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Surface functionalization of cellulose membrane via heterogeneous “click” grafting of zwitterionic sulfobetaine

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Abstract

In this article, cellulose membranes (CMs) containing zwitterionic sulfobetaine groups were prepared from cellulose membranes with azide groups and N,N-Diethyl-N-Propargyl-N-(3-sulfopropyl) ammonium via click chemistry in a one pot two-step grafting reaction. The CMs were fully characterized by attenuated total reflectance Fourier transform infrared spectra, X-ray photoelectron spectroscopy, X-ray spectroscopy analysis. Results showed that zwitterionic monomers were successfully grafted from CM surfaces and the surface morphologies were investigated by scanning electron microscope and atomic forced microscope. It has been proved that the surface roughness of zwitterionic sulfobetaine functionalized cellulose membranes were greater than the starting cellulose membranes. This new member has potential for biomedical applications.

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Acknowledgments

This work was financially supported by Major State Basic Research Development Program (973 Program) (2012CB722701), National Natural Science Foundation of China (21202127), China National Textile and Apparel Council Scientific and Technical Guidance of the Project Plan (2012005), and Scientific Research Fund of Wuhan Textile University.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, 430200, People’s Republic of China

    Wei Huang & Jingjing Huang

  2. State Key Laboratory Breeding Base of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, Wuhan, 430200, People’s Republic of China

    Wei Huang, Jingjing Huang, Canhong Xu, Shaojin Gu & Weilin Xu

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  1. Wei Huang
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  2. Jingjing Huang
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  3. Canhong Xu
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  4. Shaojin Gu
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  5. Weilin Xu
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Corresponding authors

Correspondence to Jingjing Huang or Shaojin Gu.

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Huang, W., Huang, J., Xu, C. et al. Surface functionalization of cellulose membrane via heterogeneous “click” grafting of zwitterionic sulfobetaine. Polym. Bull. 71, 2559–2569 (2014). https://doi.org/10.1007/s00289-014-1207-1

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  • DOI: https://doi.org/10.1007/s00289-014-1207-1

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