Skip to main content
SpringerLink
Log in

Synthesis, structure and behavior of new polycaprolactam copolymers based on poly (ethylene oxide)–poly (propylene oxide)–poly (ethylene oxide) macroactivators derived from Pluronic block copolymers

  • Original Paper
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

Novel series of poly (CL–co–Pluronic) polymers were successfully synthesized in situ by ring-opening polymerization (ROP) of ε-caprolactam (ε-CL). The copolymerization was activated by new type macroactivators (MAs) based on hydroxyl-terminated poly (ethylene oxide)-poly (propylene oxide)-poly (ethylene oxide) [PEO-PPO-PEO] triblock copolymers, known under the trade name Pluronic®. Toluene-2,4-diisocyanate (TDI) was used to obtain the isocyanate-terminated Pluronic prepolymers. The corresponding MAs were synthesized in situ with an N-carbamoyllactam structure. As an initiator of the copolymerization processes was used sodium lactamate (NaCL). To confirm the influence over the copolymerization process, microstructure, composition and molecular weight of the polymeric products two new types MAs based on Pluronic (P123 and F68) have been varied from 2 to 10 wt.% (vs. the monomer ε-CL). The structure of the both Pluronic based macroactivators (MAs) and accordingly obtained two series poly (CL-co-Pluronic) polymers were confirmed by 1H NMR and FT-IR analyses. Additionally, the structure, molecular weight, physicomechanical behavior, thermal stability and morphology of the new synthesized poly (CL–co–Pluronic) polymers have been investigated by Differential Scanning Calorimetry (DSC), Wide-Angle X-ray Diffraction (WAXD), Thermogravimetric Analysis (TGA) and Scanning Electron Microscopy (SEM) analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Scheme 2
Scheme 3
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Roda J, Budın J, Brozek J (2005) Modification of polyamide 6, 6th World Congress Polyamide, Duesseldorf.

  2. Budin J, Roda J, Brozek J, Kriz J (2006) Macromol Symp 204:78–84

    Article  Google Scholar 

  3. Zhang C-L, Feng L-F, Gu X-P, Hoppe S, Hu G-H (2001) Polym Eng Sci 51:2261–2272

    Article  Google Scholar 

  4. Zhang C-L, Feng L-F, Hoppe S, Hu G-H (2008) J Polym Sci Part A – Polym Chem 46:4766–4776.

  5. Hu G-H, Li H, Feng L-F (2002) Macromolecules 35:8247–8250

    Article  CAS  Google Scholar 

  6. Hu G-H, Li H, Feng L-F (2005) Polymer 46:4570–4578

    Google Scholar 

  7. Hu G-H, Li H, Feng L-F (2006) J Appl Polym Sci 102:4394–4403

    Article  CAS  Google Scholar 

  8. Kang TK, Kim Y, Cho WJ, Ha CS (1997) Polym Test 16:391–401

    Article  CAS  Google Scholar 

  9. Dawkins JV (1973) Block Copolymers, New York: Wiley

    Google Scholar 

  10. Yamashita Y, Murase Y, Ito K (1973) Jnl Polym Sci Polym Chem Edition 11:435–445

    Article  CAS  Google Scholar 

  11. Seo SW, Ha WS (1993) Jnl Appl Polym Sci 48:833–842

    Article  CAS  Google Scholar 

  12. Seo SW, Ha WS (1994) Jnl Appl Polym Sci 54:197–217

    Google Scholar 

  13. Yn MS, Ma CM (1994) Jnl Appl Polym Sci 53:213–224

    Article  CAS  Google Scholar 

  14. Petrov P, Gancheva V, Philipova TZ, Velichkova R, Mateva R (2000) Jnl Polym Sci Part A: Polym Chem 38:4154–4163

    Article  CAS  Google Scholar 

  15. Chromcová D, Baslerová L, Roda J, Brozek J (2008) Euro Polym Jnl 44:1733–1742

    Article  Google Scholar 

  16. Petrov P, Jankova K, Mateva R (2003) Jnl Appl Polym Sci 89:711–713

    Article  CAS  Google Scholar 

  17. Mateva R, Filyanova R, Velichkova R, Gancheva V (2003) Jnl Polym Sci Part A: Polym Chem 41:487–491

    Article  CAS  Google Scholar 

  18. Mateva R, Filyanova R, Dimitrov R, Velichkova R (2004) Jnl App Polym Sci 91:3251–3258

    Article  CAS  Google Scholar 

  19. Toncheva NV, Mateva R (2007) Adv Polym Tech 26:121–131

    Article  CAS  Google Scholar 

  20. Alexandridis P (1997) Colloid Interface Sci 2:478–489

    Article  CAS  Google Scholar 

  21. Alexandridis P (1998) Macromolecules 31:6935–6942

    Article  CAS  Google Scholar 

  22. Ha J.C., Kim S Y, Lee Y M (1999) Jnl Controlled Release 62:381.

  23. Liu CB, Gonga CY, Pan YF, Zhang YD, Wang JW, Huang MJ, Wang YS, Wang K, Gou ML, Tu MJ, Wei YQ, Qian ZY (2007) Colloids and Surfaces A: Physicochem Eng Aspects 302:430–438

    Article  CAS  Google Scholar 

  24. Brozek J, Marek M, Roda J, Kralicek J (1988) Macromol Chem 189:17–23

    Article  CAS  Google Scholar 

  25. Aharoni MS (1997) Nylons: Their Synthesis. Wiley, Structure and Properties, Chichester, England

    Google Scholar 

  26. Wunderlich B (1980) Macromolecular Physics. Academic, New York

    Google Scholar 

  27. Šebenda J (1968) Jnl Polym Sci Part C: Polym Symp 23:169–179

    Article  Google Scholar 

  28. Dencheva N, Nunes T, Olieveira MJ, Denchev S (2005) Polymer 46:887–901

    Article  CAS  Google Scholar 

  29. Pae Y (2006) Jnl Appl Polym Sci 99:292–299

    Article  CAS  Google Scholar 

  30. Hu G-H, Li H, Feng L-F (2002) Macromolecules 35:8247–8250

    Article  CAS  Google Scholar 

  31. Ji Y, Ma J, Liang B (2005) Mater Lett 59:1997–2000

    Article  CAS  Google Scholar 

  32. Rusu G, Rusu E (2004) High Perform Polym 16:569–584

    Article  CAS  Google Scholar 

  33. Petit D, Jerome R, Teyssie P (1979) Jnl Polym Sci Part A: Polym Chem 17:2903–2916

    CAS  Google Scholar 

  34. Rusu G, Ueda K, Rusu E, Rusu M (2001) Polymer 42:5669–5678

    Article  CAS  Google Scholar 

  35. Boscoletto AB, Trezza G, Andreis B, Milan L, Tavan M, Furlan P (1992) Macromolecules 25:5752–5758

    Article  Google Scholar 

  36. Hedrick RM, Gabbert JD (1981) Properties of RIM nylon 6 block copolymers. AIGhE Symposium, Detroit, MI

    Google Scholar 

  37. Godovskii YK, Dubovik II, Ivanova SL, Kurashev VV, Frunze T, Slonimskii SL (1977) Vysokomol Soed 19:392

    CAS  Google Scholar 

  38. Zhang CL, Feng LF, Hoppe S, Hu G-H (2011) Chem Eng Sci 66:1010–1013

    Article  CAS  Google Scholar 

  39. Clark ES, Wilson FC (1973) Nylon Plastics. Wiley, New York

    Google Scholar 

  40. Roldan LG, Rahl F, Pateson AR (1965) Jnl Polym Sci Part C: Polym Symp 8:145–155

    Article  Google Scholar 

  41. Yu YC, Jo WH (1995) Jnl Appl Polym Sci 56:895–900

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Polymer Engineering, University of Chemical Technology and Metallurgy, 8 Kliment Ohridski blvd., 1756, Sofia, Bulgaria

    Mariya Kyulavska, Rayna Bryaskova & Rosa Mateva

  2. Department of Amphiphilic and Ionogenic Polymers, Institute of Polymers at the Bulgarian Academy of Sciences, Acad. G. Bonchev Str. block 103-A, 1113, Sofia, Bulgaria

    Mariya Kyulavska

  3. University of Liege, Sart-Tilman B6a, 4000, Liège, Belgium

    Dimitriya Bozukova

Authors
  1. Mariya Kyulavska
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Rayna Bryaskova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Dimitriya Bozukova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Rosa Mateva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Rayna Bryaskova.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kyulavska, M., Bryaskova, R., Bozukova, D. et al. Synthesis, structure and behavior of new polycaprolactam copolymers based on poly (ethylene oxide)–poly (propylene oxide)–poly (ethylene oxide) macroactivators derived from Pluronic block copolymers. J Polym Res 21, 471 (2014). https://doi.org/10.1007/s10965-014-0471-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-014-0471-y

Keywords

Search

Navigation