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Palladium Complex Immobilized on Graphene Oxide as an Efficient and Recyclable Catalyst for Suzuki Coupling Reaction

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Abstract

A graphene supported palladium (Pd) catalyst for Suzuki coupling reaction has been successfully prepared by immobilizing Pd(II) onto graphene oxide surface through the in situ coordination interaction with aminosilane ligand spacers. This catalyst showed high catalytic activities in the Suzuki coupling of various aryl halides and phenylboronic acid. Moreover, it could be readily recycled and reused for several times without discernible loss of its catalytic activity.

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Acknowledgments

This study was supported by the National Natural Science Funds for Excellent Young Scholars (No. 21222608), Program for New Century Excellent Talents in University (No. NCET-12-0392), Research Fund of the National Natural Science Foundation of China (No. 21106099), Foundation for the Author of National Excellent Doctoral Dissertation of China (No. 201251), the Tianjin Natural Science Foundation (No. 11JCYBJC01700) and the Programme of Introducing Talents of Discipline to Universities (No. B06006).

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Authors and Affiliations

  1. State Key Laboratory of Chemical Engineering, School of Chemical Engineering & Technology, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin, 300072, China

    Chan Bai, Qingshan Zhao, Yang Li, Guoliang Zhang, Fengbao Zhang & Xiaobin Fan

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  1. Chan Bai
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  2. Qingshan Zhao
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  3. Yang Li
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  4. Guoliang Zhang
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  5. Fengbao Zhang
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  6. Xiaobin Fan
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Corresponding author

Correspondence to Xiaobin Fan.

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Bai, C., Zhao, Q., Li, Y. et al. Palladium Complex Immobilized on Graphene Oxide as an Efficient and Recyclable Catalyst for Suzuki Coupling Reaction. Catal Lett 144, 1617–1623 (2014). https://doi.org/10.1007/s10562-014-1299-0

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