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A Facile Preparation of Highly Active Au/MgO Catalysts for Aerobic Oxidation of Benzyl Alcohol

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Abstract

A facile method was proposed for one-step preparation of Au/MgO. In this method, the Au/MgO kept both basic sites of MgO crystal and low size of gold nanoparticles. Compared with those of Au/MgO prepared by conventional methods, Au/MgO by this method had the highest activity.

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References

  1. Zope BN, Hibbitts DD, Neurock M, Davis RJ (2010) Science 330:74–78

    Article  CAS  Google Scholar 

  2. Pina CD, Falletta E, Rossi M (2012) Chem Soc Rev 41:350–369

    Article  Google Scholar 

  3. Villa A, Veith GM, Prati L (2010) Angew Chem Int Ed 49:4499–4502

    Article  CAS  Google Scholar 

  4. Davis SE, Ide MS, Davis RJ (2013) Green Chem 15:17–45

    Article  CAS  Google Scholar 

  5. Tanaka A, Hashimoto K, Kominami H (2012) J Am Chem Soc 134:14526–14533

    Article  CAS  Google Scholar 

  6. Enache DI, Knight DW, Hutchings GJ (2005) Catal Lett 103:43–52

    Article  CAS  Google Scholar 

  7. Boronat M, Corma A, Illas F, Radilla J, Ródenas T, Sabater MJ (2011) J Catal 278:50–58

    Article  CAS  Google Scholar 

  8. Villa A, Chan-Thaw CE, Veith GM, More KL, Ferri D, Prati L (2011) ChemCatChem 3:1612–1618

    Article  CAS  Google Scholar 

  9. Hallett-Tapley GL, Silvero MJ, Bueno-Alejo CJ, González-Béjar M, McTiernan CD, Grenier M, Netto-Ferreira JC, Scaiano JC (2013) J Phys Chem C 117:12279–12288

    Article  CAS  Google Scholar 

  10. Fang W, Chen J, Zhang Q, Deng W, Wang Y (2011) Chem Eur J 17:1247–1256

    Article  CAS  Google Scholar 

  11. Takei T, Akita T, Nakamura I, Fujitani T, Okumura M, Okazaki K, Huang J, Ishida T, Haruta M (2012) In: Gates BC, Jentoft FC (eds) Advances in catalysis, vol 55. Elsevier Inc., San Diego, pp 1–126

  12. Choudhary VR, Dumbre DK (2009) Catal Commun 10:1738–1742

    Article  CAS  Google Scholar 

  13. Brett GL, He Q, Hammond C, Miedziak PJ, Dimitratos N, Sankar M, Herzing AA, Conte M, Lopez-Sanchez JA, Kiely CJ, Knight DW, Taylor SH, Hutchings GJ (2011) Angew Chem Int Ed 123:10318–10321

    Article  Google Scholar 

  14. Sunagawa Y, Yamamoto K, Takahashi H, Muramatsu A (2008) Catal Today 132:81–87

    Article  CAS  Google Scholar 

  15. Costa VV, Estrada M, Demidova Y, Prosvirin I, Kriventsov V, Cotta RF, Fuentes S, Simakov A, Gusevskaya EV (2012) J Catal 292:148–156

    Article  CAS  Google Scholar 

  16. Jia C, Liu Y, Bongard H, Schüth F (2010) J Am Chem Soc 132:1520–1522

    Article  CAS  Google Scholar 

  17. Huangfu X (2013) The effect of preparation methods and basicity of supports on catalytic performance of Au in oxidation of benzyl alcohol. Thesis of Shaanxi Normal University, PR China

  18. Bartley JK, Xu C, Lloyd R, Enache DI, Knight DW, Hutchings GJ (2012) Appl Catal B 128:31–38

    Article  CAS  Google Scholar 

  19. Estrada M, Costa VV, Beloshapkin S, Fuentes S, Stoyanov E, Gusevskaya EV, Simakov A (2014) Appl Catal A 473:96–103

    Article  CAS  Google Scholar 

  20. Wang M, Ma J, Chen C, Lu F, Du Z, Cai J, Xu J (2012) Chem Commun 48:10404–10406

    Article  CAS  Google Scholar 

  21. Min BK, Friend CM (2007) Chem Rev 107:2709–2724

    Article  CAS  Google Scholar 

  22. Li Z, Ciobanu CV, Hu J, Palomares-Báez J, Rodríguez-López J, Richards R (2011) Phys Chem Chem Phys 13:2582–2589

    Article  CAS  Google Scholar 

  23. Alhumaimess M, Lin Z, He Q, Lu L, Dimitratos N, Dummer NF, Conte M, Taylor SH, Bartley JK, Kiely CJ, Hutchings GJ (2014) Chem Eur J 20:1701–1710

    Article  CAS  Google Scholar 

  24. Corma A, Garcia H (2008) Chem Soc Rev 37:2096–2126

    Article  CAS  Google Scholar 

  25. Cao E, Sankar M, Nowicka E, He Q, Morad M, Miedziak PJ, Taylor SH, Knight DW, Bethell D, Kiely CJ, Gavriilidis A, Hutchings GJ (2013) Catal Today 203:146–152

    Article  CAS  Google Scholar 

  26. Meenakshisundaram S, Nowicka E, Miedziak PJ, Brett GL, Jenkins RL, Dimitratos N, Taylor SH, Knight DW, Bethell D, Hutchings GJ (2010) Faraday Discuss 145:341–356

    Article  CAS  Google Scholar 

  27. Nowicka E, Hofmann JP, Parker SF, Sankar M, Lari GM, Kondrat SA, Knight DW, Bethell D, Weckhuysen BM, Hutchings GJ (2013) Phys Chem Chem Phys 15:12147–12155

    Article  CAS  Google Scholar 

  28. He Q, Miedziak PJ, Kesavan L, Dimitratos N, Sankar M, Lopez-Sanchez JA, Forde MM, Edwards JK, Knight DW, Taylor SH, Kiely CJ, Hutchings GJ (2013) Faraday Discuss 162:365–378

    Article  CAS  Google Scholar 

  29. Yan Y, Chen Y, Jia X, Yang Y (2014) Appl Catal B 156–157:385–397

    Article  Google Scholar 

  30. Xu C, Wang Z, Huangfu X, Wang H (2014) RSC Adv 4:27337–27345

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Program No. 21343015), Natural Science Basic Research Plan in Shaanxi Province of China (Program No. 2013JM2003), and the Fundamental Research Funds for the Central Universities (Program No. GK201302016).

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Correspondence to Chunli Xu.

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Wang, Z., Xu, C. & Wang, H. A Facile Preparation of Highly Active Au/MgO Catalysts for Aerobic Oxidation of Benzyl Alcohol. Catal Lett 144, 1919–1929 (2014). https://doi.org/10.1007/s10562-014-1344-z

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  • DOI: https://doi.org/10.1007/s10562-014-1344-z

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