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Effect of self-assemblies on the dynamics of phloroglucinol-based Belousov-Zhabotinsky reaction: analytical approach

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Abstract

The response of the phloroglucinol-BrO3 −-Ce3+-H2SO4 Belousov-Zhabotinsky (BZ) reaction to the addition of increasing amounts of some surfactants like anionic sodium dodecyl sulphate (SDS), cationic cetyltrimethylammonium bromide (CTAB), neutral TritonX-100 {4-(1,1,3,3-tetramethylbutyl) phenyl polyethylene glycol} and zwitterionic CHAPS{3[(3cholamidopropyl)dimethylammonio]-1-propanesulphonate} is monitored potentiometrically at 30 °C under stirred batch conditions. The presence of these surfactants influences the oscillatory dynamics to an extent that depends on the nature and concentration of the surfactant added. The experimental results suggest that the oscillatory behaviour of the BZ reaction in presence of surfactants owes their behaviour to the peculiar capability of organized surfactant assemblies by selectively partitioning the key species involved in the reaction and their electrostatic interaction with the charged micellar surface in case of ionic micelles. The perturbation effects in case of TritonX-100 have been ascribed to the reaction of alcoholic groups with key species involved in the reaction. For each surfactant, the evolution of oscillations has been found to be characteristic of the surfactant.

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Acknowledgments

The authors are highly thankful to the University Grants Commission, India, for providing financial support and also to the Department of Chemistry, University of Kashmir, Srinagar, for providing infrastructural facilities to accomplish the work conveniently.

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Authors and Affiliations

  1. Department of Chemistry, University of Kashmir, Srinagar, J&K, 190006, India

    Usma Gull, G. M. Peerzada, Nadeem Bashir Ganaie & Shagufta Rashid

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  1. Usma Gull
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  2. G. M. Peerzada
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  3. Nadeem Bashir Ganaie
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  4. Shagufta Rashid
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Correspondence to G. M. Peerzada.

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Gull, U., Peerzada, G.M., Ganaie, N.B. et al. Effect of self-assemblies on the dynamics of phloroglucinol-based Belousov-Zhabotinsky reaction: analytical approach. Colloid Polym Sci 294, 421–431 (2016). https://doi.org/10.1007/s00396-015-3800-8

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  • DOI: https://doi.org/10.1007/s00396-015-3800-8

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