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POSS-Based Covalent Networks: Supporting and Stabilizing Pd for Heck Reaction in Aqueous Media

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Abstract

Palladium nanoparticles supported on Incompletely Condensed Polyhedral Oligomeric Silsesquioxane (IC-POSS) based poly (Acrylamide-co-Hydroxy ethyl methacrylate) as a novel nanohybrid catalyst were synthesized and characterized. This catalyst was found to be an efficient and reusable heterogeneous catalyst for the Heck reaction using water as the solvent in the absence of a phosphine ligand and phase transfer catalyst.

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Acknowledgements

Funding support was provided by the Research Council of University of Tabriz (N.A.) and University of Maragheh (M.A.).

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Authors and Affiliations

  1. Research Laboratory of Polymer, Department of Organic and Biochemistry, Faculty of Chemistry, University of Tabriz, P.O. Box. 55666-16471, Tabriz, Iran

    Nasser Arsalani & Ali Akbari

  2. Department of Chemistry, Faculty of Science, University of Maragheh, Golshahr, P.O. Box. 55181-83111731, Maragheh, Iran

    Mojtaba Amini

  3. Department of Chemical Engineering, University of South Carolina, Columbia, SC, 29208, USA

    Ali Akbari & Esmaiel Jabbari

  4. Institute of Chemical Engineering and Technology, Panjab University, Chandigarh, 160-014, India

    Sanjeev Gautam

  5. Advanced Analysis Center, Korea Institute of Science and Technology, Seoul, 136-791, South Korea

    Keun Hwa Chae

Authors
  1. Nasser Arsalani
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  2. Ali Akbari
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  3. Mojtaba Amini
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  4. Esmaiel Jabbari
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  5. Sanjeev Gautam
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  6. Keun Hwa Chae
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Corresponding authors

Correspondence to Nasser Arsalani, Mojtaba Amini or Esmaiel Jabbari.

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Arsalani, N., Akbari, A., Amini, M. et al. POSS-Based Covalent Networks: Supporting and Stabilizing Pd for Heck Reaction in Aqueous Media. Catal Lett 147, 1086–1094 (2017). https://doi.org/10.1007/s10562-016-1954-8

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  • DOI: https://doi.org/10.1007/s10562-016-1954-8

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