan FM, Chen Z, Yu A, Chen Z, Xiao X (2013) Sn/SnO2 embedded in mesoporous carbon nanocomposites as negative electrode for lithium ion batteries. Electrochim Acta 87(1):844–852
Wang D, Kou R, Choi D, Yang Z, Nie Z, Li J, Saraf LV, Hu D, Zhang J, Graff GL, Liu J, Pope MA, Aksay IA (2010) Ternary self-assembly of ordered metal oxide-graphene nanocomposites for electrochemical energy storage. ACS Nano 4(3):1587–1595
Lee JK, Smith KB, Hayner CM, Kung HH (2010) Silicon nanoparticles-graphene paper composites for Li ion battery anodes. Chem Commun 46(12):2025–2027
Zhao X, Hayner CM, Kung MC, Kung HH (2011) In-plane vacancy-enabled high-power Si-graphene composite electrode for lithium-ion batteries. Adv Energy Mater 1(6):1079–1084
Liu F, Song S, Xue D, Zhang H (2012) Folded structured graphene paper for high performance electrode materials. Adv Mater 24(8):1089–1094
Gwon H, Kim HS, Lee KU, Seo DH, Park YC, Lee YS, Ahn BT, Kang K (2011) Flexible energy storage devices based on graphene paper. Energy Environ Sci 4(4):1277–1283
Abouimrane A, Compton OC, Amine K, Nguyen ST (2010) Non-annealed graphene paper as a binder-free anode for lithium-ion batteries. J Phys Chem C 114(29):12800–12804
Wang C, Li D, Too CO, Wallace GG (2009) Electrochemical properties of graphene paper electrodes used in lithium batteries. Chem Mater 21(13):2604–2606
Liu S, Chen K, Fu Y, Yu S, Bao Z (2012) Reduced graphene oxide paper by supercritical ethanol treatment and its electrochemical properties. Appl Surf Sci 258(13):5299–5303
Pei S, Zhao J, Du J, Ren W, Cheng H-M (2010) Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids. Carbon 48(15):4466–4474
Dikin DA, Stankovich S, Zimney EJ, Piner RD, Dommett GHB, Evmenenko G, Nguyen ST, Ruoff RS (2007) Preparation and characterization of graphene oxide paper. Nature 448(7152):457–460
Chen H, Muller MB, Gilmore KJ, Wallace GG, Li D (2008) Mechanically strong, electrically conductive, and biocompatible graphene paper. Adv Mater 20(18):3557–3561
Myung ST, Hitoshi Y, Sun YK (2011) Electrochemical behavior and passivation of current collectors in lithium-ion batteries. J Mater Chem 21(27):9891–9911
Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339
Ferrari AC, Robertson J (2000) Interpretation of Raman spectra of disordered and amorphous carbon. Phys Rev B 61(20):14095–14107
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The authors would like to thank the financial support of the Chemical and Biomolecular engineering department and the Center for Electrochemical Engineering Research at Ohio University.
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Gildea, A.N., Wang, D. & Botte, G.G. One-step synthesis of self-supporting tin oxide/graphene electrodes for lithium ion batteries. J Appl Electrochem 45, 217–224 (2015). https://doi.org/10.1007/s10800-015-0787-2
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DOI: https://doi.org/10.1007/s10800-015-0787-2