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Mesoporous KIT-6 Supported Pd–M x O y (M = Ni, Co, Fe) Catalysts with Enhanced Selectivity for p-Chloronitrobenzene Hydrogenation

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Abstract

Bimetallic PdM (M = Ni, Co, Fe) nanoparticles were synthesized using butyllithium as a reductant, and were used to prepare Pd–M x O y /KIT-6 catalysts by appropriate oxidation and reduction treatments. These catalysts showed higher selectivity in the hydrogenation of p-chloronitrobenzene to p-chloroaniline than Pd/KIT-6. Relevant characterization was conducted using X-ray diffraction, transmission electron microscopy, N2 adsorption–desorption, X-ray photoelectron spectroscopy, inductive coupled plasma emission spectrometer, and H2 temperature-programmed reduction.

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Acknowledgments

S. Zhou thanks the Ministry of Science and Technology of China (Grant No. 2012DFA40550) for financial supports. H. Yu thanks the financial support from Ningbo Municipal Natural Science Foundation (Grant No. 2013A610038). Z. Ma acknowledges the financial support by National Natural Science Foundation of China (Grant No. 21007011).

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Authors and Affiliations

  1. College of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142, Liaoning, People’s Republic of China

    Xuejun Zhang & Peipei Zhang

  2. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, Zhejiang, People’s Republic of China

    Peipei Zhang, Hongbo Yu & Shenghu Zhou

  3. Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science and Engineering, Fudan University, Shanghai, 200433, People’s Republic of China

    Zhen Ma

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  1. Xuejun Zhang
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  2. Peipei Zhang
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  3. Hongbo Yu
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  4. Zhen Ma
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  5. Shenghu Zhou
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Correspondence to Zhen Ma or Shenghu Zhou.

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Zhang, X., Zhang, P., Yu, H. et al. Mesoporous KIT-6 Supported Pd–M x O y (M = Ni, Co, Fe) Catalysts with Enhanced Selectivity for p-Chloronitrobenzene Hydrogenation. Catal Lett 145, 784–793 (2015). https://doi.org/10.1007/s10562-015-1480-0

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  • DOI: https://doi.org/10.1007/s10562-015-1480-0

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